• Title/Summary/Keyword: yield conditions

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Studies on the One Bath Exhaust Dyeing System of Polyester/Cationized Cotton Blends with Disperse Dye/Reactive Dye (폴리에스테르/카티온화 면 혼방품의 분산염료/반응성염료에 의한 일욕염색계에 관한 연구)

  • 성우경
    • Textile Coloration and Finishing
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    • v.10 no.2
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    • pp.18-28
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    • 1998
  • in order to overcome disadvantage of the conventional two bath dyeing method of polyester/cotton blends, it had prompted significant effort to the development of the one bath dyeing method which can accomplish sayings in time, energy and water usage. Also, when dyeing polyester/cotton blends by the one bath dyeing method, the high salt concentrations needed for the reactive dye can cause particles of disperse dye, used for the polyester component, to aggregate. A supplementary problem that can occasionally be happened is the change of hue that occurs on dyed polyester in an alkaline dyebath. To improve dyeing property of polyester/cotton blends, cotton component was pretreated with epichlolohydrine-trimethylamine hydrochloride in aqueous solution of sodium hydroxide to produce a cationized cotton that can be dyed under neutral conditions with reactive dye in a non-electrolytic or il little electrolytic dyebath. The one bath dyeing method of polyester/cationized cotton blends with disperse dye/reactive dye mixture resulted in a satisfactory dyeing property and color yield in comparison with ordinary two bath dyeing method.

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SPECTRAL AND PROTOPHYSICAL PROPERTIES OF 1-PYRAZINYL-2-(3- QUINOLINYL)ETHYLENE

  • Bong, Pill-Hoon;Ryoo, Jae-Hwan
    • Journal of Photoscience
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    • v.6 no.4
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    • pp.171-176
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    • 1999
  • The spectral and photophysical properties of trans-1-pyrazinyl-2-(3-quinolinyl)ethylene (trans-3- PyQE) are investigated under various conditions in order to obtain information on ground and excited states. The absorption spectrum of trans-3-PyQE changes slightly with varying degree of solvent polarity ; the. fluorescence spectrum is shifted to the red and becomes broad and structureless as the solvent polarity increases. The fluorescence quantum yield increases with increasing solvent polarity. The fluorescence intensity of trans-3-PyQE decreases as the concentration of methyl iodide increases. The fluorescence spectra of trans-3-PyQE changes markedly upon the variation of the excitation wavelength, presumably due to an equilibrium between conformers originating from the rotation of a quasi-single bond between the quinolinyl group and ethylenic carbon atom. These results indicate that the spectral and photophysical properties of trans-3-PyQE are strongly influenced by solvent, heavy atom, and an equilibrium between conformers

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Analysis of wrinkling formation of anisotropic sheet metal (이방성 판재의 주름 발생 해석)

  • 손영진;박기철;김영석
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 1998.03a
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    • pp.21-27
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    • 1998
  • An analysis for the prediction of wrinkling formation in curved sheets during metal froming is presented. We construct "Wrinkling Limit diagram"(WLD) which represent the combinations of the critical principal stresses for wrinkling formation in curved sheet elements subjected to biaxial plane stress. Here the scheme of plastic bifurcation theory for thin shells based on the Donnell-Mushtari-Vlasov shell theory is used. In this study, the effects of the material variables (yield stress, plastic hardening coefficient, plastic anisotropic parameter, and so on) and sheet geometry on the critical conditions for wrinkling is carried out numerically.merically.

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Application of Ultrasounds for the Removal of Chlorobenzene and Chlorinated Phenols in Water (Chlorobenzene 및 Chlorinated Phenol류의 분해에 미치는 초음파의 응용)

  • 우영억;황규탁
    • Journal of environmental and Sanitary engineering
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    • v.15 no.4
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    • pp.35-43
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    • 2000
  • Aqueous solutions of chlorobenzene and chlorinated phenols were exposed to 200kHz ultrasound with a power of $6.0W/\textrm{cm}^2$ per unit volume on sonochemical reactor under ambient temperature and pressure conditions. The concentration of chlorobenzene and chlorinated phenols decreased with ultrasound, indicating first-order kinetics. Degradation rate constants are calculated from the slope of plots. The order of the rate constants is as follows : 2-chlorphenol(2-CP)$\leq$ 4-chlorophenol(4-CP)<3-chlorophenol(3-CP)$5.63~9.96({\times}10^{-2})min^{-1}$ under argon. The degradation was suppressed by the addition of t-BuOH and the suppressed yield was agreed with their reactivity for hydroxy radical. The main products of these systems were formic acid, acetic acid, small amount of methane and inorganic carbon forms as carbon dioxide, carbon monoxide in sonolysis of chlorinated phenols, and also these results agreed with change of TOC.

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A Study on the Treatment of Distillery Wastewater by Single-phase and Two-phase Anaerobic Digestion (단상(單相) 및 2상(相) 혐기성(嫌氣性) 소화(消化)에 의한 주정폐수(酒精廢水) 처리(處理)에 관한 연구(硏究))

  • Choung, Young Kyoo;Rah, Seung Woo;Park, Joon Hwan
    • Journal of Korean Society of Water and Wastewater
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    • v.7 no.1
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    • pp.5-12
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    • 1993
  • The objectives of this paper are to present data to illustrate how an advanced digestion process, two-phase digestion, can provide superior performance in terms of waste stabilization efficiency and net energy recovery. As the result, it is possible to separate enrichment cultures of acidogenic and methanogenic organisms in isolated environments by kinetic control involving manipulation of dilution rates. In single-phase digestion process, HRT and COD loading for effective operation were 14.29 days and 2.33kg $COD/m^3$ day, but two-phase digestion may be conducted efficiently at 7 days of HRT and 5.71kg $COD/m^3$ day of loading. Data from this studies showed that the two-phase process is better than single-phase digestion under all test conditions when compared on the bases of gas yield and production rate, reductions of COD and VS, buffer capacity, and unconverted volatile acids in the effluent.

