• 한국공작기계학회논문집
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• 제16권4호
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• pp.1-12
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• 2007

S45C steel has been widely used in industrial applications, such as crank shafts, gears, main spindles of machine tools, connecting rods, etc., because of its distinguished mechanical property. In the convention arc welding of S45C plates without heat treatments, it is possible for welding defects to take place, such as a void or a hot-crack, due to a high carbon composition of S45C. Laser welding process is widely used in the industrial field due to its numerous advantages: a small heat affected zone(HAZ), deep penetration, high welding speed, single-pass thick section capability, and small distortion after welding. The objective of this research works is to investigate the influence of the process parameters, such as power of laser and welding speed, on the characteristics of laser welding for the case of nickel coated and nickel uncoated S45C steel. As the result of the experiment, in case of butt welding, nickel coated S45C steel has a uniform formation of welding zone and it was judged that the welding nature was better as inner defects and the quantity of spatter were formed relatively fewer than nickel uncoated S45C steel.

• 대한화학회지
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• 제35권2호
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• pp.158-164
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• 1991

염기성용액 중의 수은전극에서 o-cresolphthalexon(OCP)의 전기화학적 거동을 직류, 펄스차이 폴라로그래피, 정전위 전해 및 순환 전압전류법으로 조사하였다. OCP는 NaCl 지지전해질에서 1전자 2단계 환원반응을 하였으며, 반파전위는 pH에 따라 변화하였다. 순환 전압전류법에 따라 고찰한 결과 첫번째 1전자 환원반응을 뒤에 형성된 라디칼은 이합체화 반응을 하였으며, 표준 속도상수는 $3.27{\times}10^{-2}$ cm/sec로 가역반응을 나타냈다. 두번째 환원반응은 전자전이반응에 이어 생성된 carbanion의 빠른 양성자화 첨가반응으로 비가역적 거동을 나타냈다. OCP의 농도(<$1{\times}10^{-4}$M)가 낮은 경우 흡착현상이 현저하게 일어났으며, -1.85V에서 정전위 전해시 전해시간이 증가함에 따라 OCP의 자주색은 점점 옅어져서 무색이 되었으며, 최종생성물은 전기적으로 불활성이 되었다. 따라서 OCP의 단계적인 전극반응은 ECEC 메카니즘으로 제안된다.

• Journal of Magnetics
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• 제20권3호
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• pp.229-240
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• 2015

In this study, nanocrystalline ferrite powders with the composition $Ni_{0.5}Zn_{0.5}Fe_2O_4$ were prepared by the autocombustion method. The obtained powders were sintered at $800^{\circ}C$, $900^{\circ}C$ and $1,000^{\circ}C$ for 4 h in air atmosphere. The as-prepared and the sintered powders were characterized by X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy, and magnetization studies. An increase in the crystallite size and a slight decrease in the lattice constant with sintering temperature were observed, whereas microstrain was observed to be negative for all the samples. Two significant absorption bands in the wave number range of the $400cm^{-1}$ to $600cm^{-1}$ have been observed in the FT-IR spectra for all samples which is the distinctive feature of the spinel ferrites. The force constants were found to vary with sintering temperature, suggesting a cation redistribution and modification in the unit cell of the spinel. The M-H loops indicate smaller coercivity, which is the typical nature of the soft ferrites. The observed variation in the saturation magnetization and coercivity with sintering temperature has been attributed to the role of surface, inhomogeneous cation distribution, and increase in the crystallite size.

• 한국환경과학회지
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• 제19권3호
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• pp.379-387
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• 2010

