• Title/Summary/Keyword: wet strength

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Synthesis and Characterization of Polyurethane for Artificial Leather Using Bio Polyol (바이오 폴리올을 이용한 인공피혁 코팅용 폴리우레탄의 합성 및 특성)

  • Sur, Suk-Hun;Choi, Pil-Jun;Ko, Jae-Wang;Lee, Jae-Yeon
    • Textile Coloration and Finishing
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    • v.30 no.4
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    • pp.321-328
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    • 2018
  • Wet polyurethane resin was synthesized by using polytrimethylene ether glycol prepared from 1,3-propanediol produced by fermentation from corn sugar as bio polyol and polyether-polyol(PTMG). Physical properties and cell characteristics by wet coagulation were investigated using the synthesized wet polyurethane resin. The tensile strength of wet polyurethane resin decreased with increasing content of bio polyol as copolymer polyol, but it tended to increase elongation at break and tear strength. As a result of thermal characteristic analysis, it was found that the glass transition temperature was slightly increased as the content of bio polyol increased. As a result of comparing the cell characteristics by the wet coagulation method, it was found that the shape of the cell was good when the ether polyol and the bio polyol were used alone.

The Effect of Coagulant on the Post Drawing and Morphology of Wet Spun Regenerated SF/Nylon 6 Blend Filaments

  • Um, In-Chul
    • International Journal of Industrial Entomology and Biomaterials
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    • v.16 no.2
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    • pp.61-66
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    • 2008
  • In this paper, the regenerated silk fibroin (SF)/nylon 6 blend filaments were fabricated using wet spinning technique and the effect of coagulant on the post drawing and morphology of blend filaments was investigated. In the result of wet spinnability, methanol, acetone, DMF, and THF showed relatively good coagulation strength and fiber formation for the regenerated SF. On the contrary, they did not exhibit strong enough to produce a uniform nylon 6 filament due to the lack of coagulation strength. In the examination of post drawing performance, methanol showed the highest maximum draw ratio of the blend filament over all blend ratios. The maximum draw ratio of SF/nylon 6 blend filaments decreased with the reduction of SF content regardless of type of coagulant. SEM observation showed the consistent result with that of post-drawing performance. As SF content decreased, the uniform and regular structure was changed to irregular one. In particular, the severe macro-phase separation between SF and nylon 6 could be detected in the 50/50 SF/nylon 6 blend filaments coagulated in methanol and THF.

Application of wood flour spacers for increasing OCC solid content in wet pressing process (II) (스페이서 사용에 의한 OCC 압착공정의 고형분 증대 (II))

  • Jung, Jae Kwon;Ji, Sung Jil;Seo, Yung Bum
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.3
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    • pp.24-33
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    • 2015
  • Linerboards containing wood flours were developed to increase solid contents in wet pressing process. Presence of wood flours in recycled fibers allowed passage of pressurized water at high wet pressing pressure, and increased solid contents while keeping the bulk of the board. The amount of wood flour addition should be controlled based on the intensity of the wet pressing pressure and the properties of the wood flours. Addition of cationic starch to the wood flour containing OCC furnish showed synergic increase of solid content and strength properties. Shapes of the wood flours such as spherical and rod type added to OCC furnish affected largely their solid content, drainage, and board physical properties.

A STUDY ON THE FRACTURE STRENGTH OF TEETH RESTORED WITH A CARBON FIBER POST UNDER CYCLIC LOADING (반복하중하에서의 carbon fiber post의 파절강도에 관한 연구)

