• Title/Summary/Keyword: wet strength

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Performance of Fixing Agents in Controlling Micro-Stickies in Recycled Newsprint Pulp

  • Wang, Li-Jun;Chen, Fu-Shan;Zhou, Lin-Jie
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.06a
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    • pp.111-116
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    • 2006
  • The microstickes control effects of some fixing agents, including an inorganic PAC, an organic polyamine (PA) and polydiallydimethyl ammonium chloride (Pdadmac), and a high cationic starch (HCS), were investigated, together with their effects on wet end performances and physical properties of handsheets. Despite that the HCS and Pdadmac had lower cationic charge densities than the PA and PAC (the HCS being even lower), they gave higher zeta potentials to fibers, and lower turbidities, cationic demands and residual COD contents to the pulp liquid phases than the PA and PAC did. In all cases, the HCS showed even better effects than the Pdadmac. In addition, drainage speed was also much higher by the HCS treatments although paper formation was worsened. All the phenomena showed that the HCS can fix more dissolved and colloidal substances to cellulose fibers, indicating that the HCS functioned mainly with flocculation and even hydrogen bonding mechanisms. Data on optical properties further indicated that the HCS interacted preferentially with colloidal substances, since it fixed more 'dirty' microstickes to fibers which decreased more sheet brightness while increasing more sheet opacity (with both higher light absorption and scattering coefficients). Interestingly, the organic fixing agents did not decrease tensile, tearing, and folding strengths of paper sheets made from 100% recycled newsprint pulp, except when they were dosed in high amounts. On the contrary, the inorganic PAC had more serious negative effects on the strength properties, especially on folding endurance. The study suggested that proper use of the HCS can lead to better microstickies control effects than traditional agents and methods.

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Etching characteristics of Al-Nd alloy thin films using magnetized inductively coupled plasma

  • Lee, Y.J.;Han, H.R.;Yeom, G.Y.
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 1999.10a
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    • pp.56-56
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    • 1999
  • For advanced TFT-LCD manufacturing processes, dry etching of thin-film layers(a-Si, $SiN_x$, SID & gate electrodes, ITO etc.) is increasingly preferred instead of conventional wet etching processes. To dry etch Al gate electrode which is advantageous for reducing propagation delay time of scan signals, high etch rate, slope angle control, and etch uniformity are required. For the Al gate electrode, some metals such as Ti and Nd are added in Al to prevent hillocks during post-annealing processes in addition to gaining low-resistivity($<10u{\Omega}{\cdot}cm$), high performance to heat tolerance and corrosion tolerance of Al thin films. In the case of AI-Nd alloy films, however, low etch rate and poor selectivity over photoresist are remained as a problem. In this study, to enhance the etch rates together with etch uniformity of AI-Nd alloys, magnetized inductively coupled plasma(MICP) have been used instead of conventional ICP and the effects of various magnets and processes conditions have been studied. MICP was consisted of fourteen pairs of permanent magnets arranged along the inside of chamber wall and also a Helmholtz type axial electromagnets was located outside the chamber. Gas combinations of $Cl_2,{\;}BCl_3$, and HBr were used with pressures between 5mTorr and 30mTorr, rf-bias voltages from -50Vto -200V, and inductive powers from 400W to 800W. In the case of $Cl_2/BCl_3$ plasma chemistry, the etch rate of AI-Nd films and etch selectivity over photoresist increased with $BCl_3$ rich etch chemistries for both with and without the magnets. The highest etch rate of $1,000{\AA}/min$, however, could be obtained with the magnets(both the multi-dipole magnets and the electromagnets). Under an optimized electromagnetic strength, etch uniformity of less than 5% also could be obtained under the above conditions.

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Studies on the Blistering Resistance(I) - The influence of pigment ratio on blistering resistance - (블리스터링에 관한 연구(제1보) - 안료의 배합비가 블리스터링에 미치는 영향 -)

  • Lim, Won-Seok;Ha, Young-Baeck;Kim, Chang-Keun;Lee, Yong-Kyu
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.39 no.2 s.120
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    • pp.25-30
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    • 2007
  • Recently the use of web offset printing has been increasing, which can provide high print speed, mass production, and high print quality. However, high speed web offset printing has frequently undergone a blistering problem when the printed paper passes through hot air dryers. Blistering occurs in the middle of the base paper or in the coating layer. This paper focused on the blistering occurring in the base paper. In order to elucidate the effect of pigment ratio on blistering, 6 types of coating color were prepared with varying GCC/clay ratios and printability and blistering were investigated focusing on structure changes in the coating layer. When the clay content in the coating layer was increased, surface roughness and surface strength were decreased and paper gloss was increased. In addition, it was found that the coating layer structure with high clay content, which contains lots of discontinuous pores, hindered water vapors to penetrate out and, as a result, blistering occurred.