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Delignification Kinetics of Trema orientalis (Nalita) in Kraft Pulping

  • Jahan, M. Sarwar;Rubaiyat, A.;Sabina, R.
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.39 no.5
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    • pp.7-11
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    • 2007
  • Kraft pulping of Trema orientalis (Nalita) was studied in order to find kinetic data for delignification. Pulping runs were carried out in the temperature range of $160-180\;^{\circ}C$ under constant and well-defined conditions. The delignification was found to be first order with respect to residual lignin and was chemically controlled. The rate of delignification reaction was increased 1.11-1.23 for $10\;^{\circ}C$ temperature increase in the range of $160-180\;^{\circ}C$ range. A mean value of 93% of lignin was removed at the transition between bulk and residual delignification. The influence of cooking temperature on the rate constant was expressed by an Arrhenius-type equation. The obtained activation energy of the delignification reaction was 6,164 cal/mol. The transition point between bulk and residual phase was shifted to lower lignin and carbohydrate yield with the increase of temperature.

Control of Slurry Flow Rate in Copper CMP (구리 CMP시 슬러리 Flow Rate의 조절)

  • Kim, Tae-Gun;Kim, Nam-Hoon;Kim, Sang-Yong;Seo, Yong-Jin;Chang, Eui-Goo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.04b
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    • pp.34-37
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    • 2004
  • Recently advancing mobile communication tools and I.T industry, semiconductor device is requested more integrated, faster operation time and more scaled-down. Because of these reasons semiconductor device is requested multilayer interconnection. For the multilayer interconnection chemical mechanical polishing (CMP) becomes one of the most useful process in semiconductor manufacturing process. In this experiment, we focus on understand the characterize and improve the CMP technology by control of slurry flow rate. Consequently, we obtain that optimal flow rate of slurry is 170ml/min, since optimal conditions are less chemical flow and performance high with good selectivity to Ta. If we apply this results to copper CMP process. it is thought that we will be able to obtain better yield.

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A Study on the Fatigue Crack Propagation Behavior by the Variation of Heat Treatment Temperature and Thickness in ATOS 55 Steel (ATOS 55강의 열처리 온도와 두께 변화에 따른 피로균열성장거동에 관한 연구)

  • 오환교
    • Journal of the Korean Society of Safety
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    • v.12 no.4
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    • pp.15-20
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    • 1997
  • This study is to investigate the behavior of fatigue crack growth with ATOS 55 steel which can be applied to the commercial car Dump Frame. It is to obtain the material coefficients after tensile and fatigue crack growth test with the variation of thickness or heat treatment. Also, that is proved the Pari's law by experiment. The summarized results are as follows ; 1) Increasing thickness, tensile and yield strength measured highly regardless to heat treatment and measured lowly as variation of heat treatment temperature. 2) Specimen of thickness 8.0㎜ measured the faster of crack growth rate than another thickness according to the results of experiment. It was the different of stress conditions in crack tip. 3) It was found that the experimental constant m was range of 2∼5 to the relationship between fatigue crack growth rate and stress intensity factor range. Also, it was to prove the Paris's law by the experiment.

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The Characteristics of Ozone Generation for Dielectric Barrier Discharge with Discharge Area variation (방전면적에 따른 유전체장벽 방전에 의한 오존생성 특성)

  • Lee, Chang-Ho;Park, Soong-Gyu;Kim, Jong-Hyun;Lee, Hyun-Chul;Song, Hyun-Jig;Lee, Sang-Keun;Park, Won-Zoo;Lee, Kwang-Sik
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2008.05a
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    • pp.379-380
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    • 2008
  • Recently, ozone is utilized in various fields and its needs are expanding. In this paper, glass and ceramic plate tyre ozonizer have been fabricated to investigate discharge parameter(input power, flow rate of supplied gas, electrode form, etc.) effect to discharge. And the conditions of discharge parameter have been investigated for optimum ozone generation. Ozone concentration is continuously increased with increasing input power for same discharge space, and ozone yield is also increased until maximum point after that it is saturated. Ozone concentration is inversely proportional to flow rate of supplied gas but ozone generation and ozone vield characteristics are improved.

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Performance Optimization of Hypervelocity Launcher System using Experimental Data

  • Huh, Choul-Jun;Lee, Jin-Ho;Bae, Ki-Joon;Jeon, Kwon-Su;Byun, Yung-Hwan;Lee, Jae-Woo;Lee, Chang-Jin
    • Journal of Mechanical Science and Technology
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    • v.18 no.10
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    • pp.1829-1836
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    • 2004
  • This study presents the performance optimization of hypervelocity launcher system by using the experimentall data. During the optimization, the RSM (Response Surface Method) is adopted to find the operating parameters that could maximize the projectile speed. To construct a reliable response surface model, 3 full factorial method is used with the selected design variables, such as piston mass and 2 driver fill pressure. Nine test data could successfully construct the reasonable response surface, which used to yield the optimal operational conditions of the system using the genetic algorithm. The optimization results are confirmed by the experimental test with a good accuracy. Thus, the optimization can improve the performance of the facility.