• The Korean Journal of Mycology
• /
• v.11 no.3
• /
• pp.115-119
• /
• 1983

The bioconversion of progesterone by Aspergillus phoenicis has been studied. The metabolism in the conditions of experiment gave $11{\alpha}-hydroxyprogesterone$ as main product. The concentration of $11{\alpha}-hydroxyprogesterone$ increased monotonically and leveled off after 40 hours of incubation. Addition of glucose into the medium reduced considerably the time for attaining limiting concentration of $11{\alpha}-hydroxyprogesterone$. The increase in initial progesterone concentration did not affected the percentage of conversion nor the time required for termination of the reaction. But it could not be represented as first order reaction with respect to progesterone concentration. The degree of inhibition of enzymes by organic solvents depended upon the concentration of solvents. At low solvent concentration, acetone proved to yield the highest conversion.

• Macromolecular Research
• /
• v.12 no.5
• /
• pp.519-527
• /
• 2004

Stable poly(methyl methacrylate-co-divinylbenzene) (poly(MMA-co-DVB)) microspheres were prepared by precipitation polymerization using acetonitrile as the main medium under various polymerization conditions, including modifications of the agitation speed, monomer and initiator concentrations, DVB content in the monomer mixture, and the use of various cosolvents. Gentle agitation was required to obtain smooth spherical particles. The individually stable microspheres were obtained at monomer concentrations of up to 15 vol% in an acetonitrile medium. The number-average diameter increased linearly with respect to increases in the monomer and initiator concentrations. We found, however, that the uniformity of the microspheres was independent of the variation of the polymerization ingredients because nuclei formation was solely influenced by the crosslinking reaction of the monomers. We obtained higher yields for the polymerization at higher concentrations of monomer and initiator. The concentration of DVB in the monomer mixture composition played an important role in determining not only the size of the microspheres but also the yield of the polymerization. In addition, although we employed various cosolvents as the polymerization medium, we found that acetonitrile/2-methoxyethanol was the only system that provided spherical particles without coagulation. This finding indicates that the precipitation polymerization is strongly dependent on the solvent used as the medium.

• Transactions of Materials Processing
• /
• v.27 no.1
• /
• pp.12-17
• /
• 2018

This paper outlines the research findings on the microstructure and mechanical properties of AZ31 Mg alloy fabricated by differential speed rolling (DSR) with respect to processing variables such as temperature, roll speed ratio (RSR), and deformation route. The resultant microstructure of the sample, deformed by 2-pass DSRs at 473 K, comprised finer grains with more uniform distribution than those at 573 and 623 K. This was due to active recrystallization, which was expected to appear during DSR at temperatures higher than 573 K. When the sample was deformed via DSR with RSR of 1:4 for the upper and lower rolls at 453 K, the values of yield and ultimate tensile strength were observed to be higher than their counterpart with RSR of 1:1. The application of sample rotation around the longitudinal axis would give rise to an excellent combination of tension strength (~330 MPa) and ductility (~20 %) at ambient temperatures. This is discussed based on its uniform fine grained structure and the softening of basal texture.

• Journal of Korean Society on Water Environment
• /
• v.30 no.2
• /
• pp.159-165
• /
• 2014

Vegetative Filter Strip (VFS) is one of effective Best Management Practices (BMPs) to prevent sediment-laden water problem, is installed at the edge of source area such agricultural area so that sediment occurred in source area is trapped by VFS before it flow into stream or river. Appropriate scale of it needs to be simulated before it is installed, considering various field conditions. In this study, a model using VFSMOD-w model and Genetic Algorithm to determine effective VFS length was developed, it is available to calibrate input parameter related to source area sediment yield through thousands of VFSMOD-w simulations. Useful DBs, moreover, are stored in the model so that very specific input parameters can be used with reasonable values. Compared simulated values to observed data values for calibration, R2 and Nash-Stucliffe model efficiency coefficient were 0.74 and 0.65 in flow comparison, and 0.89 and 0.79 in sediment comparison. The model determined 1.0 m of Filter Length, 0.18 of Filter Slope, and 0.2 cm of Filter Media Spacing to reduce 80% of sediment by VFS. The model has not only Auto-Calibration module also DBs for specific input parameters, thus, the model is expected to be used for effective VFS scale.

• Transactions of the Korean Society of Mechanical Engineers
• /
• v.12 no.1
• /
• pp.137-151
• /
• 1988

Thurbulent thermal convection between two plates, bottom plate is at higher temperature $T_{h}$ and the upper plate is at lower temperature $T_{i}$ is numerically investigated. Model equations are abridged Reynolds stress equations; full Reynolds stress equations are simplified to yield algebraic relations in case of mean square velocity fluctuations in vertical and horizontal directions. Boundary conditions for turbulent kinetic energy k and mean square temperature variance .thera.$^{2}$oner bar at the plate surfaces are set to be zero and those of dissipation rate of turbulent kinetic energy .epsilon. and dissipation rate of mean square temperature variance .epsilon.$_{\theta}$ are assumed at first grid point nearest to the boundary surfaces, whose values are approximated by inviscid estimates. Results show that temperature profiles are in good agreement with experimental data except transition region, in which temperature is over-predicted. Such discrepancy becomes larger as the Rayleigh number becomes smaller. Nusselt numbers, which are calculated from the temperature gradients at the boundary surfaces, are also in good agreement with experimental data.a.a.

