• Title/Summary/Keyword: well diffusion

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Fabrication and Characteristics of $P^+N$ and $P^+NN^+$ Junction Silicon Solar Cell ($P^+N, P^+NN^+$ 접합형 실리콘 태양전지의 제작 및 특성)

  • Lee, Dae-U;Lee, Jong-Deok;Kim, Gi-Won
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.20 no.1
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    • pp.22-26
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    • 1983
  • P+N and P+NN+ solar cells with the area of 3.36 $\textrm{cm}^2$ were fabricated by thermal diffusion. Under the light intensity of 100 mW/$\textrm{cm}^2$, total area(active area) conversion efficiency was 13.4%(14.7%) for P+N cell fabricated by 15 min boron predeposition at 94$0^{\circ}C$ and 20 min annealing at 80$0^{\circ}C$, and 14.3%(15.6%) for P+NN+ cell processed by 15 min boron predeposition at 94$0^{\circ}C$ and 50 min annealing at 80$0^{\circ}C$ after 20 min back phosphorus diffusion at 1,05$0^{\circ}C$. The minority carrier lifetime in bulk of P+NN+ cells was increased about 2~3 times comparing with P+N cells because of guttering and BSF effect due to back phosphorus doping. The methods used for efficiency improvement were AR coating, Ag electroplating, back doping and fine grid pattern as well as the control of front doping profile.

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Validation of a Real-Time Dose Assessment System over Complex Terrain (복잡한 지형상에서 실시간 피폭해석 시스템 검증)

  • Suh, Kyung-Suk;Kim, Eun-Han;Hwang, Won-Tae;Choi, Young-Gil;Han, Moon-Hee;Jung, Sung-Tae
    • Journal of Radiation Protection and Research
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    • v.24 no.1
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    • pp.31-38
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    • 1999
  • A real-time dose assessment system(FADAS : Following Accident Dose Assessment System) has been developed for the real-time accident consequence assessment against a nuclear accident. Field tracer experiment near Younggwang nuclear power plant was performed to improve the accuracy of developed system and to parameterize the site-specific parameters into the FADAS. The mean values and turbulent components of wind profile obtained through field experiment have been reflected to FADAS with site-specific conditions. The simulated results of diffusion model agreed well with the measured data through tracer experiment. The developed system is being used as a basic module of emergency preparedness system in Korea. The diffusion model which can be reflected site-specific parameters will be improved through field experiments continuously.

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Effects of various densities and velocities on gaseous hydrocarbon fuel on near nozzle flow field under different laminar coflow diffusion flames

  • Ngorn, Thou;Jang, Sehyun;Yun, Seok Hun;Park, Seol Hyeon;Lee, Joo Hee;Chung, Suk Ho;Choi, Jae Hyuk
    • Journal of Advanced Marine Engineering and Technology
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    • v.40 no.2
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    • pp.102-106
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    • 2016
  • An experimental study on the flow characteristics under various laminar coflow diffusion flames was conducted with a particular focus on the buoyancy force exerted from gaseous hydrocarbon fuels. Methane ($CH_4$), ethylene ($C_2H_4$), and n-butane ($C_4H_{10}$) were used as the fuels. A coflow burner and the Schlieren imaging technique were used to observe the flow field of each fuel near the nozzle exit as well as the flow characteristics in the flames. The results show that a vortex with a density heavier than air appeared in n-butane near the nozzle exit with a strong negative buoyancy on the fuel steam. As the Reynolds number increased through the control of the fuel velocity of the n-butane flame, the vortices were greater and the vortex tips were moved up from the nozzle exit. In addition, the heated nozzle affected the flow fields of the fuel steam near the nozzle exit.

A Study on the Computational Simulation of Cyclic Voltammetry using Semi-infinite Diffusion Model (반무한 확산모델을 이용한 순환전위법의 전산모사에 관한 연구)

  • Cho, Ha-Na;Kim, Tae-Yong;Yoon, Do-Young
    • Journal of the Korean Electrochemical Society
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    • v.14 no.3
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    • pp.138-144
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    • 2011
  • The transport phenomena of electron and ion around the electrode have been analyzed, herein the computational program to simulate the electrochemical signal of cyclic voltammetry has been implemented. For the dominant mass-transfer system, the governing equation and its boundary conditions are confined to the semi-infinite diffusion model and the reversible reaction at the electrode. In order to obtain the numerical solutions of cyclic voltammetry, MATLAB was used for the explicit finite difference method. Experimental results from the cyclic voltammetry of electrochemical system(10 mM $K_3Fe(CN)_6$ and 0.1M KCl) upon the ITO glass substrate were compared with the numerical solutions. Present program explains the experimental results fairly well, where they approached the simulated ones closely with deceasing the scan rate. Furthermore, the effects of electrode area, electrochemical reaction constants and transfering coefficients in the cyclic voltammetry were discussed quantitatively.

