Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Synthesis and Catalytic Properties of Imidazole-Functionalized Poly(propylene imine)Dendrimers

  • Baker, Lane A. ;
  • Sun, Li ;
  • Crooks, Richard M.
  • Published : 2002.05.20
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Abstract

The synthesis and characterization of third- and fifth-generation poly(propylene imine) dendrimers terminated with imidazole moieties is reported. Functionalization was achieved using simple peptide coupling reagents. These materials were characte rized by MALDI-MS, NMR, and titration. The use of these endgroup-functionalized dendrimers as catalysts for the hydrolysis of 2,4-dinitrophenyl acetate is described. Molecular simulations provide a basis for interpreting the catalytic data.

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