• 자원리싸이클링
• /
• 제22권2호
• /
• pp.18-21
• /
• 2013

본 실험에서는 상압플라즈마에 의한 목분의 표면개질에 대해 조사하였다. 복합재는 목분과 폴리프로필렌을 이용하여 제작되었다(목분 : 폴리프로필렌=55wt% : 45wt%). 상압플라즈마는 carrier gas로 헬륨과 HMDSO를 모노머로 사용하였고 3 KV, $17{\pm}1$KHz, 2 g/min의 조건에서 처리하였다. 폐목분의 인장강도는 상압플라즈마 처리를 통해 18.5 MPa에서 21.2 MPa로 14.6% 증가하였고 단일수종목분의 경우에도 21.5 MPa에서 23.4 MPa로 8.8% 증가하였다. 이것으로 상압플라즈마 처리는 목분의 표면을 개질하여 폴리프로필렌과의 계면결합력을 증가시켜주는 것을 확인하였다.

• Journal of the Korean Wood Science and Technology
• /
• 제45권6호
• /
• pp.809-827
• /
• 2017

Steam explosion was applied to extract phenolic compounds from oak wood (Quercus mongolica). The effects of three independent factors (ethanol concentration, extraction temperature and extraction time) on the total phenolic content, DPPH radical scavenging activity, and antimicrobial activity from the steam exploded oak wood were optimized using response surface methodology (RSM). The independent variables were coded at three levels and their actual values were selected on the basis of preliminary experimental results. The following optimal extraction conditions were selected: ethanol concentration 82.0%, extraction temperature $71.7^{\circ}C$, and extraction time 60.5 min for total phenolic content; ethanol concentration 78.3%, extraction temperature $70.3^{\circ}C$, and extraction time 57.6 min for DPPH radical scavenging activity; ethanol concentration 80.6%, extraction temperature $68.4^{\circ}C$, and extraction time 59.0 min for antimicrobial activity. The experimental values agreed with those were predicted within confidence intervals indicating the suitability of RSM in optimizing the ethanol extraction of phenolic compounds from the steam exploded oak wood. Under the optimized conditions, the experimental value of the total phenolic content was 111.8 mg GAE/g dry steam exploded oak wood, DPPH free radical scavenging activity was 65.7%, and antimicrobial activity was 17.0 mm, and those are reasonably close to the predicted values (109.2 mg GAE/g dry steam exploded oak wood, 62.3% and 15.9 mm, respectively).

• 한국산림과학회지
• /
• 제80권4호
• /
• pp.408-415
• /
• 1991

수간(樹幹) 둘레를 철사(鐵絲)로 결체(結締)함에 따라 인위적(人爲的)인 피해(被害)를 받으므로써 형성(形成)된 아까시나무(Robinia pseudoacacia L.) 종양재(腫瘍材)의 조직학적(組織學的) 특성(特性)을 고찰(考察)하고 아울러 정상재(正常材)와의 그 특성(特性) 차이(差異)를 구명(究明)하기 위하여 본(本) 연구(硏究)를 실시(實施)하였다. 종양재(腫瘍材)는 일부(一部) 관공(管孔) 및 대부분(大部分)의 목섬유(木纖維)와 방사조직(放射組織)이 정상배열(正常配列)에서 이탈(離脫)된 불규칙적(不規則的)인 배열(配列)을 이루고 있는 점, 횡단면상(橫斷面上)의 관공(管孔)이 다소 방사방향(放射方向)으로 신당(伸張)되어 있는 점, 선단(先端)이 굴곡(屈曲)된 목섬유(木纖維)가 방사단면상(放射斷面上)의 방사조직(放射組織) 사이에서 가끔 관찰(觀察)되는 점, 방사조직(放射組織)의 폭(幅)과 높이가 더 큰 점, 방사단면상(放射斷面上)의 목섬유(木纖維)가 서로 교착배열(交錯配列)을 이루고 있는 점, 추재부(秋材部)의 복합관공(複合管孔) 출현(出現) 빈도(頻度)가 더 큰 점, 젤라틴목섬유(木纖維)의 발달(發達)이 더 일반적(一般的)인 점 및 농색(濃色)의 검(gum)상물질(狀物質)이 국부적(局部的)으로 목섬유(木纖維), 방사조직(放射組織), 축방향유세포(軸方向柔細胞)의 내강(內腔)에 발달(發達)되어 있는 점에 있어서 정상재(正常材)와의 조직(組織) 특성(特性) 차이(差異)를 나타내었다.

