• 펄프종이기술
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• 제46권3호
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• pp.73-80
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• 2014

In this study, in order to investigate the influence of insolubilizer on the double coating structure, we carried out basic research related to the double coating formulation with four insolubilizers having various chemical types such as amino aldehyde, glyoxal and two metallic salts. It was found that although the four insolubilizers showed similar results on optical and surface properties of the coated papers, they gave different results in the printabilities of the coated papers since coating structure was significantly influenced by different reacting mechanism of the insolubilizers. Three of the insolubilizers (glyoxal, two metallic salts) showed better results than amino aldehyde type one when they were applied to top coating formulation. Metallic salts type insolubilizers showed good results in the print gloss when it was applied to top coating formulation. It was believed that amino aldehyde type insolubilizer applied top coating formulation showed good both of dry-pick and wet-pick strength.

• 한국염색가공학회지
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• 제23권1호
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• pp.51-59
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• 2011

Calcium alginate fiber were prepared by wet spinning of various conditions, including different concentrations of sodium alginate solution and $CaCl_2$ concentrations for coagulating the fiber through an absorption of calcium ion. The absorption of calcium ion during the coagulating step lead to solidify the fibers by the replacement of sodium ion with calcium ion to produce some crosslinking. The concentration of calcium ion in the calcium alginate fiber seems to be well related to the mechanical and physical property of the fiber, such as fiber strength moisture regain, and degree of swelling. The tensile strength of calcium alginate fiber was increased along with the increasing amount of sodium alginate solution. According to EDS analysis, 7 wt% $CaCl_2$ coagulation bath resulted in more calcium ion in the fiber compared to 3 wt% $CaCl_2$ coagulation bath. The decomposition temperature of calcium alginate fiber was $199^{\circ}C$, which $14^{\circ}C$ higher than that of sodium alginate.

• 한국염색가공학회지
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• 제19권4호
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• pp.10-17
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• 2007

Chitosan(CS) and cellulose acetate(CA) composite films were prepared using formic acid as a cosolvent by casting, solvent evaporating and neutralization method. This study examines if the blending method, which uses formic acid as a cosolvent is efficient in improving the mechanical properties of CS film, especially wet strength and elongation. Formic acid is an effective cosolvent for the blend of CS and CA. Under wet condition, tensile strength and elongation of the composite films were obviously higher than those of the films made from pure CS. FTIR, DSC, and X-ray diffraction showed that the composite films exhibit a high level of compatibility and that strong interaction between the CS and CA was caused by intermolecular hydrogen bonding. The affinity series of composite film to transition metal ions are Cu(II) > Cd(II) > Cr(III). The adsorption of Cu((II) ion was shown to be highly pH sensitive.

• 한국세라믹학회지
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• 제53권6호
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• pp.670-675
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• 2016

Calcium phosphate crystallites were prepared by wet chemical method for use in artificial bone. In order to obtain ${\beta}$-tricalcium phosphate (TCP), nano-crystalline calcium phosphate (CaP) was precipitated at $37^{\circ}C$ and at $pH5.0{\pm}0.1$ under stirring using highly active $Ca(OH)_2$ in DI water and an aqueous solution of $H_3PO_4$. The precipitated nano-crystalline CaP solution was kept at $90^{\circ}C$ for the growth of CaP crystallites. Through the growing process of CaP crystallites, we were able to obtain various sizes of rectangular CaP crystallites according to the crystal growing times. Dry nano-crystalline CaP powders at $37^{\circ}C$ were mixed with dry macro-crystalline CaP crystallites and the shaped mixture sample was fired at $1150^{\circ}C$ to make a ${\beta}-TCP$ block. Several tens of nm powders were uniformly coated on the surface, which was comprised of powders of several tens of ${\mu}m$, using a vibrator. The mixing ratio between the nanometer powders and the micrometer powders greatly affected the mechanical strength of the mixture block; the most appropriate ratio of these two materials was 50 wt% to 50 wt%. The sintered block showed improved mechanical strength, which was caused by the solid state interaction between the nano-crystalline ${\beta}-TCP$ and the macro-crystalline ${\beta}-TCP$.

