• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2002년도 가을 학술발표회 논문집
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• pp.531-536
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• 2002

Silica fume influences concrete diffusivity and permeability as well as strength by densifying the microstructure of the interfacial transition zone (ITZ) of high strength concrete, by reducing the capillary porosity of cement paste and by producing less diffusible and permeable pozzolanic CSH gel than CSH gel of conventional cement hydration. This paper presents a procedure to predict the chloride ion diffusivity and water permeability of the high strength concrete containing silica fume. Water binder ratio, silica fume addition, degree of hydration and volume fraction of aggregates are considered as the major factors influencing concrete diffusivity and permeability in the procedure. Analytical results using the procedure are shown and verified with other data.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2006년도 추계 학술발표회 논문집
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• pp.453-456
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• 2006

In this study, the experiment was carried out to investigate and analyze the influence of fineness of blast furnace slag powder on the properties of high strength concrete. The main experimental variables were water/binder ratio 27.5, 31.5, 35.5(%) water content $165kg/m^3$ and mineral admixtures such as blast furnace slag powder. Even in a case where the ratio of blast furnace slag powder is 70%, using a fineness of 8000 grade afforded a higher strength development than using a plain concrete, which indicates the potential of high utilization in the future. Although it has been pointed out that the concrete using blast furnace slag powder has a problem of yielding relatively low rate of strength development in the early age, it is demonstrated that this can be resolved by using a powder with fineness greater than 6000 grade. It is considered necessary that powder fineness should be upgraded for the applications such as high performance concrete to be used in high strength required areas by considering hydration heat control and early strength requirements in the future.

• 한국건축시공학회지
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• 제15권1호
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• pp.1-7
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• 2015

본 연구의 목적은 ALC 블록대체를 위한 고성능 기포콘크리트 배합설계를 개발하는 것이다. 대기양생 하에서 기포콘크리트의 고강도 발현(특히 초기재령에서)을 위하여 결합재 및 혼화제를 사전연구에서 다음과 같이 설계하였다. 규산3칼슘이 60% 이상인 보통포틀랜드시멘트에 무수석고 3%를 첨가하였으며, 폴리카르본산계 감수제에서 폴리알킬에테르 성분을 28%로 조절하였다. 이들 재료를 사용하여 물-결합재비와 단위결합재양을 변수로 기포콘크리트 11배합을 실험하였다. 배합된 기포콘크리트의 품질 및 실용성은 KS 규격의 ALC 블록의 요구조건 및 기존의 일반 기포콘크리트와 비교하였다. 실험결과 본 연구의 고성능 기포콘크리트는 ALC 블록의 요구조건을 만족하면서 높은 실용가능성을 보였다.

• 콘크리트학회논문집
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• 제29권4호
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• pp.379-387
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• 2017

본 연구에서는 기존 PVA 섬유보강 시멘트 복합체(fiber-reinforced cementitious composites, FRCCs) 대비 성능유지 90% 이상을 목표로 하여 자원순환형 재료를 치환한 PVA FRCCs를 제조 및 개발하고자 하였다. 자원순환형 재료를 치환한 FRCCs의 압축, 휨 및 직접인장강도 시험을 통하여 역학적 특성을 분석하였으며, 이와 더불어 FRCCs의 제조단계에서 이산화탄소($CO_2$) 배출량을 국내 외 LCI 데이터베이스를 통하여 평가하였다. 실험을 통해 역학적 특성을 평가한 결과, 자원순환형 재료의 치환율이 증가함에 따라 압축, 휨 및 직접인장강도가 감소하는 경향으로 나타났다. $CO_2$ 배출량은 물결합재비(W/B)가 높고, 플라이 애시(FA)의 치환율이 높을수록 감소하는 것으로 나타났다. FA의 치환율이 증가함에 따라 결합재 지수($B_i$) 또한 증가하여 단위 강도(1 MPa)를 발휘하기 위한 결합재의 양이 보통 포틀랜드 시멘트보다 FA가 높은 것으로 나타났다. FRCCs의 성능을 유지하기 위해 설정된 목표치와 $CO_2$ 배출량을 동시에 고려해 볼 때 W/B 45%, FA 25% 및 순환 잔골재 25%가 치환된 배합이 가장 우수한 것으로 나타났다.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2013년도 추계 학술논문 발표대회
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• pp.126-127
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• 2013