Trends in Sex Ratio at Birth according to Parental Social Positions: Results from Vital Statistics Birth, 1981-2004 in Korea (부모의 사회경제적 위치에 따른 자녀의 출생 성비 추이: 1981년부터 2004년까지)

  • Chun, Hee-Ran;Kim, Il-Ho;Khang, Young-Ho
    • Journal of Preventive Medicine and Public Health
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    • v.42 no.2
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    • pp.143-150
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    • 2009
  • Objectives : South Korea has experienced unprecedented ups and downs in the sex ratio at birth(SRB), which has been a unique phenomenon in the last two decades. However, little is known about socioeconomic factors that influence the SRB. Employing the diffusion theory by Rogers, this study was undertaken to examine the trends in social variations in the SRB from 1981 to 2004 in Korea. Methods : The data was taken from Vital Birth Statistics for the period from 1981-2004. We computed the annual male proportion of live births according to the parental education(university, middle/high school, primary) and occupation(non-manual, manual, others). Logistic regression analysis was employed to estimate the odds ratios of male birth according to social position for the equidistant three time periods(1981-1984, 1991-1994, and 2001-2004). Results : An increased SRB was detected among parents with higher social position before the mid 1980s. Since then, however, a greater SRB was found for the less educated and manual jobholders. The inverse social gradient for the SRB was most prominent in early 1990s, but the gap has narrowed since the late 1990s. The mother's socioeconomic position could be a sensitive indicator of the social variations in the sex ratio at birth. Conclusions : Changes in the relationship of parental social position with the SRB were detected during the 1980-2004 in Korea. This Korean experience may well be explained by diffusion theory, suggesting there have been socioeconomic differences in the adoption and spread of sex-detection technology.

Adsorption Characteristics of Non-degradable Eosin Y Dye by Carbon Nano Tubes (Carbon Nano Tubes에 의한 난분해성 염료 Eosin Y의 흡착 특성)

  • Lee, Min-Gyu;Yun, Jong-Won;Suh, Jung-Ho
    • Korean Chemical Engineering Research
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    • v.55 no.6
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    • pp.771-777
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    • 2017
  • Adsorption characteristics of Eosin Y dye by carbon nano tubes (CNTs) were examined through batch experiments. CNTs used in the study had specific surface area of $106.9m^2/g$, porosity volume of $1.806cm^3/g$, and porosity diameter of $163.2{\AA}$, respectively. Adsorption experiments were carried out as function of contact time, initial solution pH (2~10), dye concentration (100, 150 and 200 mg/L), adsorbent dose (0.05~1.0 g) and temperature (293, 313 and 333 K). The adsorption was favoured at lower pHs and temperatures. Adsorption data were well described by the Langmuir model. The adsorption process followed the pseudo-second order kinetic model. The adsorption capacity decreased with increase in temperature. The results of the intraparticle diffusion model suggested that film diffusion and particle diffusion were simultaneously occured during the adsorption process. Thermodynamic studies suggested the spontaneous and endothermic nature of adsorption of Eosin Y dye onto CNTs.

Numerical Model of One-Dimensional Advection-Diffusion Equation Applying Split-Operator Method (연산자 분리기법에 의한 1차원 이송-확산방정식의 수치모형)

  • Lee, Jeong-Gyu;Gang, Chang-Gu;Lee, Jong-In
    • Journal of Korea Water Resources Association
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    • v.30 no.2
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    • pp.143-154
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    • 1997
  • A numerical model for solving advection-diffusion equation is presented by splitoperator method combining the Holly-Preissmann scheme with a fifth-degree interpolating polynomial for advection operator and the explicit scheme porposed by Hobson et al. for diffusion operator. To examine the developed model, the obtained numerical solutions are compared with both the analytic solution and those from the existing models for the instantaneous source (Gaussian hill) and the continuous source (advanced front) at upstream boundary with constant velocity and diffusivity condition. For the various cases having different Courant and Peclet numbers, it is shown that the present study provides stable solutions even for Courant numbers exceeding one. The result obtained by the present study also agree well with existing analytical solutions for both cases. The proposed explicit scheme somewhat releases the conventional restriction of explicit schemes for determining the time step size and provides satisfactory results for relatively large time step size.

