• Title/Summary/Keyword: wood formation

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Characteristics of xylose and glucuronic acid at concentrated sulfuric acid hydrolysis (진한 황산 가수분해 반응조건에서 xylose와 glucuronic acid의 반응 특성)

  • Cho, Dae-Haeng;Kim, Yong-Hwan;Park, Jong-Moon;Sim, Jae-Hoon;Kim, Byung-Ro;Shin, Soo-Jeong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.44 no.3
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    • pp.9-14
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    • 2012
  • Formed fermentation inhibitors during acid saccharification leads to poor alcohol production based on lignocellulosic bio-alcohol production process. In this work, it is focused on the formation of fermentation inhibitors from xylan, which is influenced by reaction tempearature and time of acidic sacharifiaction of xylose and glucuronic acid. In second step of concentrated acid hydrolysis, part of xylose and glucuronic acid was converted to furfuraldehyde and formic acid by dehydration and rearrangement reactions. Furfural was form from xylose, which was highly sensitive to reaction temperature. Formic acid was come from both xylose and glucuronic acid, which supposed to main inhibitor in biobutanol fermentation. Reaction temperature of second hydrolysis was main variables to control the furfural and formic acid generation. Careful control of acid saccharification can reduce generation of harmful inhibitors, especially second step of concentrated sulfuric acid hydrolysis process.

Formation and Preservative Effectiveness of Inorganic Substances in Wood Treated with Potassium Carbonate and Calcium Chloride (탄산칼륨과 염화칼슘을 이용한 무기질 복합화 목재 중에 있어서 무기염의 생성과 방부효력)

  • Yoon, Sun-Mi;Lee, Jong-Shin
    • Journal of the Korean Wood Science and Technology
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    • v.29 no.2
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    • pp.126-132
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    • 2001
  • This research is carried out to investigate the formation and preservative effectiveness of inorganic substance, calcium carbonate($CaCO_3$), in wood. The specimens were prepared by the impregnation with saturated solutions of potassium carbonate($K_2CO_3$) into the wood followed by precipitation in saturated solutions of calcium chloride($CaCl_2$) for 24h, 72h and 120h, and then they were leached in instrument flowing with water for 24h. The weight percent gains of $K_2CO_3$ solution impregnated specimens reached approximately a maximum value (108.1%) by 72h precipitation in $CaCl_2$ solutions. Inorganic substances were observed to he produced in the lumina of tracheids of specimens. From these inorganic substances filling in the tracheids, characteristic X-rays of calcium(Ca-$K_{\alpha}$) were detected by energy dispersive X-ray analyzer. Moreover, it was shown from a leaching treatment that these substances could not he leached easily from the specimens. Therefore, they were could he considered to be insoluble calcium carbonates. The weight losses of the prepared specimens were hardly occurred by test fungi attacks. Thus inorganic substances in specimens can be said to have preservative effectiveness.

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Wood Anatomical Characteristics of Pine Tree (Pinus densiflora S. et Z.) Damaged by Air Pollution (대기오염(大氣汚染) 피해(被害) 소나무의 목재(木材) 해부학적(解剖學的) 특성(特性))

  • Kim, Yoon-Soo;Park, Byung-Dae;Shim, Keun
    • Journal of the Korean Wood Science and Technology
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    • v.15 no.2
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    • pp.105-112
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    • 1987
  • Some anatomical characterisitcs of Japanese red pine (Pinus densiflora S. et Z.) collected from pollution-exposed areas in Korea were investigated. These sites were reportedly the most severe air polluted areas in Korean peninsular. A decline in overall growth rate was apparent since the late 10-year period of growth. P. densiflora in Onsan and in Yeochon recorded in the radial growth reduction of approximately 70 and 60% respectively. The formation of earlywood in the period of air pollution was restricted, whereas the percentage of latewood increased. The maximum wood density was lower in xylem rings formed during a period of air-pollution than in rings found without pollution. Most of pine trees damaged by air pollution showed the classical type of length-on-age curve for tracheids. However, reduction in cell wall-thickness and diameter was revealed in the wood exposed to air pollutants. Nor anomalies in microstructures nor microorganisms in wood structures were found in the damaged trees.

