• Title/Summary/Keyword: yield conditions

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Photoaddtion Reactions of ο-Benzoquinones to Some Olefins and Alkynes

  • Kim, Sung-Sik
    • Journal of Photoscience
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    • v.5 no.4
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    • pp.143-148
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    • 1998
  • Photoaddition reactions of ο-benzoquinones to some organic molecules were ivestigated to yield three types of photoadducts. Irradiation (350nm UV light) of a dichloromethane solution of tetrahal-1, 2- benzoquinones and 1, 4-diphenylbutadiene yielded 1, 3-dienes, which was found to be used to synthesize 1-phenylphenanthrenes. The 1, 3-dienes were also produced, when irradiated tetrahalo--1, 2-benzoquinones and 1,4-dipenylbut-1-en-3-yne in the similar conditions, which was applied to get 9-phenylphenanthrenes. An enolic compound come from the tautomerization of dibenzoylmethane was found to add to ο-benzoquinones to give, 1, 4-dioxenes and 1, 5-diketones as the major products. Although depenylbutadiyne did not add to ο-benzoquinones, diphenylacetylene added to ο-benzoquinones to give $\rho$-quinomethanes as well as two isomeric $\rho$-quinomethanes. One-way photoisomerism was observed for two isomeric $\rho$-quinomethanes.

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Coupled flexural and torsional vibration of channel beam (휨과 비틀림이 연계된 채널보의 진동)

  • 김상환
    • Journal of KSNVE
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    • v.5 no.3
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    • pp.327-335
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    • 1995
  • The study deals with the vibration of a beam whose flexural and centroidal axes are not coincident. The elementary bending-twisting theory is employed to derive the equation of motion, in which the effects of rotary inertia are added to the bending displacements and the effects of warping are added to the twist. Bending translation is restricted to one direction so that one bending equation is used instead of two. The equations of motion are solved by using the boundary value problem. The exact natural frequencies are fund from the frequency equation, which is obtained from the condition that the homogeneous system of algebraic equations representing the spatial solution shall not yield a trivial solution. The orthogonal conditions are established, and the principal mode equations of forced vibration are derived. As an example, the cantilevered beam is chosen and the first some natural frequencies and their modal shapes are found.

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A survey on Cocoon Quality Imported in 1983 (수입원료견의 견질조사)

  • 남중희
    • Journal of Sericultural and Entomological Science
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    • v.25 no.2
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    • pp.65-68
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    • 1984
  • This survey was to realize the foreign cocoon quality and to provide data for suitable reeling conditions. Cocoons were inported from Taiwan (7 packs) and Hongkong (12 packs) in 1983. The practical inspection and classiffication of above cocoon was performed at Provincial Institute of cocoon testing and tested data were collected to evaluate the cocoon quality. The results were as follows. 1. It showed higher variation of the average raw silk yield percentage and cocoon assorting rate than domestic cocoon. 2. In view of the low quality products, cocoon price was expensive and most of packs were evaluated as inferior grade. 3. It was supposed that importing the superior quality cocoon from foreign country may be contributed to manufacturing of silk commodity of higher grade.

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Resolution of L-Carnitine from DL-Carnitine by Resting Cells of the Enterobacter sp. NH-104

  • Hwang, Ki-Chul;Bang, Won-Gi
    • Journal of Microbiology and Biotechnology
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    • v.8 no.6
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    • pp.601-605
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    • 1998
  • For the resolution of L-carnitine from DL-carnitine, resting cells of Enterobacter sp. NH-104, which had a higher capacity of D-carnitine decomposition, were harvested at maximal specific activity of D-carnitine decomposition of 47.05 unit/mg cell. The cells were frozen at $-80^{\circ}C$ to assess functions as enzyme sources. Optimal concentration of cells and DL-carnitine were 17 g/$\ell \; and \; 20 g/\ell$, respectively, and reaction buffer was best at 75 mM of Tris. HCl. Optimal temperature and pH were $36^{\circ}C$ and 8.2, respectively. When the reaction at optimal conditions was carried out for 14 h, the optical purity was 98.21 %, and the quantity and yield of remaining L-carnitine were 4.432 g/$\ell$ and 44.32%, respectively.

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Development of Analytical Methods for Insect Moulting Hormone $({\beta}-Ecdysone)$ by HPLC/UV Using Boronate Derivatization

  • Shim, Jae-Han;Kim, In-Seon;Lim, Kye-Taek
    • Applied Biological Chemistry
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    • v.41 no.4
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    • pp.251-256
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    • 1998
  • The analytical method of ${\beta}-ecdysone$, the insect moulting hormone, by high performance liquid chromatograph (HPLC) with UV detector was developed using boronic ester derivatization and applied to the extracts of Ajuga iva, Silene otites and Schistocerca egg. Derivatization of yield with methyl-, butyl-, and phenyl-boronate was completed under mild conditions with 20-hydroxyecdysone. The conversion ratios of boronate were estimated to be 70% in methylboronic acid, 89% in butylboronic acid and 93% in phenylboronic acid. Phenylboronate showed a high sensitivity and demonstrated an effective separation on HPLC. The optimum temperature and reaction time for derivative formation were $25^{\circ}C$ and 20 min. respectively. ${\beta}-Ecdysone$ was effectively identified in extracts of Ajuga iva, Silene otites and Schistocerca egg by the HPLC method.

