CHaracteristics of (Pb,La)T$TiO_3$ Thin Film by Deposition Condition of Pulsed Laser Ablation

레이저 어블레이션에 의한 (Pb,La)$TiO_3$박막의 제작조건에 따른 특성

  • 박정흠 (김포대학 전자정보계열) ;
  • 박용욱 (남서울대학교 전자정보통신공학부) ;
  • 마석범 (용인송담대학 전기설비과)
  • Published : 2001.12.01

Abstract

In this study, high dielectric materials, (Pb,La)Ti $O_3$ thin films were fabricated by PLD (Pulsed Laser Deposition) method and investigated in terms of structural and electrical characteristics in order to develope the dielectric materials for the use of new capacitor layers of Giga bit-level DRAM. The deposition conditions were examined in order to fabricate uniform thin films through systematic changes of oxygen pressures and substrate temperature. The uniform thickness and smooth morphology of (P $b_{0.72}$L $a_{0.28}$)Ti $O_3$ thin films were obtained at the conditions of substrate-target distance 5.5[cm], laser energy density 2.1[J/$\textrm{cm}^2$], oxygen pressure 200[mTorr] and substrate temperature 500[$^{\circ}C$]. After the (P $b_{0.72}$L $a_{0.28}$)Ti $O_3$ thin films were fabricated under the above conditions, they were post-annealed by RTA process in order to increase the dielectric constant. The film thickness of 1200 [$\AA$] had dielectric constant 821. Assuming that operating voltage is 2V, leakage current density of (P $b_{0.72}$L $a_{0.28}$)Ti $O_3$ thin films would result into 10$^{-7}$ [A/$\textrm{cm}^2$] and satisfied the specification of 256M DRAM planar capacitor, 4$\times$10$^{-7}$ [A/$\textrm{cm}^2$]m}^2$]

Keywords

References

  1. International Electron Devices Meeting Technology Digest K.Koyama
  2. Material Research Society v.361 The Effects of La Concentration on the Properties of PLT Thin Films:From the Perspective of DRAM Application S.J.Kang;J.S.Ryoo;Y.S.Yoon
  3. 전기전자재료학회논문지 v.11 no.6 Pt/SrTiO₃/Pbx(Zr0.52Ti0.48)O₃/SrTiO₃/Si 구조의 전기적 특성 분석 및 SrTiO₃박막의 완층층 역할에 관한 연구 김형찬;신동석;최인훈
  4. 전기전자재료학회논문지 v.45 펄스레이저 증착법의 원리와 응용 이상렬
  5. Intergrated Ferroelectrics v.8 Ferroelectric Properties and Reliability of La-Sr-Co-O/Pb-La-Zr-Ti-O/La-Sr-Co-O Heterostructures on Si for Non-Volatile Memory Applications J.Lee
  6. Phys. stat. Sol. v.(a)3 The Distortion of Vacancies in Lanthan-Doped Lead Titanate D.Hennings;K.H.Hardtl
  7. 한국전기전자재료학회 추계학술대회 논문집 Sol-Gel법에 의한 (Pb,La)TiO₃박막의 전기적 특성 구본혁;박정흠;장낙원;마석범;박창엽
  8. MRS Symp. Proc. v.310 Preferred Orientation for Sol-Gel Derived PLZT Thin Layer T.Tani;Z.Xu;David A.Payne
  9. 전기전자재료학회논문지 v.11 no.2 레이저 어블레이션에 의한 (Pb,La)TiO₃ 박막의 제작 박정흠;김준한;이상렬;박종우;박창엽
  10. KAIST 박사학위논문 배향성 PZT 박막제조와 배향성기구 분석 및 전기적 특성에 관한 연구 김창정
  11. Pulsed Laser Deposition of Thin Films Douglas D.Chrisey;Graham K.Hubler
  12. Intergrated Ferro. v.7 Thickness dependent dielectric properties of sol-gel prepared lead lanthanum titanate films D.B.Beach;R.B.Laibowitz;T.M.Shaw;A.Grill;W.F.Kane
  13. J.Mater.As. v.9 no.9 Formation of secondary phase in the Pb-containing perovskite films by pulsed laser deposition M.H.Yeh;K.S.Liu;I.N.Lin