• Journal of the Korean Wood Science and Technology
• /
• 제43권5호
• /
• pp.613-627
• /
• 2015

Simple methods of conductometric titration and infrared spectroscopy were used to quantify the surface carboxyl content of cellulose fibrils isolated by 2,2,6,6-tetramethylpiperidine-1-oxyl radical (TEMPO)-mediated oxidation. The effects of different cellulose sources, post or assisted-sonication oxidation treatment, and the amount of sodium hypochlorite addition on the carboxyl content of cellulose were reported. This study showed that post sonication treatment had no influence on the improvement of surface carboxyl charge of cellulose macrofibrils (CMFs). However, the carboxyl content increased for the isolated cellulose nanofibrils (CNFs). Thus the carboxyl content of CNFs is different from those of their corresponding bulk oxidized cellulose and CMFs. Filter paper as a CNF source imparted a higher surface charge than did hardwood bleached kraft pulp (HWBKP) and microcrystalline cellulose (MCC). It was considered that the crystallinity and microstructure of the initial cellulose affected oxidation efficiency. In addition, the carboxyl content of cellulose was successfully controlled by applying sonication treatment during the oxidation reaction and adjusting the amount of sodium hypochlorite.

• Journal of the Korean Wood Science and Technology
• /
• 제25권4호
• /
• pp.75-91
• /
• 1997

Laser cutting tests were conducted to investigate the laser cutting characteristics of solid woods such as 25mm-thick white oak(Quercus acutissima) and maple(Acer mono), and wood-based panels such as 15mm-thick medium density fiberboard and particleboard. Test variables were laser power, cutting speed, grain direction, and moisture content. Cutting depths, kerf widths and the maximum cutting speed were measured. Cutting depths were increased as focus of laser beam was moving from above the workpiece to on the surface of workpiece, and also to below the workpiece. Kerf widths were decreased as focus of laser beam was moving from above the workpiece to on the surface of workpiece, but were increased as focus of laser beam was moving from on the surface of workpiece to below the workpiece. Minimum kerf widths were obtained when focus of laser beam was positioned on the surface of workpiece. Cutting depths and kerf widths were decreased with increase in moisture content, and cutting depths and kerf widths of more dense white oak were smaller than those of maple. And also cutting depths and kerf widths of particleboard were smaller than those of medium density fiberboard.

• Journal of the Korean Wood Science and Technology
• /
• 제47권2호
• /
• pp.200-209
• /
• 2019

To improve the water resistance of melamine-urea-formaldehyde (MUF) resins, different levels of blocked polymeric 4,4 diphenyl methane diisocyanate (B-pMDI) were blended with MUF resins to prepare B-pMDI/MUF hybrid adhesives, and their adhesion performances were evaluated for the surface lamination of fancy veneer on plywood. FT-IR spectra showed that the de-blocked -NCO groups reacted with the -OH of hydroxymethyl groups of the MUF resins to form urethane bonds at 2% B-pMDI/MUF, which was detected before and after their hydrolysis. The mass loss after the hydrolysis consistently decreased as the B-pMDI level increased, indicating an improvement in the water resistance. As the B-pMDI level increased, the activation energy of hybrid adhesives decreased, which improved the reactivity of the hybrid adhesives. Additionally, the water resistance improvement of the hybrid adhesives increased the tensile shear strength of the surface laminated plywood in semi-water proof and water-proof by 23 % and 8 %, respectively, at 2% B-pMDI level. This was likely due to the urethane linkages in the hybrid adhesives. However, the formaldehyde emission from plywood panels bonded with the hybrid adhesives increased in the dry state, indicating incomplete curing of the hybrid adhesives.

