• 한국가구학회지
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• 제11권1호
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• pp.13-23
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• 2000

This study was carried out to investigate the wood properties for development the proper uses of lesser-known tree species. The tested species are Kebambang(Pentace sp.), Bawang-bawang(Dysoxylum alliaceum Bl .), Garu buaya( Gonystylus brunescens A. Shaw)grown in Indonesia. fundamental wood properties such as anatomical, physical, mechanical and chemical properties and characteristics related to wood processing were examined. The results are summarized as follows : The woods of these species are diffuse porous, coarse textured, and interlocked grained. The heartwood of Kebambang is distinguished clearly to the sapwood, but the heartwood of other species are not distinguished clearly to the softwood. The woods of Kebambang and Bawang-bawang have the moderate weight density and the low strength properties, but Garu buaya has the high weight density and the high strength properties. The woods of these species has high shrinkage. The sawing characteristics of Kebambang are excellent but the other species are moderate. The machining characteristics by planer and drying characteristics of these species are moderate. These woods has poor characteristics in bending processing and decay durability. The wood of Bawang-bawang has high content of the extractives and lignin.

• Journal of the Korean Wood Science and Technology
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• 제40권2호
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• pp.141-146
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• 2012

The outer bark of Prunus sargentii was collected, air-dried and extracted with 70% aqueous acetone. Then it was successively partitioned with n-hexane, dichloromethane ($CH_2Cl_2$), ethyl acetate (EtOAc) and $H_2O$. From the EtOAc soluble fraction, four compounds were isolated by the repeated Sephadex LH-20 column chromatography. The isolated compounds were determined as (+)-catechin (1), (-)-epicatechin (2), taxifolin (3), and neosakuranin (4) by the spectroscopic analysis including $^1H$, $^{13}C$-NMR, and 2D-NMR spectrometers. The antioxidative activities on the isolated compounds and the separated fractions were evaluated by DPPH radical scavenging assay. The crude, EtOAc, and $H_2O$ soluble fractions indicated good antioxidative potential compared to the $CH_2Cl_2$ and n-hexane soluble fractions.

• Journal of the Korean Wood Science and Technology
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• 제28권2호
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• pp.42-48
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• 2000

항균 및 항산화활성이 우수한 산뽕나무(Morus bombycis)로부터 항균 및 항산화물질 탐색을 위해 심재 에탄올 추출물을 용매분획하여 얻은 에틸아세테이트 가용부로부터 4개의 페놀성 화합물을 단리하였다. 이들을 기기분석한 결과, stilbenoid 인 2',3,4',5-tetrahydroxystilbene(oxyresveratrol), 3,4',5-trihydroxystilbene(resveratrol)과 flavonoid인 2',3,4',5,7-pentahydroxyflavone(morin) 및 3,4',5,7-tetrahydroxyflavan ((+)-afzelechin)인 것으로 동정되었다.

• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 2008년도 춘계학술대회
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• pp.222-228
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• 2008

The chemical composition and thermal, crystal characterization of oak mushroom waste were investigated in comparison with those normal oak wood for utilization of cellulose from oak mushroom waste. The oak mushroom waste contained a higher percentage of ash, and hot water extractives than oak wood. This results indicated that the materials inside the body are easily decomposed during the oak mushroom cultivation. The lower percentage of holocellulose and a-cellulose of oak mushroom waste caused by fungal decomposition too. Whereas, the thermal decomposition behavior and crystallinity of oak mushroom waste was similar to that of normal oak wood, which indicated that the cellulose characterization of oak mushroom waste is resistant to fungal decomposition. In additionally, a degree of polymerization of oak mushroom waste must be investigate for examination of cellulose crystalline characterization, especially.

• 한국산림과학회지
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• 제95권5호
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• pp.511-515
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• 2006

From the EtOAc soluble fractions of Platanus orientals Linn leaves, (+)-catechin (1), (+)-epicatechin (2), (+)-gallocatechin (3), kaempferol (4), quercetin (5), kaempferol-3-O-${\alpha}$-L-rhamnopyranoside (6), quercetin-3-O-${\beta}$-D-glucopyranoside (7) and tyrosol (8) were isolated. The structures of the isolated compounds were characterized by NMR and MS spectrometers. The antioxidative activities of the isolated compounds and fractions were evaluated by DPPH free radical scavenging method and the results indicated that compounds 1, 2, 3, 4, 5 and EtOAc soluble fraction exhibited greater activities than ${\alpha}$-tocopherol and BHT, while compounds 6, 8 and other fractions showed low activity compared to the controls.

• Journal of the Korean Wood Science and Technology
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• 제31권5호
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• pp.43-48
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• 2003

회화나무잎에서 3종의 화합물을 단리하였으며, 기기분석 결과 hypogallic acid, kaempferol, quercetin으로 각각 동정하였다. 이들 단리 물질의 항산화 활성은 라디칼 소거능으로 측정하였으며, 항산화 활성은 100 ㎍/ml의 농도에서 각각 98.2%, 96.2% 그리고 90.2%를 나타내었고 이 중 화합물 1 (hypogallic acid)과 화합물 2 (kaempferol)의 경우는 합성 항산화제인 BHT보다 높은 항산화 활성을 나타내었다.