For the decades, various of materials were used to instead of cement as the high volume CO₂ occurred during the process of cement manufacture. In this paper, incineration plant ash was used in the mortar which incorporating high volume of blast furnace slag. Water to binder ratio(W/B) is fixed as 50%,BS+RP's replacement ratio is fixed as 80%,and the replacement ratio of WA1 is range as 0,0.5,1,2,3,4,5%.For the fresh mortar, flow and chloride contents has been tested. For the hardened mortar, compressive strength at 3,7,28 days has been tested. the result shows that when the replacement ratio of WA1 is 0.5%,the chloride contents is less than 0,3 kg/m3,the flowability and strength also performed better than other replacement types of mortar.

• 대한토목학회논문집
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• 제29권4A호
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• pp.347-353
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• 2009

콘크리트 내의 염소이온 침투에 영향을 미치는 정성적인 주요 인자로는 물-결합재비, 시멘트 종류, 재령, 주위 환경의 염소이온 농도 및 건습조건 등이 있다. 이에 따라 이 연구에서는 염소이온 확산실험을 통해 시멘트 종류 및 환경조건이 염소이온 확산특성에 미치는 영향을 조사하였다. 이를 위하여 물-결합재비 32%, 38% 및 43%에 대해서 보통 포틀랜드 시멘트(OPC), 2성분계 시멘트(BBC) 및 3성분계 시멘트(TBC) 각각을 사용한 콘크리트의 확산계수를 측정하였으며, 또한 물-결합재비 43%에 대해서 표준양생 및 해양환경에 폭로된 콘크리트의 확산계수를 측정하였다. 그 결과, 염소이온 침투 저항성은 물-결합재비가 감소함에 따라 증가하고, 2성분계 및 3성분계 시멘트를 사용한 콘크리트의 침투 저항성이 OPC 콘크리트에 비하여 우수한 것으로 나타났다. 따라서, 염해환경에 노출된 철근콘크리트 구조물의 내구수명을 증진시키기 위하여 광물질 혼화재를 혼입한 2성분계 혹은 3성분계 시멘트의 사용이 요구된다. 한편, 현장 폭로 시편의 염소이온 침투 저항성은 일정하지 않은 대기온도 하에서 염소이온의 침투, 파랑 및 건습반복의 영향으로 표준양생 시편의 경우보다 다소 저하되는 것으로 나타났다.

• 한국토양비료학회지
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• 제35권5호
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• pp.290-295
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• 2002

조립 복합비료의 증량제를 점토광물 대신 인광석분말로 대체하여 연초용 복합비료(10-0-30)조립시험을 수행했다. 황산칼리 60%, 요소 22%, 인광석 18%로 조성된 분말에 10% 인산액을 점결제로 조립한 결과 소량의 점결제로서 양호하게 조립되었으며 입자분포, 입자경도, 수중 붕괴도, 흡습성 등 물리성이 매우 이상적인 입자로 조사되었다. 담배직물을 묘상기, 본포기로 나누어 폿트 비효실험 결과 생육기간이 짧은 묘상에서는 시제품의 생육이 부진하였고 본포기 폿트 재배시험에서도 인산축적이 없는 개간지 토양에서는 생육이 부진하였으나 인산이 축적된 숙전에서는 정상적으로 생육하였다.

• Corrosion Science and Technology
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• 제8권3호
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• pp.110-115
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• 2009