• Journal of the Korean Wood Science and Technology
• /
• 제46권3호
• /
• pp.285-296
• /
• 2018

ISPM No. 15에 의거한 열처리 목재의 검증을 위한 연구로서 열처리 목재 표면의 분광학적 특성을 분석하였다. IR 스펙트럼 상에서는 다양한 작용기들이 확인되지만 수종간, 열처리 시간 및 보관 기간에 따른 특별한 차이를 발견하기 어려웠다. HBI(hydrogen-bonding intensity)는 보관 기간에 따른 열처리 목재의 변화는 관찰할 수 있지만 열처리 시간에 따른 변화는 관찰하기 어려웠다. 하지만 PCA score plot 상에서 수종 내에서 60분 혹은 90분의 열처리 시간에 따라 목재의 분류가 가능하였다. PCA에서 열처리 목재의 분류의 기준은 목재 내 리그닌의 방향족 환과 셀룰로오스의 C-H bending이었으며 이들 성분에 의해 ISPM No. 15로 열처리된 목재를 분류할 수 있었다.

• Journal of the Korean Wood Science and Technology
• /
• 제39권2호
• /
• pp.179-186
• /
• 2011

In an effort to understand the hydrolytic degradation process of cured urea-formaldehyde (UF) resins responsible for the formaldehyde emission of wood-based composite panels, this study analyzed the influence of acid hydrolysis on the morphology of cured UF resins with different formaldehyde/urea (F/U) mole ratios such as 1.6, 1.4, 1.2 and 1.0. Field emission-scanning electron microscopy (FE-SEM) was employed to observe both exterior and fracture surfaces on thin films of cured UF resins before and after the etching with hydrochloric acid as a simulation of the hydrolytic degradation process. FE-SEM images showed that the exterior surface of cured UF resin with the F/U mole ratio of 1.0 had spherical structures after the acid hydrolysis while the other cured UF resins were not the case. However, the fracture surface observation showed that all the samples possessed spherical structures in the cured state of UF resins although their occurrence and size decreased as the F/U mole ratio increased. For the first time, we found the spherical structures in cured UF resins of higher F/U mole ratio of 1.4. After the acid hydrolysis, the spherical structures became a much predominant at the fracture surface. These results indicated that the spherical structures in cured UF resinswere much more resistant to the hydrolytic degradation by the acid than amorphous region.

• Journal of the Korean Wood Science and Technology
• /
• 제48권3호
• /
• pp.364-375
• /
• 2020

In this study, ultrasound-assisted extraction was performed to extract ascorbic acid from rugosa rose (Rosa rugosa Thunb.) fruit. The optimal conditions were investigated by response surface methodology, using two variable including reaction time (16-44 min) and temperature (16-44℃). The ascorbic acid extraction was sensitive to the reaction time rather than the reaction temperature, and the optimal conditions for ascorbic acid extraction were 25℃ and 30 min. Ascorbic acid and gallic acid in the rugosa rose fruit extract were completely separated by HPLC, with a resolution factor of over 1.5 between the two. The correlation coefficient of the ascorbic acid was 0.999 in a linearity test for 50-150 ㎍/mL concentration of extract. The limit of detection and limit of quantification values were 0.16 ㎍/mL and 29.89 ㎍/mL, respectively. The relative standard deviations (RSD) for repeatability and reproducibility were determined, and each RSD showed good precision at less than 5% (N=6).

• 한국펄프종이공학회:학술대회논문집
• /
• 한국펄프종이공학회 2006년도 PAN PACIFIC CONFERENCE vol.1
• /
• pp.43-49
• /
• 2006

The surface and pore structure of cellulose fibers have a significant impact on the properties and performance in applications. Cellulase enzymatic hydrolysis of cellulose fibers can result in changes to the surface and pore structure thus providing a useful tool for fiber modification. This research characterizes these changes using various test methods such as fiber dimension, water retention value, hard-to-remove water content, freezing and non-freezing bound water content, polymer adsorption, and crystallinity index. For a high-dosage enzyme treatment (0.10 g/g), the fiber length was significantly decreased and the fibers were 'cut' in the cross direction, not in the axial direction. The swelling capacities as measured by the WRV and HR water content increased for the high-dosage treatment. Three independent measurements (non-freezing bound water, polymer adsorption, and crystallinity index) are in good agreement with the statement that the amorphous regions of cellulose fibers are a more readily available substrate relative to crystalline regions. Based on the experimental results obtained herein, a model was proposed to explain surface and pore structure modification of cellulose fibers via enzymatic treatment.