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Collisionless Magnetic Reconnection and Dynamo Processes in a Spatially Rotating Magnetic Field

  • Lee, Junggi;Choe, G.S.;Song, Inhyeok
    • The Bulletin of The Korean Astronomical Society
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    • v.41 no.1
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    • pp.45.1-45.1
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    • 2016
  • Spatially rotating magnetic fields have been observed in the solar wind and in the Earth's magnetopause as well as in reversed field pinch (RFP) devices. Such field configurations have a similarity with extended current layers having a spatially varying plasma pressure instead of the spatially varying guide field. It is thus expected that magnetic reconnection may take place in a rotating magnetic field no less than in an extended current layer. We have investigated the spontaneous evolution of a collisionless plasma system embedding a rotating magnetic field with a two-and-a-half-dimensional electromagnetic particle-in-cell (PIC) simulation. In magnetohydrodynamics, magnetic flux can be decreased by diffusion in O-lines. In kinetic physics, however, an asymmetry of the velocity distribution function can generate new magnetic flux near O- and X-lines, hence a dynamo effect. We have found that a magnetic-flux-reducing diffusion phase and a magnetic-flux-increasing dynamo phase are alternating with a certain period. The temperature of the system also varies with the same period, showing a similarity to sawtooth oscillations in tokamaks. We have shown that a modified theory of sawtooth oscillations can explain the periodic behavior observed in the simulation. A strong guide field distorts the current layer as was observed in laboratory experiments. This distortion is smoothed out as magnetic islands fade away by the O-line diffusion, but is soon strengthened by the growth of magnetic islands. These processes are all repeating with a fixed period. Our results suggest that a rotating magnetic field configuration continuously undergoes deformation and relaxation in a short time-scale although it might look rather steady in a long-term view.

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Modified Shrinking Core Model for Atomic Layer Deposition of TiO2 on Porous Alumina with Ultrahigh Aspect Ratio

  • Park, Inhye;Leem, Jina;Lee, Hoo-Yong;Min, Yo-Sep
    • Bulletin of the Korean Chemical Society
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    • v.34 no.2
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    • pp.519-523
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    • 2013
  • When atomic layer deposition (ALD) is performed on a porous material by using an organometallic precursor, minimum exposure time of the precursor for complete coverage becomes much longer since the ALD is limited by Knudsen diffusion in the pores. In the previous report by Min et al. (Ref. 23), shrinking core model (SCM) was proposed to predict the minimum exposure time of diethylzinc for ZnO ALD on a porous cylindrical alumina monolith. According to the SCM, the minimum exposure time of the precursor is influenced by volumetric density of adsorption sites, effective diffusion coefficient, precursor concentration in gas phase and size of the porous monolith. Here we modify the SCM in order to consider undesirable adsorption of byproduct molecules. $TiO_2$ ALD was performed on the cylindrical alumina monolith by using titanium tetrachloride ($TiCl_4$) and water. We observed that the byproduct (i.e., HCl) of $TiO_2$ ALD can chemically adsorb on adsorption sites, unlike the behavior of the byproduct (i.e., ethane) of ZnO ALD. Consequently, the minimum exposure time of $TiCl_4$ (~16 min) was significantly much shorter than that (~71 min) of DEZ. The predicted minimum exposure time by the modified SCM well agrees with the observed time. In addition, the modified SCM gives an effective diffusion coefficient of $TiCl_4$ of ${\sim}1.78{\times}10^{-2}\;cm^2/s$ in the porous alumina monolith.

The Stress Distribution Analysis of PEMFC GDL using FEM (유한요소법을 이용한 고분자전해질연료전지 기체확산층의 응력분포 연구)

  • Kim, Chulhyun;Sohn, Youngjun;Park, Gugon;Kim, Minjin;Lee, Jonguk;Kim, Changsoo;Choi, Yusong;Cho, Sungbaek
    • Transactions of the Korean hydrogen and new energy society
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    • v.23 no.5
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    • pp.468-475
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    • 2012
  • A proper stacking force and assembly are important to the performance of fuel cell. Improper assembly pressure may lead to leakage of fuels and high interfacial contact resistance, excessive assembly pressure may result in damage to the gas diffusion layer and other components. The pressure distribution of gas diffusion layer is important to make interfacial contact resistance less for stack performance. To analyze the influence of design parameter factors for pressure distribution, and to optimize stack design, DOE (Design of Experiment) was used for polymer electrolyte membrane fuel cell stack pressure test. As commonly known, the higher clamping force improves the fuel cell stack performance. However, non-uniformity of stress distribution is also increased. It shows that optimization between clamping force and stress distribution is needed for well designed structure of fuel cell stack. In this study, stack design optimization method is suggested by using FEM (Finite Element Methode) and DOE for light-weighted fuel cell stack.