Development of Controlled Release Oral Drug Delivery System by Membrane-Coating Method-III- Preparation of Theophylline Tablets and Pharmacokinetic Evaluation in Man- (피막법에 의한 경구투여용 제어방출제제의 개발-III-테오필린함유 제어방출제제의 제조 및 사람의 타액중 농도로부터의 평가-)

  • Shim, Chang-Koo;Kim, Chong-Kook;Lee, Min-Hwa;Kim, Shin-Keun
    • Journal of Pharmaceutical Investigation
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    • v.22 no.3
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    • pp.205-210
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    • 1992
  • In order to develop a controlled-release oral drug delivery system (DDS) of theophylline (TP), microporous membrane-coated tablets were prepared and evaluated in vitro and in vivo. Rapidly water-soluble core tablets of TP (300 mg) were prepared by wet granulation and compression technique, Then the core tablets were spray-coated with polyvinylchloride (PVC) in which micronized sucrose particles were dispersed. Effect of formula compositions of coating suspensions on the pharmaceutical characteristics such as membrane strength and dissolution was investigated in vitro. The membranes remained unbroken in pH 1.2 buffer at $37^{\circ}C$ at least for 2 hours after the disintergration test. TP was released from the coated-released tablets at a zero-order rate over 8 hours. The release at pH 1.2 and 4.0 was similar in rate but a little more rapid than that at pH 6.8. The coated tablets were administered to three healthy male volunteers and their saliva profiles of TP were compared with those from the commercial sustained release TP tablets such as Slobid and Asconthin. Saliva TP concentrations from the coated tablets were successfully sustained over 48 hours after the dosing and were comparable to those of the commercial sustained-release tablets. The membrane-coating technique is very simple and does not need any sophisticated equipments. In this respect, the membrane-coated tablets may be superior to the commercial sustained-release tablets and this technique is worth adopting by the pharmaceutical industries.

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Conservation Treatment and Deterioration Evaluation of the Namwon Singyeri Maaeyeoraejwasang (Rock-Carved Seated Buddha Statue), Korea (남원 신계리 마애여래좌상의 손상도 평가 및 보존처리)

  • Chun, Yu Gun;Lee, Myeong Seong;Lee, Jae Man;Lee, Jae Jin
    • Journal of Conservation Science
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    • v.29 no.4
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    • pp.321-332
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    • 2013
  • Namwon Singyeri Maaeyeoraejwasang (Rock-Carved Seated Buddha Statue) is composed mainly foliated granite and is different metamorphic grade and weathering degree on rock location. As the results of deterioration evaluation, upper part of the buddha statue was estimated that granularity decomposition was serious and rock strength was lower than lower part. Furthermore organism assessed most effect of among weathering factors. Chl. a amount of organism species were calculated $0.2{\mu}g/cm^2$ of crustaceous lichen, $1.1{\mu}g/cm^2$ of foliose lichen, $2.3{\mu}g/cm^2$ of bryophyte. Organism was taken treatment in order of amount of Chl. a and pre-cleaning, dry cleaning, wet cleaning in sequence. It should be establish conservation plan that strengthening in consideration of lithology characteristics and setting in good condition environment to conserve long-term of Maaeyeoraejwasang.

Effect of Different Delignification Degrees of Korean White Pine Wood on Fibrillation Efficiency and Tensile Properties of Nanopaper (잣나무의 탈리그닌 정도가 습식 해섬처리 효율 및 나노종이 인장 특성에 미치는 영향)

  • Park, Chan-Woo;Lee, Seo-Ho;Han, Song-Yi;Kim, Bo-Yeon;Jang, Jae-Hyuk;Kim, Nam-Hun;Lee, Seung-Hwan
    • Journal of the Korean Wood Science and Technology
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    • v.43 no.1
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    • pp.17-24
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    • 2015
  • In this study, the effect of delignification degree of Korean white pine wood on fibrillation efficiency by wet disk-milling (WDM) and the properties of thus-obtained microfibrillated cellulose (MFC) were investigated. The effect on the tensile properties of nanopaper was also investigated. The delignification degree was adjusted by repeating 'Wise' method using sodium chlorite and acetic acid. The increase in delignification degree improved fibrillation efficiency, showing the smaller nanofiber dimension at the shorter WDM time. The filtration time of MFC water suspension was increased by the increase of WDM cycles. Tensile strength and elastic modulus of the nanopaper were increased by increasing delignification degree and disk-milling cycles.