  • Yi, Yang-Jin
    • The Journal of Korean Academy of Prosthodontics
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    • v.38 no.5
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    • pp.640-649
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    • 2000
  • In the restoration of endodontically treated teeth, carbon fiber post was recently introduced. The purpose of this in vitro study was to investigate the fracture strength of teeth restored with a pre-fabricated carbon fiber post in comparison with teeth restored with a prefabricated titanium post & custom cast gold post after cyclic loading in the different environment. A total of 30 recently extracted human central incisors of similar dimension with crowns removed were used. All teeth were placed into acrylic blocks and every steps for post and core fabrication were made accord-ing to manufacture's instruction. The post length and core dimensions were standardizd. All teeth were divided into 6 groups: 1) carbon fiber post / atmosphere, 2) titanium post / atmosphere, 3) gold post / atmosphere, 4) carbon fiber post / wet, 5) titanium post / wet, 6) gold post / wet. Carbon fiber post and titanium post were cemented in place using resin cement and cores were fabricated with Ti-Core. Custom cast gold post was made from Duralay pattern resin and cemented using resin cement, too. All specimens were thermocycled 10,000 times. After 50,000 cyclic loading, failure strength was measured using Instron testing machine. Kruskal-Wallis test followed by Mann-Whitney test was used to compare the mean fracture strength. Results were as follows : 1. All specimens showed lower fracture strength in wet environment after cyclic loading than in atmosphere condition, but did not reveal a significant difference. 2. There was no significant difference between carbon fiber post specimen and titanium post specimen in the same environment. 3. Gold cast post specimen showed significant different greater fracture strength than those of others in the same environment. 4. Carbon fiber post specimen showed no root fracture.

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Effects of Wet Pressing and Drying Conditions on Disintegration and Physical Properties of Paper (습부 압착과 건조 조건이 종이의 해리 특성 및 물성에 미치는 영향)

  • 김은영;원종명
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.35 no.2
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    • pp.12-17
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    • 2003
  • The effects of wet pressing and drying conditions on the disintegration and physical properties of paper were investigated in order to get the basic information on the resistance of paper for aqueous solution during converting processes. Wet pressing of unbeaten bleached softwood kraft pulp increased WRV at the range of grammage investigated. The increase of WRV with grammage at low wet pressing pressure(50 psi) was obvious, while it was not significant at higher wet pressing pressure(110 psi). The changes of WRV by drying were affected by the grammage and wet pressing pressure. The poorer disintegration of sheet, the higher wet pressing pressure and drying temperature. Although the strength properties were increased with the grammage, wet pressing pressure and drying temperature, results showed different trend from those of beaten pulp.

Enhancement of Paper Characteristics by Polyvinyl Alcohol/Polyamide-epichlorohydrin Coating as a Complex Strength Additive (Polyvinyl Alcohol/Polyamide-epichlorohydrin 복합 지력증강제에 의한 종이 특성 향상)

  • Jang, Yunjae;Lee, Hwaljong;Kang, Ho-Jong
    • Polymer(Korea)
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    • v.38 no.5
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    • pp.620-625
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    • 2014
  • The effect of polyvinyl alcohol/polyamide-epichlorohydrin (PVA/PAE) complex strengthening additive on dry and wet strength and surface properties of paper was investigated. The enhancements of dry and wet strength and dimensional stability were found when PVA/PAE was applied as a complex strengthening additive compared with the cases of applying individual PVA or PAE. This was understood as physical crosslinking between PVA and PAE in the PVA/PAE complex strength additive. This complex strengthening additive also lowered surface roughness and increased sizing. As a result, PVA/PAE complex strengthening additive provided the distinctive gain dot in printed papers.

Calcium Phosphate Bone Cement Based on Wet Prepared Dicalcium Phosphate

  • Chang, Myung Chul
    • Journal of the Korean Ceramic Society
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    • v.55 no.5
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    • pp.480-491
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    • 2018
  • Calcium phosphates (CaP) were prepared by a wet chemical method. Micro-crystalline dicalcium phosphate (DCPD) was precipitated at $37^{\circ}C$ and pH 5.0 using $Ca(OH)_2$ and $H_3PO_4$. The precipitated DCPD solution was kept at $37^{\circ}C$ for 96 h. Artificial bone cement was composed of DCPD, $Ca(H_2PO_4)_2{\cdot}H_2O$ (MCPM), and $CaSO_4{\cdot}1/2H_2O$, $H_2O$ and aqueous poly-phosphoric acid solution. The wet prepared CaP powder was used as a matrix for the bone cement recipe. With the addition of aqueous poly-phosphoric acid, the cement hardening reaction was started and the CaP bone cement blocks were fabricated for the mechanical strength measurement. For the tested blocks, the mechanical strength was measured using a universal testing machine, and the microstructure phase analysis was done by field emission scanning electron microscopy and X-ray diffraction. The cement hardening reaction occurred through the decomposition and recrystallization of MCPM and $CaSO_4{\cdot}1/2H_2O$ added on the surface of the wet prepared CaP, and this resulted in grain growth in the bone cement block.

