• 제목/요약/키워드: zero-order solution

검색결과 181건 처리시간 0.027초

모든 3차 수차를 제거하여 얻은 극자외선 Lithography용 4-반사경 Holosymmetric System(배율=1) (Holosymmetric 4-Mirror Optical System(Unit Maginification) for Deep Ultraviolet Lithography Obtained from the Exact Solution of All Zero Third Order Aberrations)

  • 조영민
    • 한국광학회지
    • /
    • 제4권3호
    • /
    • pp.252-259
    • /
    • 1993
  • 극자외선 과장을 사용하는 micro-lithography를 위해 등배율을 갖는 4-반사경 holosymmetric system을 설계하였다. Holosymmetric system에서는 모든 차수의 코마와 왜곡수차가 영이 된다. 이 원리를 4-구명경계에 적용하여 등배율을 갖고 5개의 3차 수차가 모두 제거된 4-구면 반사경 holosymmetric system에 대해 유일한 해를 완전히 해석적인 표현으로 구하였다. 이 4-구면경계에 남아있는 고차 수차들을 보정하기 위해 holosymmetric 성질을 유지하면서 비구면을 채용하였고 그결과 개구수 0.33과 image field diameter 7.6mm 이내에서 극자외선 파장 $0.248{\mu}m$(KrF 엑시머 레이저 빔)에 대해 거의 회절한계의 수차성능을 갖는 비구면 4-반사경 holosymmetric system를 얻었다.

  • PDF

영가철 및 개질 영가철을 이용한 triclosan의 환원분해 특성 (Reduction Characteristics of Triclosan using Zero-valent Iron and Modified Zero-valent Iron)

  • 최정학;김영훈
    • 한국환경과학회지
    • /
    • 제26권7호
    • /
    • pp.859-868
    • /
    • 2017
  • In this study, the reductive dechlorination of triclosan using zero-valent iron (ZVI, $Fe^0$) and modified zero-valent iron (i.e., acid-washed iron (Aw/Fe) and palladium-coated iron (Pd/Fe)) was experimentally investigated, and the reduction characteristics were evaluated by analyzing the reaction kinetics. Triclosan could be reductively decomposed using zero-valent iron. The degradation rates of triclosan were about 50% and 67% when $Fe^0$ and Aw/Fe were used as reductants, respectively, after 8 h of reaction. For the Pd/Fe system, the degradation rate was about 57% after 1 h of reaction. Thus, Pd/Fe exhibited remarkable performance in the reductive degradation of triclosan. Several dechlorinated intermediates were predicted by GC-MS spectrum, and 2-phenoxyphenol was detected as the by-product of the decomposition reaction of triclosan, indicating that reductive dechlorination occurred continuously. As the reaction proceeded, the pH of the solution increased steadily; the pH increase for the Pd/Fe system was smaller than that for the $Fe^0$ and Aw/Fe system. Further, zero-order, first-order, and second-order kinetic models were used to analyze the reaction kinetics. The first-order kinetic model was found to be the best with good correlation for the $Fe^0$ and Aw/Fe system. However, for the Pd/Fe system, the experimental data were evaluated to be well fitted to the second-order kinetic model. The reaction rate constants (k) were in the order of Pd/Fe > Aw/Fe > $Fe^0$, with the rate constant of Pd/Fe being much higher than that of the other two reductants.

Innovative Remediation of Arsenic in Groundwater by Nano Scale Zero-Valent Iron

  • Kanel, Sushil-Raj;Kim, Ju-Yong;Park, Heechul
    • 한국지하수토양환경학회:학술대회논문집
    • /
    • 한국지하수토양환경학회 2003년도 추계학술발표회
    • /
    • pp.87-90
    • /
    • 2003
  • This research examines the feasibility of using laboratory-synthesized nano scale zero-valent iron particles to remove arsenic from aqueous phase. Batch experiments were performed to determine arsenic sorption rates as a function of the nano scale zero-valent iron solution concentration. Rapid adsorption of arsenic was achieved with the nano scale zero-valent iron. Typically 1 mg $L^{-1}$ arsenic (III) was adsorbed by 5 g $L^{-1}$ nano scale zero-valent iron below the 0.01 g $L^{-1}$ concentration within 7min. The kinetics of the arsenic sorption followed pseudo-first-order reaction kinetics. Observed reaction rate constants ( $K_{obs}$) varied between 11.4 to 129.0 $h^{-1}$ with respect to different concentrations of nano scale zero-valent iron. A variety of analytical techniques were used to study the reaction products including HGAAS (hydride generator atomic adsorption spectrophotometer), SEM (scanning electron microscopy) and TEM (transmission electron microscopy). Our experimental results suggest novel method for efficient removal of arsenic Iron groundwater.r.