• Journal of Microbiology and Biotechnology
• /
• v.6 no.1
• /
• pp.30-35
• /
• 1996

Distillery wastewater was used in a thermophilic laboratory-scale two stage anaerobic digester to test the effects of the redox potential of the first acidogenic reactor on the performance of the system. The digester consisted of first a acidogenic reactor and the an upflow anaerobic sludge blanket (UASB) reactor. The digestor was operated at a hydraulic retention time (HRT) of 48 h. Under these conditions, about 90% of the chemical oxygen demand as measured by the chromate method ($COD_{cr}$) was removed with a gas production yield of 0.4 l/g-COD removed. The redox potential of the acidogenic reactor was increased when the reactor was purged with nitrogen gas or agitation speed was increased. The increase in reduction potential was accompanied by an increase in acetate production and a decrease in butyrate formation. A similar trend was observed when a small amount of air was introduced into the acidogenic reactor. It is believed that the hydrogen partial pressure in the acidogenic reactor was decreased by the above mentioned treatments. The possible failure of anaerobic digestion processes due to over-loading could be avoided by the above mentioned treatments.

• Transactions of the Korean Society of Pressure Vessels and Piping
• /
• v.13 no.1
• /
• pp.54-60
• /
• 2017

When a sudden rupture occurs in high energy lines, ejection of inner fluid with high temperature and pressure causes blast wave as well as thrust forces on the ruptured pipe itself. The present study is to examine pipe whip behaviors and blast wave phenomena under postulated pipe break conditions. In this context, typical numerical models were generated by taking a MSL (Main Steam Line) piping, a steam generator and containment building. Subsequently, numerical analyses were carried out by changing break locations; one is pipe whip analyses to assess displacements and stresses of the broken pipe due to the thrust force. The other is blast wave analyses to evaluate the broken pipe due to the blast wave by considering the pipe whip. As a result, the stress value of the steam generator increased by about 7~21% and von Mises stress of steam generator outlet nozzle exceeded the yield strength of the material. In the displacement results, rapid movement of pipe occurred at 0.1 sec due to the blast wave, and the maximum displacement increased by about 2~9%.

• Journal of Applied Biological Chemistry
• /
• v.59 no.4
• /
• pp.289-298
• /
• 2016

FK506 hyper-yielding mutant, called the TCM8594 strain, was made from Streptomyces tsukubaensis NRRL 18488 by mutagenesis using N-methyl-N'-nitro-N-nitrosoguanidine, ultraviolet irradiation, and FK506 sequential resistance selection. FK506 production by the TCM8594 strain improved 45.1-fold ($505.4{\mu}g/mL$) compared to that of S. tsukubaensis NRRL 18488 ($11.2{\mu}g/mL$). Among the five substrates, wheat bran was selected as the best solid substrate to produce optimum quantities of FK506 ($382.7{\mu}g/g$ substrate) under solid-state fermentation, and the process parameters affecting FK506 production were optimized. Maximum FK506 yield ($897.4{\mu}g/g$ substrate) was achieved by optimizing process parameters, such as wheat bran with 5 % (w/w) dextrin and yeast extract as additional nutrients, 70 % (v/w) initial solid substrate moisture content, initial medium pH of 7.2, $30^{\circ}C$ incubation temperature, inoculum level that was 10 % (v/w) of the cell mass equivalent, and a 10 day incubation. The results showed an overall 234 % increase in FK506 production after optimizing the process parameters.

• Environmental Engineering Research
• /
• v.17 no.2
• /
• pp.89-94
• /
• 2012

Pyrolysis/gasification technology utilizes an energy conversion technique from various waste resources, such as biomass, solid waste, sewage sludge, and etc. to generating a syngas (synthesis gas). However, one of the major problems for the pyrolysis gasification is the presence of tar in the product gas. The tar produced might cause damages and operating problems on the facility. In this study, a gliding arc plasma reformer was developed to solve the previously acknowledged issues. An experiment was conducted using surrogate benzene and naphthalene, which are generated during the pyrolysis and/or gasification, as the representative tar substance. To identify the characteristics of the influential parameters of tar decomposition, tests were performed on the steam feed amount (steam/carbon ratio), input discharge power (specific energy input, SEI), total feed gas amount and the input tar concentration. In benzene, the optimal operating conditions of the gliding arc plasma 2 in steam to carbon (S/C) ratio, 0.98 $kWh/m^3$ in SEI, 14 L/min in total gas feed rate and 3.6% in benzene concentration. In naphthalene, 2.5 in S/C ratio, 1 $kWh/m^3$ in SEI, 18.4 L/min in total gas feed rate and 1% in naphthalene concentration. The benzene decomposition efficiency was 95%, and the energy efficiency was 120 g/kWh. The naphthalene decomposition efficiency was 79%, and the energy yield was 68 g/kWh.

• Environmental Engineering Research
• /
• v.21 no.1
• /
• pp.22-28
• /
• 2016

The aim of this study was to recycle the waste livestock blood as one of the waste biomass by turning proteins, the main constituent of blood, into effective biological resources like amino acid. Ultrasonic technology was applied to solubilize the proteins in the waste livestock blood. And of the multiple ultrasonic frequencies tested, 20 kHz was confirmed to yield the highest solubilization rate. The optimum pretreatment conditions were determined to be 30-min treatment at an ultrasonic irradiation density of 0.5 W/mL, which resulted in a solubilization rate of 96.01%. Also, a gel permeation chromatography (GPC) confirmed that a large amount of proteins were solubilized, and in an experiment where ultrasonic treatment was applied to kill bacteria, death rates of general bacteria and total coliforms were found to be reduced by 99.93% and 100%, respectively. Based on these results, ultrasonic technology was confirmed to be a crucial part of treating and recycling the proteins in waste livestock blood.