Journal of environmental and Sanitary engineering (환경위생공학)

Korean Society for Environmental Sanitary Engineers (대한환경위생공학회)
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Application of Ultrasounds for the Removal of Chlorobenzene and Chlorinated Phenols in Water

Chlorobenzene 및 Chlorinated Phenol류의 분해에 미치는 초음파의 응용

  • 우영억 (대구대학교 환경교육과) ;
  • 황규탁 (대구대학교 환경교육과)
  • Published : 2000.12.01
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Abstract

Aqueous solutions of chlorobenzene and chlorinated phenols were exposed to 200kHz ultrasound with a power of $6.0W/\textrm{cm}^2$ per unit volume on sonochemical reactor under ambient temperature and pressure conditions. The concentration of chlorobenzene and chlorinated phenols decreased with ultrasound, indicating first-order kinetics. Degradation rate constants are calculated from the slope of plots. The order of the rate constants is as follows : 2-chlorphenol(2-CP)$\leq$ 4-chlorophenol(4-CP)<3-chlorophenol(3-CP)$5.63~9.96({\times}10^{-2})min^{-1}$ under argon. The degradation was suppressed by the addition of t-BuOH and the suppressed yield was agreed with their reactivity for hydroxy radical. The main products of these systems were formic acid, acetic acid, small amount of methane and inorganic carbon forms as carbon dioxide, carbon monoxide in sonolysis of chlorinated phenols, and also these results agreed with change of TOC.

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