  • PDF

Created cavity expansion solution in anisotropic and drained condition based on Cam-Clay model

  • Li, Chao;Zoua, Jin-Feng
    • Geomechanics and Engineering
    • /
    • 제19권2호
    • /
    • pp.141-151
    • /
    • 2019
  • A novel theoretical solution is presented for created (zero initial radius) cavity expansion problem based on CamClay model and considers the effect of initial anisotropic in-situ stress and drained conditions. Here the strain of this theoretical solution is small deformation in elastic region and large deformation in plastic region. The works for cylindrical and spherical cavities expanding in drained condition from zero initial radius are investigated. Most of the conventional solutions were based on the isotropic and undrained condition, however, the initial stress state of natural soil mass is anisotropy by soil deposition history, and drained cavity expansion calculation is closer to actual engineering in permeable soil mass. Finally, the parametric study is presented in order to the engineering significance of this work.

Bifurcations of non-semi-simple eigenvalues and the zero-order approximations of responses at critical points of Hopf bifurcation in nonlinear systems

  • Chen, Yu Dong;Pei, Chun Yan;Chen, Su Huan
    • Structural Engineering and Mechanics
    • /
    • 제40권3호
    • /
    • pp.335-346
    • /
    • 2011
  • This paper deals with the bifurcations of non-semi-simple eigenvalues at critical point of Hopf bifurcation to understand the dynamic behavior of the system. By using the Puiseux expansion, the expression of the bifurcation of non-semi-simple eigenvalues and the corresponding topological structure in the parameter space are obtained. The zero-order approximate solutions in the vicinity of the critical points at which the multiple Hopf bifurcation may occur are developed. A numerical example, the flutter problem of an airfoil in simplified model, is given to illustrate the application of the proposed method.

Optimisation of a novel trailing edge concept for a high lift device

  • Botha, Jason D.M.;Dala, Laurent;Schaber, S.
    • Advances in aircraft and spacecraft science
    • /
    • 제2권3호
    • /
    • pp.329-343
    • /
    • 2015
  • This study aimed to observe the effect of a novel concept (referred to as the flap extension) implemented on the leading edge of the flap of a three element high lift device. The high lift device, consisting of a flap, main element and slat is designed around an Airbus research profile for sufficient take off and landing performance of a large commercial aircraft. The concept is realised on the profile and numerically optimised to achieve an optimum geometry. Two different optimisation approaches based on Genetic Algorithm optimisations are used: a zero order approach which makes simplifying assumptions to achieve an optimised solution: as well as a direct approach which employs an optimisation in ANSYS DesignXplorer using RANS calculations. Both methods converge to different optimised solutions due to simplifying assumptions. The solution to the zero order optimisation showed a decreased stall angle and decreased maximum lift coefficient against angle of attack due to early stall onset at the flap. The DesignXplorer optimised solution matched that of the baseline solution very closely. The concept was seen to increase lift locally at the flap for both optimisation methods.

A Study on the Generation of Capillary Waves on Steep Gravity Waves

  • Lee, Seung-Joon
    • Journal of Ship and Ocean Technology
    • /
    • 제4권4호
    • /
    • pp.45-55
    • /
    • 2000
  • A formal solution method using the complex analysis is given for the problems derived by Longuet-Higgins(1963). The same method is applied to a new perturbation problem of higher approximation. Interpretation of its solution made it possible to confirm that the rough agree-ment of Longuet-Higgins\`s prediction with experimental data of Cox(1958) was mainly due to the fact that the gravity effect in the perturbation problem was neglected for the case when the basic gravity wave not sufficiently steep.

  • PDF

금속 철을 이용한 TNT 환원시의 동역학 산정 (Kinetics of 2, 4, 6-Trinitrotoluene reduction by zero valent iron)

  • 배범한
    • 한국토양환경학회지
    • /
    • 제4권1호
    • /
    • pp.97-108
    • /
    • 1999
  • 금속 철(Fe$^{0}$ )에 의한 TNT의 환원실험을 회분식 반응조를 사용하여 환원 상태에서 연구하였다. 실험 결과, 환원에 의한 TNT의 농도감소는 유사 1차 반응으로 나타났고 반응상수는 반응조에 첨가한 철의 표면적에 선형적으로 비례하였으며, 교반 속도 60 rpm에서의 반응상수는 0.0981$min^{-1}$m$^{-2}$ L로 측정되었다. Triaminotoluene로 추정되는 최종산물이 용액내에 축적되었다. 철 표면에 흡착된 물질을 용출하기 위하여 acetonitrile혹은 물(인산염 완충액, pH=7.0)로 추출을 시도하였으나 용출되는 물질은 극히 미량이었다. 또한, 용액 내에서 생물학적 분해에서의 주요 중간산물인 aminodinitrotoluenes은 검출되지 않았다. 그러므로, 철에 의한 TNT의 환원시 니트로기의 환원이 순차적으로 발생하여 아미노기를 형성하지 않고, 3개의 니트로기에 대하여 동시에 발생하는 것으로 사료된다. 이에 TNT의 환원 모델을 제시하였다.

  • PDF