• Magazine of the Korean Society of Agricultural Engineers
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• v.30 no.4
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• pp.85-93
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• 1988

This laboratory study was carried out in order to produce fundamental data for analyzing salt movement and desalinization effects, using samples of silt loam soil collected in Gyehwado and Daeho reclaimed tidelans, and samples of silty clay loam soil collected in Kimie tideland. Desalinization experiments with gypsum treatment were performed to analyze changes of the hydraulicc conductivity with changes of the soil property and the salt concentration during the desalinization of reclaimed tideland soils by leaching through the subsufface drainage, and correlations between factors infl uencing the reclamation of salt affected soils were analyzed by the statistical method. The results were summarized as follows: 1. The reclaimed tideland soils used in this study were saline-sodic soils with the high exchangeable sodium percentage and the high electrical conductivity. 2. Changes of the hydraulic conductivity with the amount of leaching water and the leaching time elapsed were affected by the amount of gypsum except exchangeable sodium and clay contents. The regression equation between the depth of water leached per unit depth of soil (Dw / Ds : X) or the square root of the leaching time elapsed (T $^1$ $^2$ : X) and the relative hydraulic conductivity (HCr:Y) could be expressed in Y=a . bx. 3. The more exchangeable sodium and clay contents regardless of the amount of gypsum, the more the leaching time was required until a given volume of water was leached through the soil profile. The regression analysis showed that the relationship between the depth of water leached per unit depth of soil(Dw /Ds:X) and the square root of the leaching time elapsed(T$^1$$^2$ :Y) could be described by Y=a . Xb. 4. The hydraulic conductivity was influenced to a major degree by the salt concentration provided that the electrical conductivity was below 10 mmhos / cm during the desalinization of reclaimed tideland soils. The regression equation between the relative electrical conductivity ( ECr : X) and the relative hydraulic conductivity (HCr:Y) could be expressed in Y=a + b . X-$^1$. 5. In conclusion, the hydraulic conductivity, leaching requirements and the leaching time elapsed can be estimated when the salt concentration decreases to a certain level during the desalinization of reclaimed tidelands, and the results may be applied to the analysis of salt movement and desalinization effects.

• Korean Journal of Agricultural Science
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• v.49 no.2
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• pp.379-387
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• 2022

A large amount of the mineral nitrogen is necessary for crop growth. With the use of nitrogen fertilizers, agricultural yield has increased during the last few decades. However, at the same time, nitrate from the cultivated land can be a source of environmental pollution, especially in water systems. For nitrogen management, it is necessary to analyze the pattern of nitrogen movement in soil. In this study, nitrogen leaching in upland soils was evaluated using undisturbed lysimeters with different soil textures during sesame cultivation. The soil texture of the lysimeters was clay loam (Songjung series) and sandy loam (Sangju series) soils. Sesame was cultivated from May 25 to August 24 in 2020. The standard amount of NPK fertilizer (N-P₂O₅-K₂O = 2.9-3.1-3.2 kg·10 a^-1) was applied before sowing. The amount of nitrogen leaching was calculated by multiplying the nitrogen (NO₃-N + NH₄-N) concentration and the amount of water drained below 1.5 m soil depth. The water was drained through percolation into macropores in the clay loam lysimeter. In contrast, in the sandy loam lysimeter, water drained more slowly than in the clay loam lysimeter. There was a slight difference in the total amount of leachate during the cultivation period, but the amount of nitrogen leaching was high in sandy loam soil. During the sesame cultivation period, the amount of nitrogen leaching from clay soil was 5.64 kg·10 a^-1, and 10.70 kg·10 a^-1 for sandy soil. We found that there was a difference in leaching depending on the soil physical characteristics. Therefore, it is necessary to consider the characteristics of soil to evaluate the leaching of nitrogen.

