• 제목/요약/키워드: ~biodiesel

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DME를 이용한 승용 디젤 커먼레일 엔진의 연소 및 배기특성 (Combustion and Emission Characteristics of Passenger Car Common-rail Diesel Engine with DME Fuel)

  • 이동곤;연인모;노현구;최석천;이창식
    • 한국자동차공학회논문집
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    • 제18권6호
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    • pp.91-97
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    • 2010
  • This paper described the effects of DME blended fuel on the engine combustion and emission characteristics of four cylinder CRDI diesel engine. Biodiesel was added into the DME fuel in order to improve the low kinematic viscosity of DME fuel. In this work, the experiment was performed under th various injection timings and injection strategy at constant engine speed and engine load. To maintain the fuel pressure and temperature, pressure and temperature controllers were installed to the DME fuel system. The results show that ignition delay was shortened and combustion duration was extended when DME blended fuel is supplied. Despite of slightly higher NOx emission with DME blended fuel at equal conditions in comparison with those of diesel fuel, the engine showed lower HC and CO emission characteristics.

연속공정에서 알칼리 및 혼합촉매를 사용한 자트로파유의 바이오디젤화 (Conversion of Jatropha Oil into Biodiesel in Continuous Process Using Alkali and Mixed Catalysts)

  • 현영진
    • 한국응용과학기술학회지
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    • 제26권4호
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    • pp.394-399
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    • 2009
  • The esterification of palmitic acid in Jatropha Oil using 8wt% p-TSA catalyst was done at the 1:8 molar ratio of oil to methanol and $65^{\circ}C$. The conversion of palmitic acid appeared to be 95.3% in 60min. After that, the continuous transesterification of the oil using 0.5wt% KOH, 0.8wt% TMAH mixed catalyst[40vol% KOH(0.5wt%) + 60vol% TMAH(0.8wt%)] and 1.1wt% TMAH was conducted with the flow rates and the molar ratios at $65^{\circ}C$. The overall conversion of Jatropha Oil increased with the decrease of flow rate and showed 95.6% with 9ml/min of flow rate at the 1:8 molar ratio of oil to methanol and $65^{\circ}C$. But it showed 87% with 15ml/min of flow rate at the same conditions. The recovery of methanol(%) appeared to be 86% at the 1:8 molar ratio of oil to methanol, mixed catalyst and $65^{\circ}C$.

Characterization of an Alkaline Family I.4 Lipase from Bacillus sp. W130-35 Isolated from a Tidal Mud Flat with Broad Substrate Specificity

  • Kim, Hee Jung;Jung, Won Kyeong;Lee, Hyun Woo;Yoo, Wanki;Kim, T. Doohun;Kim, Hoon
    • Journal of Microbiology and Biotechnology
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    • 제25권12호
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    • pp.2024-2033
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    • 2015
  • A gene encoding lipolytic enzyme, lip7-3, was isolated from Bacillus sp. W130-35 isolated from a tidal mud flat. The gene encoded a protein of 215 amino acids with a signal peptide composed of 34 amino acid residues. Lip7-3 belonged to the family I.4 lipase and showed its maximal activity at pH 9.0 and 60℃. Its activity increased in the presence of 30% methanol and, remarkably, increased as well to 154.6% in the presence of Ca2+. Lip7-3 preferred p-nitrophenyl octanoate (C8) as a substrate and exhibited broad specificity for short- to long- chain fatty acid esters. Additionally, Lip7-3 showed a low degree of enantioselectivity for an S-enantiomer (e.g., (S)-methyl-3-hydroxy-2-methylpropionate). It efficiently hydrolyzed glyceryl tributyrate, but did not hydrolyze glyceryl trioleate, fish oil, or olive oil. Its substrate specificity and activation by the solvent might offer a merit to the biotechnological enzyme applications like transesterification in the production of biodiesel.

