Bulletin of the Korean Chemical Society

  • 제25권6호
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  • Pages.869-872
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  • 2004
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Hg2+-Selective Chemosensor Derived from 8-Hydroxyquinoline Having Benzothiazole Function in Aqueous Environment

  • 발행 : 2004.06.20
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초록

Newly synthesized 8-hydroxyquinoline based benzothiazole derivative 2 showed a distinctive $Hg^{2+}$-selectivity over other transition metal ions in aqueous solution. The fluorescence emission at 455 nm of 2 was completely quenched upon interaction with $Hg^{2+}$ ions in dioxane-$H_2O$ system (9 : 1, v/v). The selectivity was decreased in the order of $Hg^{2+}\;>>\;Cu^{2+}\;>\;Cd^{2+}\;>\;Pb^{2+}\;{\thickapprox}\;Zn^{2+}\;{\thickapprox}\;Ni^{2+},\;and\;Hg^{2+}$ concentration dependent fluorescence quenching profile was observed in the presence of common interfering metal ions as background. The fluorescence behavior of 2 suggests that the prepared compound could be used as a fluorescent signaling subunit for the construction of new $Hg^{2+}$-sensitive ON-OFF type supramolecular switching systems.

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  2. Hg2+-Selective Chemosensor Derived from 8-Hydroxyquinoline Having Benzothiazole Function in Aqueous Environment. vol.35, pp.44, 2004, https://doi.org/10.1002/chin.200444164
  3. Design and Synthesis of Nanosensor Based on CdSe Quantum Dots Functionalized with 8-Hydroxyquinoline: a Fluorescent Sensor for Detection of Al3+ in Aqueous Solution vol.28, pp.3, 2018, https://doi.org/10.1007/s10895-018-2238-z
  4. Photonic logic gates based on metal ion and proton induced multiple outputs in 5-chloro-8-hydroxyquinoline based tetrapod vol.30, pp.11, 2006, https://doi.org/10.1039/b607524j
  5. Solvatochromic Fluorescence Behavior of 8-Aminoquinoline-Benzothiazole: A Sensitive Probe for Water Composition in Binary Aqueous Solutions vol.26, pp.1, 2005, https://doi.org/10.5012/bkcs.2005.26.1.047
  6. Rhodamine-based chemosensor for Hg2+ in aqueous solution with a broad pH range and its application in live cell imaging vol.8, pp.18, 2010, https://doi.org/10.1039/c0ob00013b
  7. A water-soluble highly sensitive and selective fluorescent sensor for Hg2+ based on 2-(2-(8-hydroxyquinolin)-yl)benzimidazole via ligand-to-metal charge transfer (LMCT) vol.4, pp.32, 2004, https://doi.org/10.1039/c4ra00060a
  8. Highly Selective Ratiometric Fluorescent Probes for Detection of Perborate Based on Excited‐State Intramolecular Proton Transfer (ESIPT) in Environmental Samples and Living Cells vol.1, pp.3, 2004, https://doi.org/10.1002/slct.201500032
  9. Reaction-based sensing of fluoride ions using desilylation method for triggering excited-state intramolecular proton transfer vol.28, pp.7, 2004, https://doi.org/10.1080/10610278.2015.1122195
  10. Magnified Fluorescent Aptasensors Based on a Gold Nanoparticle−DNA Hybrid and DNase I for the Cycling Detection of Mercury(II) Ions in Aqueous Solution vol.58, pp.47, 2004, https://doi.org/10.1021/acs.iecr.9b03622