Journal of the Korean Wood Science and Technology

The Korean Society of Wood Science & Technology (한국목재공학회)
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Spectroscopic Characterization of Wood Surface Treated by Low-Temperature Heating

저온 열처리 목재 표면의 분광학적 특성

  • Kim, Kang-Jae (Agricultural Science and Technology Research Institute, Kyungpook National University) ;
  • Nah, Gi-Baek (Department of Wood Science and Technology, College of Agriculture and Life Sciences, Kyungpook National University) ;
  • Ryu, Ji-Ae (Department of Wood Science and Technology, College of Agriculture and Life Sciences, Kyungpook National University) ;
  • Eom, Tae-Jin (Major in Wood Science and Technology, School of Forestry, Sciences and Landscape Architecture, College of Agriculture and Life Sciences, Kyungpook National University)
  • 김강재 (경북대학교 농업과학기술연구소) ;
  • 나기백 (경북대학교 임산공학과) ;
  • 류지애 (경북대학교 임산공학과) ;
  • 엄태진 (경북대학교 산림과학조경학부 임산공학전공)
  • Received : 2018.04.30
  • Accepted : 2018.05.18
  • Published : 2018.05.25
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Abstract

As a study for the verification of heat treated wood according to ISPM No. 15, the spectroscopic characteristics of the heat treated wood surface were analyzed. Various functional groups were observed on the IR spectrum, but it was difficult to find any particular difference between wood species, heat treatment time and storage period. HBI (hydrogen-bonding intensity) shows the change of the heat treated wood according to the storage time, but the change of wood with the heat treatment time was hard to be observed. On the PCA score plot, however, it was possible to sort the wood according to the heat treatment time of 60 minutes or 90 minutes in the species. The standards for classification of heat-treated wood in PCA were aromatic rings in lignin and C-H bending in cellulose, and these components were able to classify heat-treated wood by ISPM No. 15.

ISPM No. 15에 의거한 열처리 목재의 검증을 위한 연구로서 열처리 목재 표면의 분광학적 특성을 분석하였다. IR 스펙트럼 상에서는 다양한 작용기들이 확인되지만 수종간, 열처리 시간 및 보관 기간에 따른 특별한 차이를 발견하기 어려웠다. HBI(hydrogen-bonding intensity)는 보관 기간에 따른 열처리 목재의 변화는 관찰할 수 있지만 열처리 시간에 따른 변화는 관찰하기 어려웠다. 하지만 PCA score plot 상에서 수종 내에서 60분 혹은 90분의 열처리 시간에 따라 목재의 분류가 가능하였다. PCA에서 열처리 목재의 분류의 기준은 목재 내 리그닌의 방향족 환과 셀룰로오스의 C-H bending이었으며 이들 성분에 의해 ISPM No. 15로 열처리된 목재를 분류할 수 있었다.