• Computers and Concrete
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• 제31권6호
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• pp.501-511
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• 2023

The strengthening efficiency of biopolymer treated soil depends on biopolymer type, concentration ratio, soil type, initial water content, curing time and mixing method. In this study, the physical and mechanical properties of xanthan gum (XG) treated kaolinite were investigated through compaction test, Atterberg limit test, triaxial test and unconfined compression test. The results indicated that the optimum water content (OWC) increased from 30.3% of untreated clay to 33.5% of 5% XG treated clay, while the maximum dry density has a slight increase from 13.96 kg/m³ to 14 kg/m³ of 0.2% XG treated clay and decrease to 2.7 kg/m³ of 5% XG treated clay. Meanwhile, the plastic limit of XG treated clay increased with the increase of XG concentration, while 0.5% XG treated clay can be observed the maximum liquid limit with 79.5%. Moreover, there are the ideal water content about 1.3-1.5 times of the optimum water content achieving the maximum dry density and curing time to obtain the maximum compressive strength for different XG contents, which the UCS is 1.52 and 2.07 times of the maximum UCS of untreated soil for 0.5% and 1% XG treated clay, respectively. In addition, hot-dry mixing can achieve highest UCS than other mixing methods (e.g., dry mixing, wet mixing and hot-wet mixing).

• 접착 및 계면
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• 제10권2호
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• pp.84-89
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• 2009

The objective of this research was to investigate the curing behavior and adhesion performance of urea-melamine-formaldehyde (UMF) resin for the four types of UMF-1, UMF-2, UMF-3, and UMF-4 which synthesized by the staged addition of melamine. Also, various network structures of these resin types were discussed based on their different curing behavior and adhesion performance. The curing behavior was evaluated by DMTA and thermal stability was checked by TGA. Adhesion performance was evaluated by dry and wet shear strengths and the pH value of each cured resin was checked to see its effect on the adhesion performance. The results indicated that the UMF-1 resin type by the addition of melamine initially with the urea and formaldehyde at the same F/(U+M) rate showed the lowest thermal stability, rigidity (${\Delta}E^{\prime}$), temperature of tan ${\delta}$ maximum ($T_{tan}\;_{\delta}$), and wet shear strength, and pH value of cured resin. In wet shear strength, however, the UMF-4 resin type appears to be slightly higher than UMF-1 resin type.

• Journal of the Korean Wood Science and Technology
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• 제39권6호
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• pp.498-504
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• 2011

The purpose of this study was to investigate and develop an eco-frendly wood adhesive based on vegetable oil (especially soybean oil), the renewable and sustainable natural resources, using ozonification technology for the chemical structure modification. The waste soybean oil (WSBO) was reacted with $O_3$ at the rate of $450m{\ell}$(acetone) : $50m{\ell}$ (WSBO) for different times, 1, 2, 3 hrs. The investigation of the modified chemical strecture of the ozonied WSBOs were conducted using FT-IR. As ozonification time increased, the peak of the unsaturated double bonds was disappeared especially ozonized-3hrs and aldehyde or carboxyl peak appeared because ozonification broke the oil into small molecules. The plywood were made at $150^{\circ}C$ with 4 minutes hot-press time using the different ozonized 3 hrs WSBO/pMDI adhesives and were tested for the dry, wet, cyclic boil test according to the Korea Industrial Standard F3101 Ordinary plywood. The bond strengths gradually increased until 1 : 0.5~1 : 3, but it decreased 1 : 4, as the contents of pMDI increased. The results of the dry, wet and cyclic bond strengths the equivalent ratio was formed approximately between 1 : 2~1 : 3. And the 1 : 1~1 : 4 strengths met constantly the standard requirement of 7.0kgf/$cm^2$ (KS F3101). From the comprehensive view on the results of above experiment, it could be confirmed that ozonized WSBO/pMDI has characteristics of effective reactivity and wet stability showed as an excellent candidate of wood adhesive applications.

