• Journal of the Korean Ceramic Society
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• v.46 no.4
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• pp.365-371
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• 2009

It is well known that the properties of concrete such as the compressive strength, water permeability, water tightness and durability are affected by micro-structure in hardened cement paste. Especially, for durability of concrete, watertightness of cementitious materials is the most critical property among various properties. Recently, many types of materials as organic and/or inorganic materials are used for watertightness of concrete. In this study, The effect of Stearic Acid at $0.5\;wt%{\sim}3.0\;wt%$ adding ratios on the hydration and watertightness property of cement were investigated. And we also discussed the changing of microstructure in hardened cement paste by addition of Stearic Acid. Cement paste with Stearic Acid showed improvement of watertightness by reducing of cement total pore volume and decomposition of Stearic Acid.

• Journal of the Korea Concrete Institute
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• v.12 no.3
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• pp.39-46
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• 2000

This study is to investigate the watertightness properties of waterproofing admixture mixed redispersible polymer and siliceous powder. Series I deals with change in micro-structure of mortar by waterproofing admixture according to the water/cement ratios of 0.5, 0.6, 0.7 and 0.8 Crystal growth in micro-structure was observed through SEM to estimate on the watertightness effect of it. SeriesII deals with watertightness properties of waterproofing admixture on water permeability coefficient, crack restoration capacity and carbonation depth. SeriesII deals with watertightness properties of waterproofing admixture on water permeability coefficient, crack restoration capacity and carbonation depth. The result of this study can be summarized as follows. 1) Fluidity of mortar and concrete was increased by adding waterproofing admixture. 2) From observation through SEM. Crystals grew larger and denser in micro-structure as fiberic crystalization. 3) Waterproofing admixture is good watertightness properties in a level of high water/cement ratios and long limit of time. 4) Crack restoration capacity was appeared and durability was progressed by waterproofing admixture.

• Journal of the Korean Ceramic Society
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• v.45 no.6
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• pp.350-357
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• 2008

The use of shotcrete-sprayed concrete for the support of underground excavations was pioneered by the civil engineering. Now, for the nuclear wastes disposal plant in our country, watertightness of shotcrete is one of the very important properties. This study evaluated the watertightness of shotcrete using cement mineral accelerator with watertightness materials for the long-term watertightness. In this study, for improvement of watertightness of shotcrete, it used two types of obtainable at a store. Watertightness tests of shotcrete were performed the water absorption coefficient, permeability, porosity and hydrates variation. In a shotcrete containing watertightness materials, watertightness of shotcrete was improved about $15%{\sim}65%$ rather than plain shotcrete.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2010.05a
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• pp.13-16
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• 2010

This study is an Investigation on the Watertightness Properties of Rain-Block System on the Sliding-Roof Joint of Large-Span Membrane Structures. In this experimental, we test the watertightness performance of joint part of sliding door in roof of large span membrane structure(for pilot project) under environment of rain and wind. A shape of rain water blocking systems of joint part in sliding door verifies the defects and effects of water leakage prevention in precipitation with the wind conditions. For obtaining watertightness of large span membrane structures, it is necessary quality of joints and performance, and quality of membrane material of a retractable roof as well as a closed roof. Also, for obtaining quality in joints, it is essential to make a watertightness guideline for design of large-span membrane.

• Proceedings of the Korea Concrete Institute Conference
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• 2004.05a
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• pp.36-39
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• 2004

In this study, effects of fluosilicate salt based chemical admixture(MZ) on the watertightness and hardening properties of concrete were investigated. Mix proportions for experiment were modulated at 0.55 of water to cement ratio and addition amount of MZ to $2.0\%$ at intervals $0.5\%$. Compressive strength, porosity and microstructure of hardened concrete cured at several days were executed to evaluate watertightness and hardening properties. It is ascertained that watertightness and hardening properties of concrete could be improved by an adequate addition of fluosilicate salt based chemical admixture.

