A Study of $SO_2$ Adsorption Characteristics by Adsorbents in a Fixed Bed Reactor

고정층 반응기를 이용한 흡착제 종류에 따른 $SO_2$ 흡착특성에 관한 연구

  • Published : 1999.04.01

Abstract

This study evaluated the availability as an alternative adsorbent which is cheaper and more efficient than CuO/${\gamma}$-$Al_2O_3$ which have been studing vigorously to remove $SO_2$. Five adsorbents (CuO/${\gamma}$-$Al_2O_3$, Iron ore, Slag, LD slag, $Fe_2O_3$) was employed in a fixed bed reactor. $SO_2$ breakthrough curves were obtained as a function of temperature, initial gas velocity and particle size. Saturation capacities calculated by the numerical integration of breakthrough curves of $SO_2$ increased with increasing reaction temperature. $SO_2$ breakthrough curve equation of $Fe_2O_3$ for this system can be expressed as Kr=3,914,000 exp(-37,329.86/RT). By means of the breakthrough curve, the influence of bed height on breakthrough time was also estimated.

Keywords

References

  1. 대한환경공학학회지 v.18 no.3 연탄제에 의한 배연탈황 흡착탑의 $SO_{2}$흡착특성 결정 모세영;박인호;김민수
  2. 고려대학교 화학공학과 학위논문 유동층반응기에서 천연방간광석을 이용한 SOx/NOx 동시 제거반응 특성 박태성
  3. 플라즈마를 이용한 유해가스처리 신기술, 가스상 오염물질처리 신기술 송영훈;김용진;김석준
  4. 대한관경공학회지 v.13 no.1 석회석 특성이 유동층 연소로의 탈황에 미치는 영향. 오광중;홍성창;김재용;도동섭
  5. 고려대 석사학위논문 유동층반응기에서 천연망간광석을 이용한 이산화황제거 정순관
  6. Electron Beam을 이용한 유해가스 처리 기술, 가스상 오염물질처리 신기술 한범수;조기헌;조광제
  7. 대한환경공학회지 v.20 no.1 유동층 반응기에서 Natrual Manganese Dioxide를 이용한 탈황연구 홍성창;정순관
  8. Ind. Eng Chem. v.52 Acelis,J.D.;G.Thodos
  9. The Canadian Journal of Chemical Engineering v.49 Rate of Reaction of SO₂with Metal Oxides DAVID W. DeBERRY;KARL J. SLADEK
  10. AIChE v.33 no.2 Alkali-Alumina Sorbents for High-Temperature Removal of$SO_{2}$ Gavalas.G.R;Sergin Edelstein;M. Flytzari Stephanopulps;T.A.Weston
  11. Chemical Reaction Engineering(2nd ed.) Levenspiel,O.
  12. J Air Pollution Control Assoc. v.20 McCrea, D.H.;A.J. Forney;J G. Myers
  13. Journal of Chemical Engineering of JAPAN v.16 no.2 $SO_{2}$ Removal by CuO on Υ-alumina Moo Hwan CHO;Won Kook LEE
  14. Sulphur adsorption, desorption, exchange on platinum/alumina. rhenium/alumina, platinum rhenium/alumina catalysts v.86 Ponilzsch,L.;M.Wilde;P.Tetenyi;M.Dobrovoiszky;Z.Paal
  15. SOx Adsorption/Desorption process on Υ-Alumina for SOx transfer catalysis v.16 Soren Anderson;Robert Pomp;Nils Gosta Vannerberg
  16. Applied Catalysts v.71 Evalluation of magnesium aluminate spinel as a sulfur dioxide transfer catalyst Waqif,M.;O. Saur;J.C.Lavalley;Y.Wang;B.A. Morrow
  17. Ind Eng. Chem. Proc. Eds. Dev v.15 no.2 Yates,I.G.;R.J.Bests