Forward osmosis membrane filtration for microalgae harvesting cultivated in sewage effluent

  • Kim, Su-Bin;Paudel, Sachin;Seo, Gyu Tae
    • Environmental Engineering Research
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    • 제20권1호
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    • pp.99-104
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    • 2015
  • The purpose of this study is to evaluate the performance of forward osmosis (FO) system for harvesting microalgae cultivated in secondary sewage effluent. Microalgae species used in this study were chlorella sp. ADE4. The drawing agents used for forward osmosis system were seawater and concentrate of sea water reverse osmosis (SWRO) system. Chlorella sp. ADE4 cultured in secondary sewage effluent illustrated moderate efficiency in removal of total nitrogen (TN) (68%) and superior performance in total phosphorus (TP) removal (99%). Comparison of seawater and SWRO concentrate as drawing agent were made in FO membrane separation of the microalgae. The result from this study depicts that SWRO concentrate is strong drawing agent in FO membrane system providing an average dewatering rate of $4.8L/(m^2{\cdot}hr)$ compared to seawater with average dewatering of $2.9L/(m^2{\cdot}hr)$. Results obtained from this study indicated that FO system could be viable option for harvesting the microalgae for further biodiesel production. SWRO concentrate as a drawing agent could be very important finding in field of membrane technology for disposal of SWRO concentrate.

Performance and emission characteristics of biodiesel blends in a premixed compression ignition engine with exhaust gas recirculation

  • Kathirvelu, Bhaskar;Subramanian, Sendilvelan
    • Environmental Engineering Research
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    • 제22권3호
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    • pp.294-301
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    • 2017
  • This paper is based on experiments conducted on a stationary, four stroke, naturally aspirated air cooled, single cylinder compression ignition engine coupled with an electrical swinging field dynamometer. Instead of 100% diesel, 20% Jatropha oil methyl ester with 80% diesel blend was injected directly in engine beside 25% pre-mixed charge of diesel in mixing chamber and with 20% exhaust gas recirculation. The performance and emission characteristics are compared with conventional 100% diesel injection in main chamber. The blend with diesel premixed charge with and without exhaust gas recirculation yields in reduction of oxides of nitrogen and particulate matter. Adverse effects are reduction of brake thermal efficiency, increase of unburnt hydrocarbons (UBHC), carbon monoxide (CO) and specific energy consumption. UBHC and CO emissions are higher with Diesel Premixed Combustion Ignition (DPMCI) mode compared to compression ignition direct injection (CIDI) mode. Percentage increases in UBHC and CO emissions are 27% and 23.86%, respectively compared to CIDI mode. Oxides of nitrogen ($NO_x$) and soot emissions are lower and the percentage decrease with DPMCI mode are 32% and 33.73%, respectively compared to CIDI mode.

Enhanced Biofuel Production from High-Concentration Bioethanol Wastewater by a Newly Isolated Heterotrophic Microalga, Chlorella vulgaris LAM-Q

  • Xie, Tonghui;Liu, Jing;Du, Kaifeng;Liang, Bin;Zhang, Yongkui
    • Journal of Microbiology and Biotechnology
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    • 제23권10호
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    • pp.1460-1471
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    • 2013
  • Microalgal biofuel production from wastewater has economic and environmental advantages. This article investigates the lipid production from high chemical oxygen demand (COD) bioethanol wastewater without dilution or additional nutrients, using a newly isolated heterotrophic microalga, Chlorella vulgaris LAM-Q. To enhance lipid accumulation, the combined effects of important operational parameters were studied via response surface methodology. The optimal conditions were found to be temperature of $22.8^{\circ}C$, initial pH of 6.7, and inoculum density of $1.2{\times}10^8cells/ml$. Under these conditions, the lipid productivity reached 195.96 mg/l/d, which was markedly higher than previously reported values in similar systems. According to the fatty acid composition, the obtained lipids were suitable feedstock for biodiesel production. Meanwhile, 61.40% of COD, 51.24% of total nitrogen, and 58.76% of total phosphorus were removed from the bioethanol wastewater during microalgal growth. In addition, 19.17% of the energy contained in the wastewater was transferred to the microalgal biomass in the fermentation process. These findings suggest that C. vulgaris LAM-Q can efficiently produce lipids from high-concentration bioethanol wastewater, and simultaneously performs wastewater treatment.

