Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Synthesis and Characterization of Molybdenum(V)-Oxo Complexes with ONO-Donors

  • Published : 19950100
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Abstract

Six-coordinate molybdenum(Ⅴ)-oxo complexes (PyH)[MoOCl2L] and (R4N)-[MoOCl2L] (R=CH3 and C2H5) with N-salicylidene-2-aminophenol(L1) and its derivatives(L2=5-CH3, L3=3-CH3O, L4=5,6-C4H4 and L5=5-NO2) as ONO-donor ligands have been synthesized and the spectral and electrochemical properties of the complexes by elemental analysis, molar conductivity, UV-vis, IR, 1H NMR and CV have been studied.

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References

  1. Inorg. Chem. v.28 Purohit, S.;Koley, A. P.;Prasad, L. S.;Manoharan, P. T.;Ghosh, S.
  2. Inorg. Chem. v.27 Mondal, J. U.;Schultz, F. A.;Brennan, T. D.;Scheidt, W. R.
  3. Inorg. Chem. v.20 Rajan, O. A.;Chakravorty, A.
  4. J. Chem. Soc., Dalton Trans. Bhattacharjee, S.;Bhattacharyys, R.
  5. Inorg. Chem. v.23 Topich, J.;Lyon, J. T.
  6. In Molybdenum Chemistry of Biological Significance Bray, R. C.
  7. Enzymes v.12 Bray, R. C.
  8. J. Am. Chem. Soc. v.103 Cramer, S. P.;Wahl, R.;Rajagoplan, K. V.
  9. J. Chem. Soc. Dalton, Trans Bhattacharjee, S.;Bhattacharyya, R.
  10. Inorg. Chem. v.22 Berg, J. M.;Holm, R. H.
  11. Inorg. Chim. Acta v.7 Sabet, H.;Rudolf, M. F.;Jezowska-Trzebltowska, B.
  12. Textbook of Practical Organic Chemistry(5th Ed.) Furniss, B. S.;Hannaford, A. J.;Smith, P. W. G.;Tatchell, A. R.
  13. Bull. Korean Chem. Soc. v.13 Kim, J. S.;Koo, B. K.
  14. Coord. Chem. Rev. v.7 Geary, W. J.
  15. J. Chem. Soc. A. Greenwood, N. N.;Straughan, B. P.;Wilson, A. E.
  16. Bull. Korean Chem. Soc. Kim, H. J.;Koo, B. K.
  17. Inorg. Chim. Acta. v.35 Hill, W. E.;Atabay, N.;McAuliffe, C. A.;McCullough, F. P.;Razzolci, S. M.
  18. Transition Met. Chem. v.9 Chandra, S.;Sharma, K. K.
  19. Spectrochimica Acta v.23 Kovacis, J. E.
  20. Can. J. Chem. v.53 Alyea, E. C.;Malek, A.
  21. Inorg. Chim. Acta v.85 Yamanouchi, K.;Yamada, S.;Enemark, J. H.
  22. J. Chem. Soc., Dalton Trans. Marchi, A.;Duatti, A.;Rossi, R.;Magon, L.;Pasqualini, R.;Bertolasi, V.;Gille, G.
  23. Prog. Inorg. Chem. v.22 Lippard, S. J.
  24. Tables of Spectral Data for Structure Determination of Organic Compounds Pretsch, E.;Seibl, J.;Simon, W.;Clere, K.;Fresenius, W.(ed.);West, Th. S.(ed.)
  25. Refer to page H75
  26. J. Chem. Soc. Allen, E. A.;Briscon, B. J.;Edwards, D. A.;Fowles, G. W. A.;Wiliams, R. G.
  27. Prog. Inorg. Chem. v.22 Lippard, S. J.
  28. J. Chem. Soc.,Dalton Trans. Chaudhury, M.

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