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Consideration of Techniques for Agricultural Water Demands Estimation (농업용수 수요량 예측기법 고찰)

  • Park, Jae-Heung;Lee, Yong-Jig
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 2002.10a
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    • pp.37-40
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    • 2002
  • It is to show the problems of the existing techniques to estimate agricultural water demand and to suggest the new methods considering the water demand for non-irrigated area and decrease of water loss in canal. It is to suggest the methods to improve the techniques for estimating agricultural water demand and to analyze the water demand and supply according to the facilities capacity. Until now, the concept of per the unit used to estimate agriculture water demand is useful to estimate demand, but is insufficient to cope with the variations of conditions in future. And the paddy area of government is not realistic against a trend of decrease. Water demand decrease is caused by constructions of irrigation facilities as constructing of irrigation canal, but application loss ratio is fixed. Increase of the water demand owing to the increase of the yield per the unit area is also the actual condition which is not considered. The guide-line must contain these contents for a demand estimate.

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Estimating and Analysis of Soil Loss from Upland Watershed Using WEPP Model (WEPP 모형을 이용한 밭유역의 토양 유실량 추정 및 분석)

  • Kang, Min-Goo;Park, Seung-Woo;Son, Jung-Ho;Kang, Moon-Sung
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 2002.10a
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    • pp.85-88
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    • 2002
  • This paper presents the result of the Water Erosion Prediction Project(WEPP) watershed scale model's application for prediction of sediment yield from a watershed which is comprised of hillslopes and channels and analyses of the soil loss from hillslopes and channels with crop practice and shape. To evaluate the model's application, the model is applied to a watershed that comprised of six hillslope and one channel, and the result was a good agreement with the observed values. The soil loss from hillslope was increased as the hills lope was under fallow conditions and slope length was longer. The soil loss from the channel was increased at the downstream for the concentration of flow.

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Laboratory Scale Preparation of S-Adenosyl-L-Methionine from Yeast (효모로부터 S-Adenosyl-L-Methionine의 실험실 규모 생산)

  • 이종남;류양욱;최명언
    • Microbiology and Biotechnology Letters
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    • v.19 no.6
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    • pp.588-591
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    • 1991
  • S-adenosyl-L-methionine (SAM) is essential substrate for biological methylation reactions. The present work describes a reoptimized procedure of SAM preparation in laboratory scale by the method of yeast fermentation. The fermentation medium enriched with methionine and the culture conditions were reoptimized. The isolation steps consisted of 5 steps including extractions, precipitations, and chromatography. This improved procedure over original method provides relatively high yield of biologically active product within a 4 day-period.

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Production of Cathepsin B Inhibitor by Steptomyces luteogriseus KT-10 (Streptomyces luteogriseus KT-10에 의한 Cathepsin B 저해물질의 발효생산)

  • 한길환;김상달
    • Microbiology and Biotechnology Letters
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    • v.27 no.6
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    • pp.458-465
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    • 1999
  • Streptomyces luteogriseus KT-10 isolated from Korean farm soil produced a strong cathepsin B inhibitor. Optimal conditions for the cathepsin B inhibitor production by s. luteogriseus KT-10 were evaluated. The cathepsin B inhibitor was produced with maximal yield in the cultural condition of pH 7.0 and $25^{\circ}C$ for 4 days. Optimal medium for the cathepsin B inhibitor production was determined to be a medium containing 20g, peptone 3g, yeast extract 1g, K2HPO4 0.5g, MgSO4.7H2O 0.5g, NaNO3 0.5g, NaCl 0.5g per l. The cathepsin B inhibitor produced by S. luteogriseus KT-10 could also inhibit the other proteinases such as trypsin, papain, and cathepsin D.

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Efficiency of methyl-esterified eggshell membrane biomaterials for intensified microalgae harvesting

  • Choi, Hee-Jeong
    • Environmental Engineering Research
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    • v.22 no.4
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    • pp.356-362
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    • 2017
  • This study investigates the use of methyl-esterified eggshell membranes (MESM) for the harvesting of microalgae species under various conditions. Eggshell membranes were esterified with HCl to impact polycationic characteristics. After methyl esterification, the negative surface charge property of eggshell membrane was changed from negative to positive for all pH values to improve microalgae sorption capacity. The harvesting efficiency of microalgae by MESM reached 78-99% for all pH ranges evaluated. In addition, a 150 mesh particle size and $10mg\;L^{-1}$ MESM dose were found to yield up to 98% microalgae harvesting. These results indicate that the high cationic charge of MESM strongly adsorbs the negatively-charged microalgae. MESM is biocompatible and can be applied to the harvest of microalgae.