Application of WCT(Wet Compaction Test) for Fiber Evaluation

  • Seo, Yung-B.;Ha, In-Ho;Lee, Chun-Han
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.38 no.5 s.118
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    • pp.9-15
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    • 2006
  • Wet compaction test (WCT) is a fiber evaluation method where wet fibers are compressed at one side of a cylinder and water drains out from the other side. The consistency of the fiber furnishes and their pressures are recorded during the test. In the previous study we found that WCT results always gave better coefficients of determination in fiber furnish drainage, and paper properties (density, tensile, tear, and burst strength) than those of WRV (water retention value). Fiber freeness and fiber length correlated well with drainage and tear strength of the furnishes, respectively; however, their correlations were very much improved by combining the WCT results. In this study, we used the WCT test for fractionated fiber furnishes to see whether improvement of the WCT is possible. We found that strength properties such as breaking length and burst index were correlated better with the fractionated long fiber furnishes. Drainage was greatly affected by the presence of short fiber furnishes. We used bleached chemical pulps (SwBKP, HwBKP), recycled pulp (OCC), and mechanical pulp (BCTMP) as fiber furnishes in this study. Fiber fractionation can be performed on-line in these days by using multifractor and WCT can be used as an on-line test in papermachine in the future.

Physical Properties of Poly(vinyl alcohol) with Polyamide-epichlorohydrin as a Wet Strength Additive for Paper (Polyamide-epichlorohydrin 지력 증강제 함유 폴리비닐알코올의 물성 연구)

  • Jang, Yunjae;Lee, Hwaljong;Kang, Ho-Jong
    • Polymer(Korea)
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    • v.37 no.6
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    • pp.730-735
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    • 2013
  • The physical properties of poly(vinyl alcohol) (PVA) with polyamide-epichlorohydrin (PAE) for wet strength additives in paper industry were investigated. Upon introducing PAE to PVA, not only melting and crystallization enthalpy in DSC but also the area of diffraction peaks in XRD decreased, which represented the fact that PAE acted as a crosslinking agent for PVA. However, this crosslinking seemed to be physical crosslinking having relatively less bonding energy compared to chemical crosslinking since the crystallization in PVA was able to take place by thermal annealing. This physical crosslinking and crystallization by thermal annealing enhanced the thermal stability and mechanical strength in PVA and consequently, these improvements are desired in the paper manufacturing process to increase the dry and wet strength in the paper.

Temperature Distribution of Wet-Mixed High Strength Sprayed Polymer Mortar for Fire Resistance of Tunnel (터널 내화용 고강도 습식 스프레이 폴리머 모르타르의 화재 발생시 내부온도분포)

  • Won, Jong Pil;Choi, Seok Won;Park, Chan Gi;Park, Hae Kyun
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.4C
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    • pp.283-290
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    • 2006
  • Concrete has advantages in fire situations as it is non-combustible and has low thermal conductivity. However, concrete that is not designed against fire can experience significant explosive spalling from the build-up of pore pressures and internal tensile stresses when heated. In this study, the performance of wet-mixed high strength sprayed polymer mortar for fire resistance of tunnel system was evaluated by experimentally and numerically. The fire test was performed in fire resistance(electric) furnace according to RABT(Richtlinien fur die Ausstatung und den Betrieb von $Stra{\beta}entunneln$) time heating temperature curve, so as to evaluate the temperature distribution with cover thickness of wet-mixed high strength sprayed polymer mortar for fire resistance of tunnel system. Based on experimental results and numerical analysis, the proper cover thickness of wet-mixed high strength sprayed polymer mortar determined the more than 4cm.