• Journal of Environmental Science International
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• v.4 no.4
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• pp.379-386
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• 1995

Permethrin [3-phenox yben zyl(1RS)-cis,tans-3-(2,2-dichloroviny1)-2,2- dimethylcyclopropane carboxylate] insecticides were selected to study adsorption and leaching potentials related to pollution on Commerce silty clay loam soil near Baton Rouge, Louisiana, USA. GLC-ECD chromatogram of permethrin included 32.5 % of cis-pemehin and 67.4 % of trans-permethrin. Extraction efficiencies of is and trmu-pemetun were 92.5 % and 92.3 % in fortified water, respectively and 85.9 % and 88.8 % in fortified soil, respectively. At a 1:10 moi]/water ratio,the Koc values for sis and fan isomers of permethrin were 938 and 877, respectively. Leaching of permethrin was evaluated in soil columns$(5.4 cm i.d. \times 26 cm length)$. Total recoveries of the permethrin applied to the soil column were $84.5\pm3.1%$. When the soil columns were leached with three pore volumes of water, the distributions of cis-permethrin leached were 6.10 % and 0.07 % of amount applied in the untreated zone soil and leachate water, respectively Trans-pemethrin distributions were 5.20 % in the untreated zone soil and 0.05 % in leachate water. Cis and trans-pemethrin was strongly adsorbed to soil. The results of the study showed the strong relationship between adsorption and leaching. Cis and trans-permethrin to be leached into the groundwater in soils with shallow aquifers were suggested a low leaching potential.

• Journal of the Korean Wood Science and Technology
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• v.33 no.6 s.134
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• pp.87-94
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• 2005

This study was carried out to investigate the effect of soil types and soil properties on wood preservative leaching. Radiata pine (Pinus radiata Don.) sapwood stakes, which had been treated with 2.0%(w/v) CCA, were leached for 12 weeks by a common laboratory method in four different soils and for 14 days by the AWPA standard leaching method in water. The physical and chemical properties of the four soils were determined, and the percent leaching of the individual component of CCA was correlated with the various soil properties. The data show that leaching of preservative chemicals from treated wood exposed to soil is influenced by the type of soil. The preservative leaching was greater when wood was exposed to water than when the wood was in contact with water-saturated soil. The greatest chromium, copper and arsenic leaching from CCA-treated stakes were observed in the sandy loam, loam, and sand, respectively, and the least amount of leaching of CCA components occurred in the silty loam. The leaching of preservative components from treated wood is extremely complex and appears to be influenced differently by the soil properties. The extent of copper leaching from CCA treated wood appears to be related to exchangeable Mg and sum of bases. There is a reasonably good relationship between chromium leaching and exchangeable Mg, and between arsenic leaching and exchangeable K, soil Ni, Mn, Fe, Cr, or Cu content. Since this study was conducted based on laboratory leaching method using small cross-sectional dimensions; thus, data obtained from this experiment should not be used to predict leaching characteristics from commercial-size wood used in real situation. Accordingly, further studies are necessary using outdoor ground-contact leaching.

• Computers and Concrete
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• v.32 no.1
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• pp.45-60
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• 2023

Concrete in water environment is easily subjected to the attack of leaching, which causes its mechanical reduction and durability deterioration, and the key to improving the leaching resistance of concrete is to increase the compaction of its microstructure formed by the curing. This paper performs a numerical investigation on the intrinsic relationship between microstructures formed by the hydration of cement and slag and leaching resistance of concrete in water environment. Firstly, a shrinking-core hydration model of blended cement and slag is presented, in which the interaction of hydration process of cement and slag is considered and the microstructure composition is characterized by the hydration products, solution composition and pore structure. Secondly, based on Fick's law and mass conservation law, a leaching model of hardened paste is proposed, in which the multi-species ionic diffusion equation and modified Gérard model are established, and the model is numerically solved by applying the finite difference method. Finally, two models are combined by microstructure composition to form an integrated curing-leaching model, and it is used to investigate the relationship between microstructure composition and leaching resistance of slag-blended cement pastes.

• Magazine of the Korean Society of Agricultural Engineers
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• v.31 no.1
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• pp.96-105
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• 1989

This laboratory study was performed to produce basic data for the estimation of water requirements for desalinization, through analyzing changes of the electrical conductivity and the exchangeable sodium percentage during the desalinization of reclaimed tidelands. Desalinization experiments were carried out by two water management practices, namely, the leaching method by subsurface drainage and the rinsing method by surface drainage, using samples of silt loam soil and silty clay loam soil collected in reclaimed tidelands. The results obtained from this study were summarized as follows : 1. The sample soils used in this study were saline-sodic soils with the high electrical conductivity and the high exchangeable sodium percentage. 2. Changes of the electrical conductivity and the exchangeable sodium percentage with water requirements for desalinization showed a similar tendency in the desalinization experiment by the same water management practice. 3. The regression equation between the relative electrical conductivity(EC/EC) and water requirements for desalinization(Dw/Ds) could be described by Dw/Ds=O. 29x(EC/EC.) -0.982 (Leaching method), Dw/Ds=3. 678X0. 030(EC/EC ) (Rinsing method). 4. The regression equation between the relative exchangeable sodium percentage (ESP/ESP ) and water requirements for desalinization (Dw/Ds) could be expressed in Dw/Ds = 0.039 x (ESP/ESP. ) - 1. 134 (Leaching method), Dw/Ds=7. 197X0. 024(ESP/ESP ) (Rinsing method). 5. It was estimated that water requirements for the adequate desalinization would be Dw/Ds=0.3 (Leaching method) and Dw/Ds=3.0 (Rinsing method)