Sediments of Little Scioto (LS) River in Ohio was contaminated by poor disposal of creosote from Baker Wood Creosoting Facility. Among the primary compounds of creosote, Polycyclic Aromatic Hydrocarbons (PAHs) are the most common ingredient PAHs are known for toxic, carcinogenic and mutagenic compounds. There are many difficulties to remove the PAHs in nature environment because their characteristics are having a less water-solubility, volatile and low mobility properties as increasing the molecular weight. The generation of hydroxyl radicals (${\cdot}OH$) and hydrogen peroxide ($H_2O_2$) forms as well as high temperature (5000 K) and pressure (1000 atm) by a physico-chemical effects of ultrasound during a cavitation collapse can promote the degradation and desorption of PAHs in sediment And it can also produces shock wave and microjets which are able to change the size and surface of particle in solid-liquid system as one of physical effects. Therefore, we explored to understand the role of particle size, the effect of elimination for PAHs concentration by ultrasound and optimize the conditions for ultrasonic treatment. The condition of various size of particles (> $150{\mu}m$, < $150{\mu}m$) and solid-liquid ratio (12.5g/L, 25g/L) for the treatment was considered and ultrasonic power (430 W/L) with liquid - hexane extraction and microwave extraction method were applied after ultrasound treatment.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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• pp.370.1-370.1
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• 2014

Giant magnetoresistance (GMR), tunneling magnetoresistance (TMR), and magnetic random-access memory (MRAM) are currently active areas of research. Magnetite, Fe3O4, is predicted to possess as half-metallic nature, ~100% spin polarization (P), and has a high Curie temperature (TC~850 K). On the other hand, Spinel ferrite CoFe2O4 has been widely studies for various applications such as magnetorestrictive sensors, microwave devices, biomolecular drug delivery, and electronic devices, due to its large magnetocrystalline anisotropy, chemical stability, and unique nonlinear spin-wave properties. Here we have investigated the magneto-transport properties of epitaxial CoxFe3-xO4 thin films. The epitaxial CoxFe3-xO4 (x=0; 0.4; 0.6; 1) thin films were successfully grown on MgO (100) substrate by molecular beam epitaxy (MBE). The quality of the films during growth was monitored by reflection high electron energy diffraction (RHEED). From temperature dependent resistivity measurement, we observed that the Werwey transition (1st order metal-insulator transition) temperature increased with increasing x and the resistivity of film also increased with the increasing x up to $1.6{\Omega}-cm$ for x=1. The magnetoresistance (MR) was measured with magnetic field applied perpendicular to film. A negative transverse MR was disappeared with x=0.6 and 1. Anomalous Hall data will be discussed.

• 한국재료학회지
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• 제25권12호
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• pp.659-665
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• 2015

The self-propagating high temperature synthesis approach was applied to synthesize amorphous boron nano-powders in argon atmospheres. For this purpose, we investigated the characteristics of a thermally induced combustion wave in the $B_2O_3+{\alpha}Mg$ system(${\alpha}=1.0-8.0$) in an argon atmospheres. In this study, the exothermic nature of the $B_2O_3-Mg$ reaction was investigated using thermodynamic calculations. Experimental study was conducted based on the calculation data and the SHS products consisting of crystalline boron and other compounds were obtained starting with a different initial molar ratio of Mg. It was found that the $B_2O_3$ and Mg reaction system produced a high combustion temperature with a rapid combustion reaction. In order to regulate the combustion reaction, NaCl, $Na_2B_4O_7$ and $H_3BO_3$ additives were investigated as diluents. In an experimental study, it was found that all diluents effectively stabilized the reaction regime. The final product of the $B_2O_3+{\alpha}Mg$ system with 0.5 mole $Na_2B_4O_7$ was identified to be amorphous boron nano-powders(< 100 nm).

• 상하수도학회지
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• 제28권6호
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• pp.647-655
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• 2014

To perform long-term sewer monitoring, It is important to understand the nature of the wastewater flow that occurs at the point on early stage of the monitor and to prevent in advance a problem which may caused. We can infer the flow properties and external factors by analyzing the scatter graph obtained from the measured data flow rate monitoring data since an field external factor affecting the sewage flow is reflected in the flow rate monitoring data. In this study, Selecting the three points having various external factors, and we Inferred the sewer flow characteristics from depth-velocity scatter graph and determined the analysis equation for the dry-weather flow rate data. At the'point 1' expected non-pressure flow, we were able to see the drawdown effect caused by the free fall in the manhole section. At the'point 2', existed weir and sediments, there was backwater effect caused by them, and each of size calculated from the scatter graph analysis were 400 mm and 130 mm. At the'Point 3', there is specific flow pattern that is coming from flood wave propagation generated by the pump station at upstream. In common, adequate equations to explain the dry weather flow data are flume equation and modified manning equation(SS method), and the equations had compatibility for explaining the data because all of $R^2$ values are over 0.95.