• Journal of the Korean Society of Hazard Mitigation
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• v.10 no.5
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• pp.17-25
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• 2010

We studied on the watertightness improvement of cementitious material for durability enhancement of concrete. For improvement of watertightness of OPC and OPC with fly ash, we used various materials with watertightness properties to OPC and OPC with fly ash. The performance of watertightness improvement of cementitious materials closely related to formation of CSH by pozzolanic reaction and to reducing of size of contact angle in cement pore by using organic fatty acid. And volume of CSH formation at early hydration have an influence of watertightness improvement and reduction of long-term water absorption rate. In using of fly ash, improvement of workability by using the spherical fly ash caused to densify on the structures of cement material and CSH formation by pozzolanic reaction and cement using fly ash also caused watertightness improvement of cementitious materials. For improvement of concrete durability by watertightness, cementitious materials need using watertightness materials and at using fly ash, also it have to the effect of improvement of watertightness of cementitious materials by pozzolanic reaction.

• Applied Chemistry for Engineering
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• v.20 no.5
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• pp.505-510
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• 2009

It is well known that the properties of concrete such as the compressive strength, water permeability, water tightness and durability are affected by micro-structure in hardened cement paste. Especially, for durability of concrete, watertightness of cementitious materials is the most critical property among various properties. Recently, many types of material such as organic and/or inorganic materials are used for watertightness of concrete. In this study, we examined the effect of fluorine-based emulsion on watertightness property. And we also discussed the change of microstructure and formation of hydrates in hardened cement paste by the addition of fluorine-based emulsion. Cement paste with fluorine-based emulsion showed improvement of watertightness by the surface activation of cement paste and by formation of $CaF_2$ fine crystals in cement pore structure.

• Journal of the Korea Concrete Institute
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• v.17 no.5 s.89
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• pp.769-774
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• 2005

Fluosilicic acid(H2SiF6) is recovered as an aqueous solution which absorbs $SiF_4$ produced from the manufacturing of industrial-graded H3PO4 or HF. Generally, fluosilicates are the salts produced by the reaction of H2SiF6 and metal salts. Addition of fluosilicates to cement endows odd properties through unique chemical reaction with the fresh and hardened cement. This study was performed to know mechanical properties and watertightness using fluosilicates based composite made from fluosilicates and other compounds. Mix proportions for experiments were modulated at 0.45 of water to cement ratio and $0.0-2.0\%$ of adding ratio of fluosilicates based composite. Evaluation for mechanical properties of concrete was conducted to know fresh state of concrete, hardening state of concrete, and watertightness. Evaluation for watertightness of concrete was carried out permeability, absorption test and porosity analysis. In addition. Scanning Electron Microscopy(SEM) and Energy Dispersive X-Ray(EDX) used for investigating micro-structure and atomic component distributed in hardened concrete. It is ascertained that characteristics of mechanical properties and watertightness was more improved than non-added because of packing role of fluosilicates based composite and pozzolanic reaction of soluble $SiO_2$. Also, concrete added fluosilicates based composite had a tendency to delay setting time and only $0.5\%$ addition of fluosilicates based composite delayed 150 minutes compared with non-added.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.05b
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• pp.617-620
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• 2006

This study is related to comprehending performance for watertightness and crack control of concrete added with crack reducing agent concerning to high strength concrete mixs. It was confirmed that watertightness of concrete added with agent could be improved by evaluation absorption ratio, permeability ratio and pore size distribution of hardened concrete. As well resistance to crack resulted from shrinkage was transferred to better state by the addition of agent.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.429-432
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• 2008

Large area members such as foundation concrete of underground structures in power plants have an effect on structural stability and durability of the structure due to danger of crack occurrence and shrinkage crack that occur owing to the difference of temperature by heat of hydration between inside and outside of the members at initial age. And a construction for waterproofness is performed additionally to protect marine structures from osmosis of seawater because the structures adjoin below the surface of sea. So, if a rise of the heat of hydration, crack, and corrosion of bars are controled effectively using a composite such as fluosilicate salt in concrete production process of a initial construction, expenses are cut down and construction hours are reduced by securing durability through improvement of watertightness. The property tests of adiabatic temperature by hydration are carried out at initial age about standard concrete and test concrete using a fluosilicate salt composite to evaluate an effect on improvement of watertightness for concrete structures in this study. And the experiments such as a permeability test of hardened concrete, a water absorption test, a compression strength test and a elongation test are carried out and the results from these are described.