• Resources Recycling
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• v.31 no.2
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• pp.56-62
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• 2022

This study investigated the water leaching behavior of vanadium in Na₂CO₃-roasted vanadium-bearing titaniferous magnetite (VTM) concentrate. The magnetic concentrate and Na₂CO₃, mixed in a mass ratio of 4:1, were roasted at 1050 ℃, kept for 3 h, and ground to a size of D₅₀ = 48.79 ㎛ using a rod mill. The effects of leaching temperature and pulp density on water leaching were then investigated. The results show that the vanadium leaching efficiency decreased to 90.4%, 88.2%, and 83.8% as the temperature increased to 25, 55, and 85 ℃, respectively, whereas it remained almost constant 90.4%, 87.0%, and 87.0% as the pulp density increased to 10, 50, and 100 w/v%, respectively. Based on the preliminary leaching results, multi-stage leaching was conducted with the experimental conditions of 25 ℃, 100 w/v%, 300 rpm, and 1 h. The vanadium concentration in the final leaching solution was determined as 16.20 g/L after four stages of leaching. Thus, a high-concentration sodium vanadate solution was prepared by multi-stage leaching.

• Structural Engineering and Mechanics
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• v.86 no.6
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• pp.779-791
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• 2023

Long-termly used in water supply, an underground concrete pipe is easily subjected to the coupled action of pressure loading and flowing water, which can cause the chemo-mechanical damage of the pipe, resulting in its premature failure and lifetime reduction. Based on the leaching characteristics and damage mechanism of concrete pipe, this paper proposes a coupled chemo-mechanical damage and failure model of underground concrete pipe for water supply, including a calcium leaching model, mechanical damage equation and a failure criterion. By using the model, a numerical simulation is performed to analyze the failure process of underground concrete pipe, such as the time-varying calcium concentration in concrete, the thickness variation of pipe wall, the evolution of chemo-mechanical damage, the distribution of concrete stress on the pipe and the lifetime of the pipe. Results show that, the failure of the pipe is a coupled chemo-mechanical damage process companied with calcium leaching. During its damage and failure, the concentrations of calcium phase in concrete decrease obviously with the time, and it can cause an increase in the chemo-mechanical damage of the pipe, while the leaching and abrasion induced by flowing water can lead to the boundary movement and wall thickness reduction of the pipe, and it results in the stress redistribution on the pipe section, a premature failure and lifetime reduction of the pipe.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2003.04a
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• pp.455-458
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• 2003

We investigated the leaching of elements from anthracite ashes by interactions with seawater. The results show that consumption rates of dissolved oxygen are 7.5 times greater in the seawater system than in the fresh water system and indicate that the differences in DO consumption rate may plat a role in regulating the element leaching from the coal ashes. It is revealed that seawater's pH buffering capacity is the most important factor that makes the leaching of elements and their chemical behaviors in the seawater system different from those in the fresh water environments. In overall, element leaching from the weathered ash is smaller than that from the fresh ash. However, the leaching of Si, Fe, Al, Mn, phosphate, and some other elements were independent of weathering. They were dependant only on the pH of the solutions.

• Computers and Concrete
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• v.31 no.4
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• pp.315-325
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• 2023

Calcium leaching is one of the main deterioration factors in concrete structures contact with water, such as dams, water treatment structures, and radioactive waste structures. It causes a porous microstructure and may be coupled with various harmful factors resulting in mechanical degradation of concrete. Several numerical modeling studies focused on the calcium leaching depth prediction. However, these required a lot of cost and time for many experiments and analyses. This study presents an artificial neural network (ANN) approach to predict the leaching depth quickly and accurately. Totally 132 experimental data are collected for model training and validation. An optimal ANN model was proposed by ANN topology. Results indicate that the model can be applied to estimate the calcium leaching depth, showing the determination coefficient of 0.91. It might be used as a simulation tool for engineering problems focused on durability.