• 한국항공우주학회지
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• 제32권7호
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• pp.51-59
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• 2004

저속충격에 의한 복합재의 파손 모드를 규명하기 위하여 PVDF 센서를 이용한 신호취득 방법과 측정된 PVDF 센서 신호를 시간-주파수 분석법 (time-frequency analysis)인 국소 퓨 리에 변환 및 웨이블렛 변환을 적용하여 분석할 수 있는 실험적 전차에 대하여 고찰하였다. 고분자 암전센서를 이용하여 저속충격시 발생할 수 있는 여러 충격손상 형태 모재균열, 층간분리, 섬유파단에 의한 응력파 측정 가능성을 고찰하기 위하여 일련의 저속충격 시험을 수행하였다. 충격 시험 후, 저속 충격을 받은 적층판에 대하여 C-scan 과 단면 검사를 통하여 센서 신호, 손상 모드 및 크기에 대한 상관관계를 고찰하였다. 센서신호의 취득과 신호분석을 통하여 저속충격의 발생/진행과정을 알 수 있는 많은 중요한 정보가 PVDF 센서신호에도 내재되어 있음을 알 수 있으며 PVDF 센서 신호를 주의 깊게 분석함으로써 저속 충격에 의한 복합재료의 손상 모드 규명이 가능하며 저속충격 위협에 대한 복합재 구조물의 건전성 모니터링에 활용할 수 있는 가능성을 제시하였다.

• 대기
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• 제26권2호
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• pp.301-319
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• 2016

The evolutionary process of the polar low, which caused the heavy snowfall in the East Coast area on 11~12 February 2011, was investigated to describe in detail using synoptic weather charts, satellite imageries, and ERA (European Centre for Medium-Range Weather Forecasts Re-Analysis) -Interim reanalysis data. It was revealed that 1) the polar low was generated over the sea near Busan where a large cyclonic shear in the inverted trough branched from the parent low existed, 2) during the developing and mature stages, there was a convectively unstable region in the lower layer around the polar low and its south side, 3) the polar low was developed in the region where the static stability in the 500~850 hPa layer was the lowest, 4) the result from the budget analysis of the vorticity equation indicated that the increase in the vorticity at the lower atmosphere, where the polar low was located, was dominated mainly by the stretching term, 5) the warm core structure of the polar low was identified in the surface-700 hPa layer during the mature stage, 6) there was a close inverse relationship between a development of the polar low and the height of the dynamic tropopause over the polar low, and 7) for generation and development of the polar low, large-scale circulation systems, such as upper cold low and its combined short wave trough, major low (parent low), and polar air outbreak, should be presented, indicating that the polar low has the nature of the baroclinic disturbance.

• Journal of Ginseng Research
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• 제31권3호
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• pp.159-174
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• 2007

Pharmacology of Korean Red ginseng gives us unique possibility to develop new class of antiepileptic drugs today and to improve one's biological activity. The chemical structures of ginsenosides (GS) have some principal differences from well-known antiepileptic new generation drugs. The antiepileptic effect of GS was also demonstrated in all models of epilepsy in rats (young and adult), which have studied, in all models of epilepsy including status epilepticus (SE), induced by lithium - pilocarpine. In our experiments in rats new evidences on protective effects were exerted as a result of premedication by GS. Pre-treatment of several GS could induce decrease of the seizures severity and brain structural damage (by MRI), neuronal degeneration in hippocampus. Wave nature of severity of motor seizures during convulsive SE was observed during lithium-pilocarpine model of SE in rats (the first increase of seizures was 30 min after the beginning of SE and the second - 90 min after. The efficacy of treatment on SE by ginsenoside as expected was observed after no less 3 weeks by daily GS i.p. administration. It is blocked SE or significantly decrease the severity of seizures during SE. The implication of presented data is that combination of ginsenosides from Korean Red ginseng and ginseng cell culture Dan25 that could be applied for prevention of epileptical status development. However, a development of optimal ratio of different ginsenosides $(Rb_1$ Rc, Rg, Rf,) should consummate in the new antiepileptic drug development.