A Study on Electron Injection Characteristics of Organic Light Emitting Diodes with Doped Cathodes of Organic Light Emitting Diodes

  • Published : 2003.01.01

Abstract

The co-evaporated cathodes composed of A1 and CsF is adopted to enhance the electrical and the optical properties of organic light emitting diodes (OLEDs). The hole transport layer (HTL), made of 50nm thick N,N-dipheny1-N,N-bis(3-methylphenyl)-1,1-bipheny14,4-diamine (TPD), and the electron transport layer (ETL), made of 50nm thick tris(8-hydroxy-quinoline) aluminum (A1q$_3$), were deposited under the base pressure of 1.6$\times$10$^{-6}$ Torr. In depositing A1-CsF, the mass ratio of CsF is varied between 1 and 10wt%. OLEDs with co-evaporated cathodes have luminance of about 35,000cd/$m^2$, and external quantum efficiency of about 1.38%. Cs tends to diffuse into the organic layer and then re-forms Cs$^{+}$cation and free electron with the Cs-doped surface region.n.

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References

  1. 'Organic electroluminescent diodes.', C. W. Tang and S. A. VanSlyke, Appl. Phys. Lett. 51, p.913 (1987)
  2. 'Electroluminescence of doped organic thin films.', C. W. Tang, S. A. VanSlyke, and C. H. Chen, J. Appl. Phys., 65, p.3610 (1989)
  3. 'Carrier tunneling and device characteristics in polymer light emitting diodes.' I. D. Parker, J. Appl. Phys., 75, p.1656 (1994)
  4. 'Highly efficient and bright organic electroluminescent devices with an aluminum cathode.' G. E. Jabbour, Y. Kawabe, S. E. Shaheen, J. F. Wang, M. M. Morrell, B. Kippelen, and N. Peyghambarian, Appl. Phys. Lett., 71 p.1762 (1997)
  5. 'Lithium-aluminum contacts for organic lightemitting devices.' E. I. Haskal, A. Curioni, P. F. Seidler, W. Andreoni, Appl. Phys. Lett., 71, p.1151 (1997)
  6. 'Improvement in electron and hole injection at electrodes and in recombination at a two-organic-layer interface.', M. Fujihira, C, Ganzorig, Materials Science and Engineering B, 85, p.203 (2001)
  7. 'Bright organic electroluminescent devices having a metal-doped electron-injecting layer.' J. Kido, T. Matsumoto , Appl. Phys. Lett., 73 p. 2866 (1998)
  8. 'Lithium doping of semiconducting organic charge transport materials.' G. Parthasarathy, C. Shen, A. Kahn, and S. R. Forrest, J. Appl. Phys., 89, p.4986 (2001)
  9. 'An experimental study of poly(9,9-dioctyl-fluorene) and its interfaces with Al, LiF and CsF.', G. Greczynski, W. R. Salaneck, M. Fahlman, Appl. Surface Science, 175-176, p.319 (2001)
  10. 'Aluminum based cathode structure for enhanced electron injection in electroluminescent organic devices.' G. E. Jabbour, B. Kippelen, N. R. Armstrong, and N. Peyghambarian, Appl. Phys. Lett., 73, p.1185 (1998)
  11. 'A lithium carboxylate ultrathin film on an aluminum cathode for enhanced electron injection in organic electroluminescent devices.' C. Ganzorig, M. Fujihara. Jpn. J. Appl. Phys. 38 p. L1348 (1999)
  12. 'Interfacial chemistry of $Alq_{3}$ and LiF with reactive metals.' M. G. Mason, C. W. Tang, L. -S. Hung, P. Raychaudhuri, J. Madathil, and D. J., Giesen, J. Appl. Phys. 89 p. 2756 (2001)
  13. Kwan C. Kao, Wei Hwang, 'Electrical Transport in Solids' p. 159, (1981)