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Two-dimensional numerical experiment considering cohort size and wood jam characteristic on driftwood (유목의 유입규모와 군집특성을 고려하는 2차원 수치모의 실험)

  • Kang, Taeun;Jang, Chang-Lae
    • Journal of Korea Water Resources Association
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    • v.54 no.6
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    • pp.407-418
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    • 2021
  • In this study, the two-dimensional flow model, Nays2DH, and driftwood dynamics model were combined to analyze the flow and driftwood behavior depending on the characteristics of the inflow of driftwood and the length of the driftwood stem. In particular, the Dashpot-spring model was added to the driftwood dynamics model to simulate the collision motion of the driftwood, and the wood jam characteristics by the collision of the driftwood were compared. As a result of the simulation, the pass rate of the obstacle section, the travel distance of wood jam, and the mean position of the wood pieces were respondent sensitively by the length of the driftwood stem, but the cohort size of the driftwood supply was insignificant excepting for the pass rate. Through this study, we could understand the interaction between hydraulic structures and driftwood, and through this, it is believed that it will be helpful in establishing a durable maintenance plan for hydraulic structures by predicting the transport and jam formation phenomena of driftwood in advance.

On the Pith-damaged Wood of Larix leptolepis Gorden (낙엽송(落葉松)(Larix leptolepis Gorden)의 심부재(心腐材))

  • Min, Du Sik;Lee, Shae Pyo;Choi, Tae Ho
    • Journal of Korean Society of Forest Science
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    • v.79 no.4
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    • pp.419-423
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    • 1990
  • This study was carried out to investigate the cause of pith-damaged wood formation, the state of growth, and difference of chemical composition of Japanese Larix(L. leptolepis Gorden). 1. Larix grew normaly to 10 years, and the volume increment was 32.4%. But it was gradually decreased to 19.4% from 11 to 13 years that the heartwood damage was occurred. Therefore, the volume increment was decreased 13%. The decayed wood was formed from fire wound portion of bark by forest fire. The volume loss from pith-dagmaged wood occurred by forest fire was more than 20%. 2. On the ash content, heartwood(0.05%) and pith-damaged wood(0.08%) was lower than sapwood(0.29%). The difference of extractive contents are considered the reason. It is considered that this ash content difference is depend upon the extractive contents among sap, heart and decayed wood parts. Holocellulose contents were from 54.3% to 59.3% and there were no difference among heartwood, pith-damaged wood, and sapwood, On the pentosan contents, heartwood(6.3%) and pith-damaged wood(6.6%) were higher than sapwood. Lignin contents of pith-damaged wood was tower than heartwood (34.4%). This seems to weaken all kinds of wood strength.

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Formation Conditions of Na-cellulose II with Three Fold Helix (3회나선축을 갖는 Na-cellulose II의 형성조건에 관한 고찰)

  • Kim, Nam-Hun;Lee, Myoung-Ku
    • Journal of the Korean Wood Science and Technology
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    • v.27 no.1
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    • pp.18-23
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    • 1999
  • The formation conditions of Na-cellulose II with three fold helix were investigated by an x-ray diffraction method. Na-cellulose II was formed through Na-cellulose I. It seems that the concentration of sodium hydroxide in Na-cellulose II is higher than both those of Na-cellulose I and Na-cellulose III. Na-cellulose II was formed well by different rinsing and drying methods even though the sample treatment was carried out in very short periods of time. Metal-complexed Na-cellulose swollen in the mixture of $Cu(OH)_2$ and sodium hydroxide is stable in wet state, and changed to a different polymorph by drying.

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A Study on the Development of Hwaseonji from Bamboo Pulp (대나무펄프를 이용(利用)한 화선지(畵宣紙) 개발(開發)에 관(關)한 연구(硏究))

  • Cheon, Cheol
    • Journal of the Korean Wood Science and Technology
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    • v.20 no.2
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    • pp.43-50
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    • 1992
  • This study was carried out to investgate the possiblity of using waste bamboo and bast fiber from paper mulberry for Hwaseonji production. 3 types of Hwaseonji were made in an experimental system, 100% bamboo pulp, bamboo pulp mixed with bast fiber in two different ratios, 70% : 30% and 40% : 60%, respectively. The result were as follows: 1. The chinese ink blots of Hwaseonji made from bamboo pulp only was satisfactory, but its tensile strength showed a low value. In order to improve the tensile strength, we must develope a new beating method with musilige. 2. The burst strength increased as the bast fiber content increased. But it is a special characteristic of Hwaseonji, that an even formation of paper is required. Therefore, only the short bast fiber is needed. 3. The tensile strength was raised by increasing the bast fiber content to 60%, resulting in a more durable Hwaseonji. 4. In even thickness, the higher opacity showed the more bast fiber. So the opacity of product III (bamboo: 40%, bast fiber: 60%) is the highest. 5. The commodity value of hand-made paper should be grade-up after a dedusting process.