Keywords

References

  1. Brockerhoff, E.G., Bain, J., Kimberley, M., Knizek, M. 2006. Interception frequency of exotic bark and ambrosia beetles (Coleoptera: Scolytinae) and relationship with establishment in New Zealand and worldwide. Canadian Journal of Forest Research. 36(2): 289-298. https://doi.org/10.1139/x05-250
  2. Carrillo, F., Colom, X., Sunol, J.J., Saurina, J. 2004. Structural FTIR analysis and thermal chracterisation of lycell and viscose-type fibers. European Polymer Journal 40(9): 2229-2234. https://doi.org/10.1016/j.eurpolymj.2004.05.003
  3. Colom, X., Carrillo, F. 2002. Crystallinity changes in lyocell and viscose-type fibres by caustic treatment. European Polymer Journal 38(11): 2225-2230. https://doi.org/10.1016/S0014-3057(02)00132-5
  4. Faix, O. 1991. Classification of lignins from different botanical origins by FT-IR spectroscopy. Holzforschung. 45(s1): 21-27. https://doi.org/10.1515/hfsg.1991.45.s1.21
  5. Fengal, D. 1993. Influence of water on the OH valency range in deconvoluted FTIR spectra of cellulose. Holzforschung 47(2): 103-108. https://doi.org/10.1515/hfsg.1993.47.2.103
  6. Haack, R.A., Britton, K.O., Brockerghoff, E.G., Cavey, J.F., Garrett, L.J., Kimberley, M., Lowenstein, F., Nuding, A., Olson, L.J., Turner, J., Vasilaky, K.N. 2014. Effectiveness of the International Phytosanitary Standard ISPM No. 15 on reducing wood borer infestation rates in wood packaging material entering the United States. PLOS ONE. 9(5): e96611(1-15). https://doi.org/10.1371/journal.pone.0096611
  7. Hwang, S.W., Lee, W.H., Horikawa, Y., Sugiyama, J. 2015. Chemometrics approach for species identification of Pinus densiflora Sieb. Et Zucc. and Pinus densiflora for. erecta Uyeki. Journal of the Korean Wood Science and Technology 43(6): 701-713. https://doi.org/10.5658/WOOD.2015.43.6.701
  8. Kalutskaya, E.P., Gusev, S.S. 1980. An infrared spectroscopic investigation of the hydration of cellulose. Polymer Science U.S.S.R. 22(3): 550-556. https://doi.org/10.1016/0032-3950(80)90378-0
  9. Leonowicz, A., Cho, N.S., Wasilewska, M.W., Rogalski, J., Luterek, J. 1997a. Enzymes of white-rot fungi cooperate in biodeterioration of lignin barrier. Journal of the Korean Wood Science and Technology 25(2): 1-20.
  10. Leonowicz, A., Gianfreda, L., Rogalski, J., Jaszek, M., Luterek, J., Wasilewska, M.W., Malarczyk, E., Dawidowicz, A., Fink-Boots, M., Ginalska, G., Staszczak, M., Cho, N.S. 1997b. Appearance of laccase in wood-rotting fungi and its inducibility. Journal of the Korean Wood Science and Technology 25(3): 29-36.
  11. Liang, C.Y., Marchessault, R.H. 1959. Infrared spectra of crystalline polysaccharides. I. Hydrogen bond in native cellulose. Journal of Polymer Science Part A: Polymer Chemistry 37(132): 385-395.
  12. Nelson, M.L., O'Connor, R.T. 1964. Relation of certain infrared bands to cellulose crystallinity and crystal latticed type. Part I. Spectra of lattice types I, II, III and of amorphous cellulose. Journal of Applied Polymer Science 8(3): 1311-1324. https://doi.org/10.1002/app.1964.070080322
  13. Oh, S.Y., Yoo, D.I., Shin, Y., Kim, H.C., Kim, H.Y., Chung, Y.S., Park, W.H., Youk, J.H. 2005. Crystalline structure analysis of cellulose treated with sodium hydroxide and carbon dioxide by means of X-ray diffraction and FTIR spectroscopy. Carbohydrate Research 340(15): 2376-2391. https://doi.org/10.1016/j.carres.2005.08.007
  14. Park, S.Y., Kim, J.C., Kim, J.H., Yang, S.Y., Kwon, O., Yeo, H., Cho, K.C., Choi, I.G. 2017. Possibility of wood classification in Korean softwood species using near-infrared spectroscopy based on their chemical compositions. Journal of the Korean Wood Science and Technology 45(2): 202-212. https://doi.org/10.5658/WOOD.2017.45.2.202
  15. Ryu, J.A., Nah, G.B., Kim, K.J., Eom, T.J. 2017. Chemical and chemometrical analysis of heat treated wood materials for import and export cargo. 2017 Proceeding of Fall Conference of the Korea Technical Association of the Pulp and Paper Industry, p. 44.
  16. Sagisaka, S. 1972. Decrease of glucose 6-phosphate and 6-phosphogluconate degydrogenase activities in the xylem of Populus gelrica on budding. Plant Physiology 50(6): 750-755. https://doi.org/10.1104/pp.50.6.750
  17. Savitzky, A., Golay, M.J.E. 1964. Smoothing and differentiation of data simplified least squares procedures. Analytical Chemistry 36(8): 1627-1639. https://doi.org/10.1021/ac60214a047
  18. Schwanninger, M., Rodrigues, J.C., Pereira, H., Hinterstoisser, B. 2004. Effects of short-time vibratory ball milling on the shape of FT-IR spectra of wood and cellulose. Vibrational Spectroscopy 36(1): 23-40. https://doi.org/10.1016/j.vibspec.2004.02.003
  19. Široký, J., Blackburn, R.S., Bechtold, T., Taylor, J., White, P. 2010. Attenuated total reflectance fourier-transform infrared spectroscopy analysis of crystallinity changes in lyocell following continuous treatment with sodium hydroxide. Cellulose 17(1): 103-115. https://doi.org/10.1007/s10570-009-9378-x
  20. Zahid, M.I., Grqurinovic, C.A., Walsh, D.J. 2008. Quarantine risks associated with solid wood packaging materials receiving ISPM 15 treatments. Australian Forestry 71(4): 287-293. https://doi.org/10.1080/00049158.2008.10675047