A Study on the Zeta-potential of CMP processed Sapphire Wafers

CMP 가공된 사파이어웨이퍼의 웨이퍼내 표면전위에 관한 연구

  • 황성원 (전북지방 중소기업청) ;
  • 신귀수 (전북전략산업기획단) ;
  • 김근주 (전북대학교 기계공학과, 공업기술연구센터)
  • Published : 2005.02.01

Abstract

The sapphire wafer was polished by the implementation of the surface machining technology based on nano-tribology, The removal process has been performed by grinding, lapping and chemical-mechanical polishing. For the chemical mechanical polishing process, the chemical reaction between the slurry and sapphire wafer was investigated in terms of the change of Zeta-potential between two materials. The Zeta-potential was -4.98 mV without the slurry in deionized water and was -37.05 mV for the slurry solution. By including the slurry into the deionized water the Zeta-potential -29.73 mV, indicating that the surface atoms of sapphire become more repulsive to be easy to separate. The average roughness of the polished surface of sapphire wafer was ranged to 1∼4$\AA$.

Keywords

References

  1. Amano, H., Sawaki, N., Akasaki, I. and Toyoda, Y., 'Metalorganic vapor phase epitaxial growth of high quality GaN films using an AIN buffer layer,' Appl. Phys. Lett., Vol. 48, No.5, pp. 353-355, 1986 https://doi.org/10.1063/1.96549
  2. Strite, S. and Morkocs, H. J. of Vac. Sci. Technol. B, Vol. 10, No.4, pp. 1237-1266, 1992 https://doi.org/10.1116/1.585897
  3. Nakamura, S. and Fasol, G., 'The Blue Laser Diode,' Springer, Berlin, pp. 23, 1997
  4. Kh. S., Bagdasarov, 'Synthesis of large single crystals of corundum,' from 'Ruby and sapphire' edited by. L. M. Beiyaev (Nauka Pub. Moscow 1974), pp. 15-38
  5. Kim, S. Y., Seo, Y. Jin., Kim, T. H., Lee, W. S., Kim, C. I. and Chang, E. G., 'A Study for Global Planarization of Mutilevel Metal by CMP,' Trans. on EEM, Vol, 11, No. 12, pp. 1084-1090, 1998
  6. Hwang, S. W., Shin, G. S., Kim, K. and Suh, N. S., 'A Study on the Micro-lapping process of Sapphire Wafers for optoelectronic devices,' J. of the KSPE, Vol. 21, No.2, pp. 218-223, 2004
  7. Jeong, H. D., 'A Global Planarization of Interlayer Dielectric Using Chemical Mechanical Polishing for ULSI Chip Fabrication,' J. of the KSPE, Vol. 13, No. 11, pp. 46-56, 1996
  8. Jeong, H. D. and Kim, K. J., 'Effect of Slurry pH on CMP Characteristics,' Proceedings of the KSPE, spring, Vol. 2, No. 1, pp. 963-966, 1998
  9. Lee, S. H., kim, H. J., Ahn, D. G. and Jeong, H.D., 'A Study on Novel Conditioning for CMP,' J. of the KSPE, Vol. 16, No.5, pp. 40-47, 1999
  10. Cho, W., Ahn, Y. M., Baek, C. W. and Kim, Y. K., 'Chemical Mechanical Polishing of Aluminum Thin Films,' J. of the KSPE, Vol. 19, No.2, pp. 49-57, 2002
  11. Kim, S. J., Ahn, Y. M., Kim, Y. K. and Baek, C. W., 'Study on Chemical Mechanical Polishing for Reduction of Micro-Scratch,' J. of the KSPE, Vol. 19, No.8, pp. 134-140, 2002
  12. Kim, C. B., Kim, S. Y. and Sea, Y. J., 'Characteristics of Slurry Filter for Reduction of CMP Slurry induced Micro-scratch,' Trans. on EEM, Vol. 14, No.7, pp. 557-565, 2001
  13. Pohl, M. C. and Griffiphs, D. A., 'The Importance of Particle Size to the Performance of Abrasive Particle in the CMP process,' J. of Electric Materials, Vol. 25, No. 10, pp.1612-1616, 1996 https://doi.org/10.1007/BF02655584
  14. Yu, C. C., Doaa, T. T. and Laulusa, A. E., 'Method of Chemical Mechanical Polishing Aluminum Containing Metal Layers and Slurry for Chemical Mechanical Polishing,' US Patent, 5209816, 1993
  15. Papoulis, A., 'Probability, Random Variables and Stochastic Processes,' McGraw-Hill, New York, 1965
  16. Gutsche, H. W. and Moody, J. W., 'Polishing of sapphire with colloidal silica,' J. Electrochem. Soc. Vol. 125, 136, 1978 https://doi.org/10.1149/1.2131378
  17. OTSUKA ELECTRONICS, 'Electrophroretic Light Scattering Spectrophotometer,' Technical report LS-1003, 1998