분사압력 변화에 따른 디젤-DME연료의 다단분사 특성에 관한연구 (An Investigation on Spray Characteristics of Diesel - DME with Change of Injection Pressure)

  • 정연호;양지웅;오충환;임옥택
    • 한국분무공학회지
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    • 제18권4호
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    • pp.188-195
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    • 2013
  • An investigation on spray characteristics of fuels which diesel and di-methyl ether (DME) with change of injection pressure used the multi-injection in constant volume combustion chamber (CVCC). Diesel was already used famous fuel which we could use. DME showed similar features with diesel like as cetane number, auto-ignition temperature. High cetane number of diesel and DME could make possible to compression ignition. DME showed different atomization from diesel due to evaporating pressures and boiling points. Experiments were carried out in CVCC equipped with Delphi solenoid 6-hole type injector and the spray characteristics of diesel and DME were tested the various pre and pilot injection. Terms of injections and a number of injections in multi-injection has been controlled. Experiments were performed in 2 types that 1500 rpm, 2000 rpm and under the condition of injection ranging from 100 bar to 500 bar. From the results of this experiment diesel showed longer spray penetration than DME. That result showed different of atomization speed DME and diesel. Result of high injection pressure condition showed similar spray characteristics diesel and DME. After this investigation, new conditions and experiments using laser light to go forward and add the fuels like as the biodiesel and diesel and DME blend.

구조 안전성을 고려한 수소 연료 전지차 용기 밸브의 솔레노이드 액추에이터 설계 (Design of Solenoid Actuator for FCV Cylinder Valve Considering Structural Safety)

  • 이효렬;안중환;신진오;김화영
    • 한국생산제조학회지
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    • 제25권3호
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    • pp.157-163
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    • 2016
  • Green vehicles include electric vehicles, natural gas vehicles, fuel cell vehicles (FCV), and vehicles running on fuel such as a biodiesel or an ethanol blend. An FCV is equipped with a cylinder valve installed in an ultra-high pressure vessel to control the hydrogen flow. For this purpose, an optimum design of the solenoid actuator is necessary to ensure reliability when driving an FCV. In this study, an electromagnetic field analysis for ensuring reliable operation of the solenoid actuator was conducted by using Maxwell V15. The electromagnetic field analysis was performed by magnetostatic technique, according to the distance between magnetic poles in order to predict the attraction force. Finally, the attraction force was validated through comparison between the Maxwell results and measurement results. From the results, the error of attraction force ranged from 4.53 % to 9.05 % at testing conditions.

바이오에너지 원료작물 생산 및 연구동향 (Bioenergy Crop Production and Research Trends)

  • 김광수;김용범;장영석;방진기
    • Journal of Plant Biotechnology
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    • 제34권2호
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    • pp.103-109
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    • 2007
  • The increasing industrialization of the world has led to precipitous rise for the demand of petroleum-based fuels. The world is presently confronted with the twin crises of fossil fuel depletion and environmental pollution. The search for alternative fuels, which promise a harmonious correlation with sustainable development, energy conservation, efficiency and environmental preservation, has become highly pronounced in the present. Bioenergy is playing an increasingly important role as an alternative and renewable source of energy. Use of Bioenergy has several potential environmental advantages. The most important perhaps is reduction in life cycle greenhouse gases emissions relatives petroleum fuels, since bioenergy is derived from plants which convert Carbon dioxide ($CO_{2}$) into Carbohydrates in their growth. Bioenergy includes solid biomass, biomas and liquid bio-fuels which are fuels derived from crop plants, and include biomass that's directly burned. The two most important bio liquid fuels today are bioethanol from fermenting grain, grass, straw or wood, and biodiesel from plant seed oil.

폐 글리세롤과 돈분의 혼합 소화 (Co-digestion of Waste Glycerol with Swine Manure)

  • 김상현
    • 유기물자원화
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    • 제18권2호
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    • pp.71-75
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    • 2010
  • 바이오디젤 과정에서 부산물로 발생하는 글리세롤의 양은 가까운 시일 안에 글리세롤 수요를 초과할 것으로 예상되고 있다. 본 연구에서는 글리세롤의 유효 이용 및 처리 측면에서 돈분과의 혼합 소화 가능성을 타진하였다. 글리세롤이 13.8 g/L로 투입된 경우 돈분 단독 소화에 비해 메탄 생성량과 속도가 각각 90%, 120% 향상되어 혼합 기질로 사용될 수 있음을 보였으며, 글리세롤로부터 메탄의 수율은 232 mL/g였다. 그러나 27.5 g/L 이상의 농도에서는 저해작용으로 인해 메탄 생성 속도가 감소되었다. 돈분과의 혼합 소화 시 글리세롤의 최적 주입 농도는 13.8 g/L부근인 것으로 사료된다.