• 한국화재소방학회논문지
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• 제22권5호
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• pp.79-82
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• 2008

바이오디젤은 식물성기름등으로부터 제조시 메탄올과의 반응으로부터 제조되므로 바이오디젤의 잔존 메탄올은 화재폭발위험성을 높일 수 있다. 바이오디젤에 존재하는 메탄올의 위험도를 측정하기 위하여 바이오디젤에 메탄올을 일정 비율로 첨가하여 인화점과 동점도를 측정하였다. 바이오디젤의 인화점은 메탄올의 증가에 따라 현저히 감소하였으며 동점도도 감소하는 것으로 나타났다. 실험결과 바이오디젤 연료에 반응물 메탄올이 잔존하거나 또는 연료의 점성을 낮추기 위하여 첨가되는 메탄올은 바이오디젤의 인화점을 낮추어 화재폭발 위험성이 높은 것으로 나타났다.

• 한국유기농업학회지
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• 제14권3호
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• pp.237-249
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• 2006

The objective of this paper was to evaluate economic feasibility of biodiesel production. Biodiesel is a diesel-fuel replacement produced from domestic renewable resources such as vegetable oils. This paper deals mainly with the income and cost data to analyze economic feasibility of biodiesel. The income of a rape farmer for biodiesel was 206,894won/10a, and it's similar to barley income. In addition a rape production for biodiesel have ancillary effect. Therefore we have to use direct payment for encouraging the production and use of biodiesel.

• Asian-Australasian Journal of Animal Sciences
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• 제22권11호
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• pp.1531-1539
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• 2009

This study compared the nutritional value of canola (B. napa) and mustard (B. hirta) press cakes obtained from the biodiesel industry as ingredients for use in diets fed to broiler chickens. A total of 210, one-day old, male broiler chicks were randomly assigned to one of seven dietary treatments. The control diet was based on wheat and soybean meal and contained 15% canola meal. For the experimental diets, 5, 10 or 15% of the canola meal was replaced with an equal amount of either canola or mustard biodiesel press cake. Dry matter and neutral detergent fiber digestibility were significantly higher for birds fed diets containing either canola or mustard biodiesel press cake compared with canola meal. Dry matter and neutral detergent fiber digestibility of the canola biodiesel press cakes was higher than the mustard biodiesel press cakes. Ether extract digestibility and nitrogen retention were significantly higher for birds fed canola biodiesel press cake compared with canola meal and mustard biodiesel press cake. Body weight gain and feed intake did not differ between birds fed canola or mustard biodiesel press cake and canola meal. In addition, there was no significant difference in body weight gain or feed intake between birds fed diets containing canola or mustard biodiesel press cake. Feed conversion was significantly improved for birds fed either canola or mustard biodiesel press cake compared with canola meal. Mortality was unaffected by treatment. Since the performance of broilers fed canola biodiesel press cakes was essentially the same as that of broilers fed canola meal, it is difficult to justify a premium to be paid for canola biodiesel press cake over that paid for canola meal. In addition, there was no difference in the performance of broilers fed biodiesel press cake obtained from canola or mustard seed. As mustard seeds are generally available at a lower price than canola seed, there may be some incentive to use mustard rather than canola seed for producing biodiesel press cake for use in poultry production.

• 한국응용과학기술학회지
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• 제36권4호
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• pp.1399-1409
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• 2019

바이오디젤은 신재생연료이면서 환경 친화적인 수송용 액상 바이오연료이다. 곤충은 새로운 바이오디젤 원료로 여겨지고 있다. 특히, 동애등에는 높은 지질을 함유하고 있어 재생가능한 바이오디젤 원료이다. 동애등에 유래 바이오디젤은 포화지방산 함량이 높고 다불포화지방산 함량이 낮아 품질이 좋은 바이오디젤을 만들 수 있다. 동애등에 유래 바이오디젤은 EN 14214의 대부분 품질기준을 만족한다. 동애등에는 기존의 식물성 원료, 미세조류에 비해 지질 수율이 높아 바이오디젤 생산성이 높다. 본 논문에서는 곤충 유래 바이오디젤의 전반적인 생산 방법과 품질 특성에 대해 서술하였다.

• Tribology and Lubricants
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• 제26권1호
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• pp.78-87
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• 2010

Biodiesel have been studied as alternative fuel due to solution of air pollution and fossil fuel exhaustion. Biodiesel from animal fat and vegetable oil was known as eco-friendly fuel like low toxicity, biodegradable compare to petrodiesel. In particular, biodiesel have excellent lubricity due to involved ester functional group. This paper shows the biodiesel's lubricity based on worldwide biodiesel research.