A study on the Freezing-Thawing Resistance for Repair Material of Concrete Structure (콘크리트 보수재료의 동결융해저항성에 관한 연구)

  • Lee, Bong-Chun;Chae, Sung-Tae;Jung, Sang-Hwa;Woo, Young-Je;Moon, Jae-Heum;Kim, Tae-Sang
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.621-624
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    • 2008
  • Repair materials which applied to the concrete structures may have different quality characteristics depending on the environmental factors. Evaluation on durability of domestic repair materials have not yet secured enough quality performance on durability, mainly due to the lack of test methods resulted from various environmental factors. In this study, we carried out the tests on freezing and thawing resistance of domestic repair materials with different environmental factors applied under BS EN 13687, and analyzed the results by comparing with Korea's national test standards(KS F 4716). The results indicate that after the repetition of dry and wet conditions and the test on freezing and thawing with salt immersion resistance bond strength might show great difference depending on the type of repair materials and the size of sample. For securing better quality performance of repair materials, it is required to establish various standards on the test methods of freezing and thawing resistance with different environmental factors applied.

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Study for Synthesis and Properties of Polyurethane Based on Polyester Polyol with Varying Hydroxyl Values for Automotive Pre-painted Metal Sheet Applications (자동차 선도장 강판용 폴리에스테르 폴리올 기반 폴리우레탄의 합성과 물성에 대한 연구)

  • Kang, Choong Yeol;Lee, Jae Young;Noh, Seung Man;Nam, Joon Hyun;Park, Jong Myung;Jung, Hyun Wook;Yu, Sang Soo
    • Journal of Adhesion and Interface
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    • v.12 no.1
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    • pp.34-42
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    • 2011
  • The roll coating process is well-known for completely replacement coating system with an existing wet paint process for automotive which has low productivity and is not environment-friendly process. It is very important to evaluate the curing behavior, corrosion resistance and processing property as well as rheological behavior in order to realize a film flexibility and hardness simultaneously. In this study, we have synthesized the polyester resin modified with hydroxyl values and molecular weight to apply the pre-painted system, and then evaluated the curing behavior, deep drawing, tensile strength and rheological properties. It was observed that N-0375-40 of 40 (mg KOH/mol) hydroxyl values showed the most suitable for flexibility, film hardness, and curing behavior.

Crack and Cutting Resistance Properties of Natural Rubber(NR) Compounds with Silica/Carbon Black Dual Phase Filler (Silica/Carbon Black이 충전된 NR 가황물의 내Crack 및 내Cutting 특성)

  • Son, Woo-Jung;Cho, Ur-Ryung;Kim, Won-Ho
    • Elastomers and Composites
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    • v.37 no.2
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    • pp.86-98
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    • 2002
  • The application of silica/carbon black dual phase fillers to natural rubber(NR) compound was investigated. When the amounts of filler content were restricted to 60phr, the optimum ratio of dual phase fillers were 25phr/35phr of silica/carbon black. It was found that these new fillers give better overall performance in comparison with carbon black in tear strength, crack resistance, and cutting resistance. Also the thermal degradation resistance of NR vulcanizates which were filled with dual phase fillers was better than that of the carbon black. Dual phase fillers filled NR vulcanizates showed better viscoelastic properties, like tan${\delta}$, for the wet skid resistance and rolling resistance of motor vehicle tires.

The effect of bacterial cellulose membrane compared with collagen membrane on guided bone regeneration

  • Lee, So-Hyoun;Lim, Youn-Mook;Jeong, Sung In;An, Sung-Jun;Kang, Seong-Soo;Jeong, Chang-Mo;Huh, Jung-Bo
    • The Journal of Advanced Prosthodontics
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    • v.7 no.6
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    • pp.484-495
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    • 2015
  • PURPOSE. This study was to evaluate the effects of bacterial cellulose (BC) membranes as a barrier membrane on guided bone regeneration (GBR) in comparison with those of the resorbable collagen membranes. MATERIALS AND METHODS. BC membranes were fabricated using biomimetic technology. Surface properties were analyzed, Mechanical properties were measured, in vitro cell proliferation test were performed with NIH3T3 cells and in vivo study were performed with rat calvarial defect and histomorphometric analysis was done. The Mann-Whitney U test and the Wilcoxon signed rank test was used (${\alpha}<.05$). RESULTS. BC membrane showed significantly higher mechanical properties such as wet tensile strength than collagen membrane and represented a three-dimensional multilayered structure cross-linked by nano-fibers with 60 % porosity. In vitro study, cell adhesion and proliferation were observed on BC membrane. However, morphology of the cells was found to be less differentiated, and the cell proliferation rate was lower than those of the cells on collagen membrane. In vivo study, the grafted BC membrane did not induce inflammatory response, and maintained adequate space for bone regeneration. An amount of new bone formation in defect region loaded with BC membrane was significantly similar to that of collagen membrane application. CONCLUSION. BC membrane has potential to be used as a barrier membrane, and efficacy of the membrane on GBR is comparable to that of collagen membrane.