Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Electrochemical Reduction of Oxygen at Co(II)-3,4-bis (salicylidene diimine)toluene Complex supported Glassy Carbon Electrode

  • Published : 19950100
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Abstract

Electrochemical reduction of oxygen has been carried out at glassy carbon electrode and carbon ultramicroelectrode, the surface of which is modified with a new Co(Ⅱ)-Schiff base complex, Co(Ⅱ)-3,4-bis(salicylidene diimine)toluene in 1 M KOH solution. The results obtained from cyclic voltammetric and chronoamperometric experiments are consistent with the formation of the reasonably stable superoxide ions as a primary electron transfer reaction product. The exchange rate constant obtained for oxygen reduction is about 0.02 cm/s.

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References

  1. Electrochemistry; A Specialist Periodical Report v.8 Schiffrin, D. J.;Pletsher, D.(ed.)
  2. Oxygen Chemistry Sawyer, D. T.
  3. Acc. Chem. Res v.12 Wilshire, J.;Sawyer, D. T.
  4. Acc. Chem. Res. v.14 Sawyer, D. T.;Valentine, J. S.
  5. Inorg. Chem. v.29 Shin D.-S.;Doddapaneni, N.;Park, S.-M.
  6. Electrochemistry of Carbon v.84-1 The Electrochem. Society Proceedings Series Yeager, E.;Molla, J. A.;Gupta, S.;Sarapangani, S.(ed.);Akridge, J. R.(ed.);Schum, B.(ed.)
  7. Electrochem. Soc. Ext. Abst v.93-1 Choi, Y. K.;Park, S.-M.
  8. J. Kor. Chem. Soc. v.37 Choi, Y. K.;Chjo, K. H.;Park, J. K.
  9. J. Electroanal. Chem. v.103 Nikolic, B. Z.;Adzic, R. R.;Yeager, E. B.
  10. J. Electrochem. Soc. v.127 Zagel, J.;Bindra, P.;Yeager, E. B.
  11. J. Electrochem. Soc. v.131 Bull, R. A.;Fan, F. R.;Bard, A. J.
  12. J. Electroanal. Chem. v.196 Zecevic, S.;Simic-Glavaski, B.;Yeager, E. B.
  13. J. Electroanal. Chem. v.200 Elzing, A.;Van der Putten, A.;Visscher, W.;Barendrecht, E.
  14. J. Electroanal. Chem. v.214 Van der Putten, A.;Elzing, A.;Visscher, W.;Barendrecht, E.
  15. J. Electroanal. Chem. v.297 Qayang, J.;Shigehara, K.;Yamada, A.;Anson, F. C.;Ngamei
  16. Inorg. Chem. v.27 Collman, J. P.;Hendricks, N. H.;Leidner, C. R.;Ngameni, E.
  17. J. Am. Chem. Soc. v.102 Collman, J. P.;Denisevich, P.;Konai, Y.;Marrocco, M.;Koval, C.;Anson, F. C.
  18. J. Am. Chem. Soc. v.103 Geiger, T.;Anson, F. C.
  19. J. Am. Chem. Soc. v.105 Durand, Jr. R. R.;Bencosme, C. S.;Collman, J. P.;Anson, F. C.
  20. J. Phys. Chem. v.89 Liu, H.-Y.;Abdalmuhdi, I.;Chang, C. K.;Anson, F. C.
  21. J. Am. Chem. Soc. v.106 Chang, C. K.;Liu, H.-Y.;Abdalmuhdi, I.;Anson, F. C.
  22. J. Electroanal. Chem. v.306 Gupta, S.;Fierro, C.;Yeager, E. B.
  23. Electrochim. Acta v.29 Yeager, E. B.
  24. Electrochim. Acta v.157 Van Den Brink, F.;Visscher, W.;Barendrecht, E.
  25. J. Appl. Electrochem. v.21 Elmorsi, M. A.;Gabor, M.;Barendrecht, E.
  26. J. Electroanal. Chem. v.112 Fischer, P.;Heibaum, J.
  27. J. Am. Chem. Soc. v.60 Ueno, K.;Martell, A. E.
  28. J. Chem. Edu. v.60 Kissinger, Peter T.;Heineman, W. R.
  29. Electrochemical Methods Bard, A. J.;Faulkner L. R.
  30. Electroanal. Chem. v.15 Wightman, R. M.;Wipf, D. O.
  31. Electroanalysis v.3 Sucheta, A.;Rusling, J. E.
  32. Anal. Chem. v.57 Baransky, A. S.;Fawcett, W. R.;Gilbert, C. M.
  33. Anal. Chem. v.37 Nicholson, R. S.
  34. Modern Electrochemistry v.2 Bockris, J. O'M.;Reddy, A. K. N.