At the onset of corrosion of steel in concrete, hydrogen ions usually evolve in the process of electrochemical reaction, thereby decreasing the pH of the pore solution, which can be buffered by cement hydration products, as being representatively illustrated by calcium hydroxide. Hence, a fall in the pH is dependent on properties of cement hydration (i.e. hydration products and degree of hydration). The present study tested acid neutralization capacity (ANC) of cementitious binders of OPC(Ordinary Portland Cement), 30% PFA(Pulverized Fuel Ash), 60% GGBS(Ground Granulated Blast Furnace Slag), 10% SF(Silica Fume) to quantify the resistance of cement matrix to a pH fall. Cement pastes were cast at 0.4 of a free W/C ratio with 1.5% chlorides by weight of binder in cast. Powder samples obtained crushed and ground specimen after 200 days of curing were diluted in still water combined with different levels of 1M nitric acid solution, ranging from 0.5 to 20 mol/kg. Then, the pH of diluted solution was monitored until any further change in the pH did not take place. It was seen that the pH of the diluted solution gradually decreased as the molar amount of nitric acid increased. At some particular values of the pH, however, a decrease in the pH was marginal, which can be expressed in the peak resistances to a pH fall in the ANC curve. The peaks occurred at the variations in the pH, depending on binder type, but commonly at about 12.5 in the pH, indicate a resistance of precipitated calcium hydroxide. The measurement of water soluble chloride at the end of test showed that the amount of free chloride was significantly increased at the pH corresponding to the peaks in the ANC curve, which may reflect the adsorption of hydration products to chlorides.

• 한국건축시공학회지
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• 제8권4호
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• pp.79-85
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• 2008

The purpose of this study is to evaluate the mix design of pH reducing cement concrete which can be used for environment-friendly concrete. Cement pastes and concretes are prepared with water-binder ratios and various admixtures such as blast-furnace slag, fly ash and recycled cement, and tested for compressive strength and pH. pH is measured through pore solution expressed from hydrated cement paste by special apparatus. From the test results, regardless of water-binder ratio, The pH of expressed pore solution from hydrated cement paste which is made of ordinary portland cement with blast-furnace slag, fly ash is decreased with increasing of admixtures content, and compressive strength is also slightly improved. The compressive strength of cement paste made of recycled cement which is burnt at $1000^{\circ}C$, for 2 hours is considerably increased compared with that of none-burnt recycled cement due to restoration of hydraulic property, but pH is a little higher. Porous concrete with ordinary portland cement has high pH in the range of 12.22 to 12.59, however, that is reduced to the range of 8.95 to 10.39 by carbonation at the surface of porous concrete. The pH reduction of porous concrete is possible by various admixture addition, however their degrees are very slight. Therefore, to reduce the pH considerably, carbonation method of porous concrete is better in pH reduction methods for plant survival condition of pH of 9.0 or less. In this study, it is apparent that pH for the environment-friendly porous concrete products used in the construction field can be suppressed by this carbonation method and various admixtures addition.

• Advances in concrete construction
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• 제6권6호
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• pp.561-583
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• 2018

A variety of polycarboxylate ether (PCE)-based superplasticizers are commercially available. Their influence on the rheological retention and slump loss in respect of concrete differ considerably. Fluidity and slump loss are the cardinal features responsible for the quality of concrete. These are related to the dispersion of cement particles and the hydration process which are greatly influenced by type of polycarboxylate ether (PCE)-based superplasticizers. On the backdrop of relatively less studies in the context of rheological retention of high strength self-consolidating concrete (HS-SCC), the experimental investigations were carried out aiming at quantifying the effect of the six different PCE polymers (PCE 1-6) on the rheological retention of HS-SCC mixes containing two types of Ordinary Portland Cements (OPC) and unwashed crushed sand as the fine aggregate. The tests that were carried out included $T_{500}$, V-Funnel, yield stress and viscosity retention tests. The supplementary cementitious materials such as fly ash (FA) and micro-silica (MS) were also used in ternary blend keeping the mix paste volume and flow of concrete constant. Low water to binder ratio was used. The results reveal that not only the PCEs of different polymer groups behave differently, but even the PCEs of same polymer groups also behave differently. The study also indicates that the HS-SCC mixes containing PCE 6 and PCE 5 performed better as compared to the mixes containing PCE 1, PCE 2, PCE 3 and PCE 4 in respect of all the rheological tests. The PCE 6 is a new class of chemical admixtures known as Polyaryl Ether (PAE) developed by BASF to provide better rheological properties in even in HS-SCC mixes at low water to binder mix. In the present study, the PCE 6, is found to help not only in reduction in the plastic viscosity and yield stress, but also provide good rheological retention over the period of 180 minutes. Further, the early compressive strength properties (one day compressive strength) highly depend on the type of PCE polymer. The side chain length of PCE polymer and the fineness of the cement considerably affect the early strength gain.