• 펄프종이기술
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• 제48권3호
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• pp.57-65
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• 2016

Indigo (Polygonum tinctorium L.) is a typical blue dye which had been used from ancient times. This study was going to shade the complicated traditional methods extracting indigo dye by the fermentation and producing as adsorbate on calcium hydroxide, which says so called as the 'Indigo lime'. Accordingly we were going to make indigo through the hydrolysis of the hot water extractives of indigo leaves simply. During hot-water extraction, ${\beta}$-glucosidase which required hydrolysis of the linkage between indigo and glucose was not activated. To achieve this goal, indican was acid-hydrolyzed to glucose and indigo. The acetic acid, citric acid, hydrochloric acid, and sulfuric acid were used for the hydrolysis of hot water extractives. The hydrolysis conditions of extractives performed in water bath at $80^{\circ}C$ for 120 minutes and in an autoclave for 120 minutes. In the acid hydrolysis of extracted indican by hot water, the indican yields of acetic acid and hydrochloric acid hydrolysis were higher than sulfuric acid in water bath. Also, the indican yield of hydrochloric acid hydrolysis was better than sulfuric acid in autoclave. The hot water extracted indican was confirmed by HPLC analysis and its structure was confirmed by UV-Vis and FT-IR spectroscopy, compared with isolated indigo and commercial synthesized indigo. This improved extraction and hydrolysis methods can be replace the traditional indigo making method.

• Journal of the Korean Wood Science and Technology
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• 제48권2호
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• pp.231-244
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• 2020

As a way of finding value-added materials from waste medium density fiberboard (MDF), this study characterized cellulose nanocrystals (CNCs) isolated by ammonium persulfate (APS) oxidation using recycled MDF fibers. Chemical composition of the recycled MDF fibers was done to quantify α-cellulose, hemicellulose, lignin, nitrogen, ash and extractives. The APS oxidation was performed at 60 ℃ for 16 h, followed by ultrasonication, which resulted in a CNC yield of 11%. Transmission electron microscope images showed that rod-like CNCs had an average length and diameter of 167±47 nm and 8.24±2.28 nm, respectively, which gave an aspect ratio of about 20. The conductometric titration of aqueous CNCs suspension resulted in a carboxyl content of 0.24 mmol/g and the degree of oxidation was 0.04. Attenuated total reflection Fourier transform infrared (ATR-FTIR) spectroscopy clearly showed the presence of carboxyl group on the CNCs prepared by the APS oxidation. The change of pH of the aqueous CNC suspension from 4 to 7 converted the carboxyl group to sodium carboxylate group. These results showed that the APS oxidation was facile and CNCs had a one-step preparation method, and thus suggested an optimization of the oxidation condition in future.

• Journal of the Korean Wood Science and Technology
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• 제34권3호
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• pp.90-98
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• 2006

일반적으로 동물성 섬유(견, 모)는 단백질 섬유로서 매염제를 쓰지 않고도 염색이 잘되는 편이지만, 식물성 섬유인 면, 마 등은 섬유소이므로 색소의 흡착이 불량하여 염색성이 우수한 염색 보조제로 전처리 한 다음, 주매염제를 처리해야 좋은 결과를 얻을 수 있다. 식물성 섬유의 일종인 인피섬유로 이루어진 한지의 천연염색 효과 향상을 위해 염색 보조제로 콩즙, 탈지분유 및 키토산을 한지에 전처리를 한 다음, 황벽나무 수피, 찔레나무 지엽, 꼭두서니 및 자초 뿌리로부터 염료를 추출하고 $Al_2(SO_4)_3$와 $Fe(OH)(CH_3COO)_2$를 매염제로 사용하여 염색한 한지의 염색특성과 견뢰도를 분석하였다. 천연염색 한지의 색상 및 색차 분석결과 염색 보조제를 사용한 것이 모든 염료에서 무처리 시료보다 염색이 양호하였으며, 사용한 염색 보조제 중에서는 콩즙으로 전처리한 시료가 가장 우수한 염색 효과를 나타내었다. 촉진노화 시험을 통한 천연염색 한지의 견뢰도를 분석한 결과 자초가 가장 불량한 것으로 나타났으며, 꼭두서니가 비교적 우수한 것으로 나타났다.

• Journal of the Korean Wood Science and Technology
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• 제30권4호
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• pp.51-57
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• 2002

항산화활성이 우수한 아까시나무 심재 에탄올 조추출물로부터 항산화물질을 탐색할 목적으로 4종의 화합물을 단리하였으며, MS, NMR 등의 분광학적 방법에 의해 그 화학적 구조를 3-𝛽-stigmast-5-en-3-ol(daucosterol)를 비롯하여 스틸베노이드 화합물인 3,3',4',5-tetrahydroxystilbene과 후라보노이드인 3,3',4',5',7-pentahydroxyflavone(robinetin) 및 3,3',4',7-tetrahydroxyflavanone(fustin)으로 각각 동정하였다. 단리된 화합물의 프리라디칼 소거능을 측정하여 항산화활성을 검정한 결과, 페놀성 수산기가 5개인 3,3',4',5',7-pentahydroxyflavone은 천연항산화제 및 합성항산화제보다 높은 항산화활성을 나타내어 단리화합물 중 가장 항산화활성이 높은 것으로 나타났다. 또한, 페놀성 수산기가 4개인 3,3',4',5-tetrahydroxystilbene과 3,3',4',7-tetrahtdroxyflavanone도 천연항산화제인 𝛼-tocopherol보다 높은 항산화활성을 나타내었으나 3-𝛽-stigmast-5-en-3-ol은 항산화활성이 없는 것으로 나타나 프리라디칼 소거능에 의한 항산화활성은 화합물의 페놀성 수산기 수에 크게 좌우되는 것으로 판단되었다. 이상의 결과 아까시나무의 높은 항산화활성은 3,3',4',5',7-pentahydroxyflavone, 3,3',4',5-tetrahydroxystilbene 및 3,3',4',7-tetrahydroxyflavanone에 기인하는 것으로 사료되었다.