• 한국구조물진단유지관리공학회 논문집
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• 제9권1호
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• pp.251-258
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• 2005

지금까지의 대부분의 방수 방식 및 보수 등의 보호마감설계는 외부환경으로부터 콘크리트의 보호차원에서 목표재료성능을 중시 하였으나 시공과정에서 콘크리트바탕자체와의 상응성을 충분히 검토하지 못함으로서 그 요구수명을 다하지 못한 사례가 많다. 따라서 본 연구는 상하수시설 및 항만시설 등과 같은 콘크리트구조물에 있어서 콘크리트를 보호하기 위한 방식피복재의 내구성으로 수밀성, 내화학성 및 내마모성의 평가 결과 방식피복재 A 및 B형 모두 성능이 우수한 것으로 나타났다. 또한 바탕의 건조/습윤 조건, 방식피복재 도포후의 양생조건 및 다양한 온도조건에서 부착성능을 평가한 결과, 모든 경우에 있어서 기준치인 부착강도 $15kgf/cm^2$보다 정도 큰 값을 나타내었다. 또한 현장 적용성 평가로 실구조물 2곳에 대한 시험시공 결과 방식피복재 A 및 B형 모두 기준값 이상으로, 상하수도 및 지하철 시설물과 같은 콘크리트 구조물의 방수 방식 및 보수재료로서 사용이 적합한 것으로 판단된다.

• 한국의류학회지
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• 제45권6호
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• pp.1035-1051
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• 2021

This study compares the strength properties of Jumchi-Hanjis dyed with 70% and 100% persimmon juice concentrations and undyed Jumchi-Hanjis. The Juumchi-Hanjis were made from Dakjis (mulberry papers), which were mixed with different ratios of fibers from paper mulberries originating in Korea and Thailand, including wood pulp from Canada. Research results showed that tensile, wet tensile, and bursting strengths of Jumchi-Hanjis dyed with 70% concentration were higher than those of undyed Jumchi-Hanjis. However, the tearing strengths of the dyed Jumchi-Hanjis were lower than those of undyed Jumchi-Hanjis. The wet tensile strengths of Jumchi-Hanjis dyed with 100% concentration were higher than those of dyed with 70% concentration. The increase and decrease of tensile, tearing, and bursting strengths depending on persimmon juice dyeing differed as per the mixing ratio of the raw materials of Jumchi-Hanjis. Dyeing with 100% persimmon juice concentration tends to be more useful than 70% to increase the tensile (MD) and wet tensile strengths of Jumchi-Hanjis containing only Korean mulberry fibers (90%) and wood pulp (10%) as raw materials. Dyeing with 100% concentration tends to be less useful than 70% to increase the tensile, tearing and bursting strengths of Jumchi-Hanjis with high proportions (90% or 60%) of mulberry fibers from Thailand.

• Geomechanics and Engineering
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• 제36권6호
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• pp.619-629
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• 2024

To improve the utilization rate of phosphate tailings (PTs) and widen the sources of subgrade filler, the PTs is employed to modify clay, forming a PTs modified clay, applied in the subgrade. Accordingly, the environmental friendliness of PTs was investigated. Subsequently, an optimal proportion was determined through compaction and California Bearing Ratio (CBR) experiments. Afterward, the stability of mixture with the optimal proportion was further evaluated through the water stability and dry-wet stability experiments. Finally, via the gradation and microstructure experiments, the strength mechanism of PTs modified clay was analyzed. The results show that the PTs were classified in the non-hazardous solid wastes, belonging to Class A building materials. With the increase of PTs content and the decrease of clay content, the optimum water content and the swelling degree gradually decrease, while the maximum dry density and CBR first increase and then decrease, reaching their peak value at 50% PTs content, which is the optimal proportion. The resilient modulus of PTs modified clay at the optimal proportion reaches 110.2 MPa. The water stability coefficient becomes stable after soaking for 4 days, while the dry-wet stability coefficient decreases with the increase of cycles and tends to be stable after 8 cycles. Under the long-term action, the dry-wet change has a greater adverse impact than continuous soaking. The analysis demonstrates that the better strength mainly comes from the skeleton role of PTs and the cementation of clay. The systematic laboratory test results and economic analysis collectively provide data evidence for the advantages of PTs modified clay as a subgrade filler.