• International Journal of Safety
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• 제11권1호
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• pp.11-14
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• 2012

Hazard of Biodiesel (BDF) was studied. Biodiesel is a name for a variety of ester-based fuel made from vegetable oils. Recently importance of biodiesel is increasing, and its fires were sometimes reported. Therefore we studied on hazard of biodiesel comparing (petroleum) diesel oil and vegetable oil, raw materials of biodiesel. We found that biodiesel is auto-oxidized easily and ignites, and its flash point decreases when even small amount of methanol exists. And there are various raw materials to manufacture biodiesel, so we studied the difference of these materials, and their aging on safety.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2011년도 춘계학술대회 초록집
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• pp.220.2-220.2
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• 2011

Biodiesel and biodiesel blend fuel are receiving increasing attention as alternative fuels for diesel engines without substantial modifications. Biodiesel fuels and blending have been widely studied and applied in diesel engine because of biodiesel's lower sulfur, lower aromatic hydrocarbon and higher oxygen content. Biodiesels have the potential to be oxidized in different condition. It has reported that oxidation deterioration of biodiesel is different in the condition of storage and oxidation causes chemical property change of methyl esters. Sunlight intensity, temperature, material of container and contact surface with oxygen are key dominant factors accelerating oxidation deterioration. In this study, we chose temperature among key oxidation conditions and metal container filled with biodiesel was heated at about $110^{\circ}C$ for 10 days in order to accelerate oxidation deterioration. To better understand the effect of biodiesel blends on emission, steady state tests were conducted on a heavy duty diesel engine. The engine was fueled with Ultra Low Sulphur Diesel(ULSD), a blend of 10% and 20%(BD10, BD20) on volumetric basis, equipped with a common rail direct injection system and turbocharger, lives up to the requirements of EURO 3. The experimental results show that the blend fuel of normal biodiesel with BD10 and BD20 increased NOx. The result of PM was similar to diesel fuel on BD10, but the result of PM on BD20 was increased about 63% more than its of diesel. The blend fuel of Oxidation biodiesel with BD10 and BD20 increased NOx as the results of normal biodiesel. But PM was all increased on BD10 and BD20. Especially THC was extremely increased when test fuel contains biodiesel about 140% more than its of diesel. Through this study, we knew that oxidation deterioration of biodiesel affects emission of diesel engine.

• 동력기계공학회지
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• 제13권6호
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• pp.29-34
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• 2009

Recently, we have a lot interest in a sudden rise of oil prices and a change weather for the earth warmming, so, development of new alternative fuels need in order to spare fossil fuel and reduce exhaust emissions for air pollution prevention. Biodiesel, which can be generated from natural renewable sources such as new or used vegetable oils or animal fats, may be used as fuel in diesel engine of compression ignition engine. In this paper, the combustion characteristics between neat diesel oil and biodiesel blends(10 vol.% biodiesel and 20 vol.% biodiesel) were tested using four stroke, direct injection diesel engine, especially this biodiesel was produced from soybean oil at our laboratory. This analysis showed that cylinder pressures, the rate of pressure rises and the rate of heat releases were decreased as the blending ratios of biodiesel to diesel oil increased because of lower heating value of biodiesel in spite of increased oxygen content in biodiesel.

• Journal of Advanced Marine Engineering and Technology
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• 제32권1호
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• pp.27-32
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• 2008

Recently, we have a lot of interest in alternative fuels to provide energy independence from oil producing country and to reduce exhaust emissions for air pollution prevention. Biodiesel, which can be generated from natural renewable sources such as new or used vegetable oils or animal fats, may be used as fuel in diesel engine of compression ignition engine. In this paper, the test results on specific fuel consumption and exhaust emissions of neat diesel oil and biodiesel blends(10 vol.% biodiesel and 20 vol.% biodiesel) were presented using four stroke, direct injection diesel engine, especially this biodisel was produced from soybean oil at our laboratory. This study showed that Soot and CO emission were decreased as the blending ratios of biodiesel to diesel oil increased, on the other hand NOx emission was slightly increased because of the oxygen content in biodiesel. Also, the biodiesel blends yielded slightly higher specific fuel consumption than that of diesel oil because of lower heating value of biodiesel.

• 한국자동차공학회논문집
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• 제15권6호
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• pp.81-86
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• 2007

Biodiesel fuel that consists of saturated and unsaturated long-chain fatty acid alkyl esters is an alternative diesel fuel produced from vegetable oils or animal fats. However, air causes autoxidation of biodiesel fuel during storage, which can reduce fuel quality by adversely affecting its properties, such as the kinematic viscosity and acid value. One approach for improving the resistance of fatty derivatives to autoxidation is to mix them with antioxidants. This study investigated the effectiveness of five such antioxidants in mixtures with biodiesel fuels produced by three biodiesel manufacturers : tert-butylhydroquinone (TBHQ), butylated hydroxyanisole (BHA), butylated hydroxytoluene (BHT), propyl gallate (PrG) and $\alpha$-tocopherol. Oxidation stability was determined using Rancimat equipment. The results show that TBHQ, BHA, and BHT were the most effective and $\alpha$-tocopherol was the least effective at increasing the oxidation stability of biodiesel. This study recommends that TBHQ and PrG be used for safeguarding biodiesel fuel from the effects of autoxidation during storage.