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Changes of Chemical Bond in Woody Charcoal from Different Carbonization Temperatures (목질탄화물 내의 화학 결합 변화)

  • Jo, Tae-Su;Lee, Oh-Kyu;Choi, Joon-Weon;Cho, Sung-Taig;Kim, Suk-Kuwon
    • Journal of the Korean Wood Science and Technology
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    • v.37 no.1
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    • pp.87-93
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    • 2009
  • Properties and chemical bonding of wood charcoal were investigated to understand the chemistry occurring in wood carbonization. From the pH changes of wood charcoal, it is revealed that it becomes acidic to weakly basic for charcoal carbonized at about $300^{\circ}C$, whereas it turns to basic at higher carbonization temperature higher than $600^{\circ}C$. Also, the ratio of carbon atoms in the charcoal was increased with increasing the carbonization temperature, while those of oxygen and hydrogen atoms. This tendency was significant when the carbonization temperature was increased up to $600^{\circ}C$ and the ratio changes of the atoms became stable at above $600^{\circ}C$. In the changes of chemical bonding, the ratio of C-C bonding was increased and those of C-O-H and C-O-R bonding was decreased significantly. It is considered that bondings connected to oxygen atoms tends to be broken, and the ratio of C-C bonding increased. Consequently, it is expected that this change may causes occurrence of new functional groups. In addition to that, it seems to be that the chemical bondings undergo the partial decomposition, formation, and recombination steps, Because ratio of C=O bonding tended to be increased or decreased by increasing the carbonization temperature. This understanding of chemical bond changes in charcoal can be a compensative consideration on the knowledges made only by physical parameters in the properties of micro-pore which has limited to explain the phenomenon. Also, it is considered that this can be treated as a basic knowledge for upgrading and development of use of wood charcoal.

Practical Use of Vacuum Press for Curvature Formation in Wooden Furniture Design (목 가구 디자인에서 곡면 성형을 위한 베큠프레스의 활용)

  • Wee, Han-Lim
    • Archives of design research
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    • v.18 no.4 s.62
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    • pp.155-164
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    • 2005
  • In contrast with product design field, some designers who work in furniture field tend to do their own studio works as well as typical designing part. Especially in the small furniture studios for the limited quantity batch production, custom made or handmade craft furniture which is finished with high quality, the propensity for their own production is more obvious than in the big furniture companies in this case. In this kind of small-scale furniture studios, they have more chance to create the various formative works and 'curved shape' is one of the most important elements to form creative pieces. Except by caning, it is very difficult to make curved wooden shape because of own characteristic of wood. Therefore, the special techniques of bending wood are essential to formative furniture production and vacuum press system is introduced as a main subject for the bending wood method in this study. Especially for the designers who work as makers as well at the small furniture studios, the value of vacuum press system on efficiency and productivity of work was sought by testing and improving the method of wood bending techniques. According to this practical searching, ideally sufficient condition on vacuum pressing work was founded as a result on this study.

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Densified Pellet Fuel Using Woody Core of Industrial Hemp (Cannabis sativa L.) as an Agricultural waste (농업부산물인 산업용 대마(Cannabis sativa L.) 목부를 이용한 고밀화 펠릿 연료)

  • Han, Gyu-Seong;Lee, Soo-Min;Shin, Soo-Jeong
    • Korean Journal of Plant Resources
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    • v.22 no.4
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    • pp.293-298
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    • 2009
  • We prepared densified wood pellet by agricultural waste. The hemp woody core was used as replacing wood resource. Hemp was separated into the bast fiber and the woody core by hot steaming treatment. The hemp woody core had a similar lignin content(19.4%) and carbohydrate composition with hardwood(20-25% lignin in hardwood), respectively. Also, the hemp had a low ash content(0.5%), which resulted in a low ash formation in pellet burning. Heating value of the hemp pellet(18.40 MJ/kg) had a very similar to the pellet made by hardwoods. The hemp woody core could be replaced the hardwood for densified wood pellet.