• Journal of the Korea Concrete Institute
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• v.23 no.6
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• pp.817-826
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• 2011

Concrete using eco-cement has a problem with long-term strength development. However, currently, a long-term strength development mechanism is not confirmed, resulting in a lack of application of eco-cement in construction fields. In this study, the curing humidity influence on development in long-term strength of concrete using eco-cement and the relationship between strength and pore structure were examined. The results showed that wet cured eco-cement with a high water/cement ratio showed serious long-term strength reduction due to non-reduction of pore volume (pore size over 10 nm) in mortar caste with eco-cement. Also, the study results on improvement of long-term strength of eco-cement by partial replacement with ordinary portland cement and finely-ground fly ash showed that both of these alternatives improved long-term strength of concrete caste with eco-cement due to gradual refinement of their micro-structure.

• Corrosion Science and Technology
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• v.8 no.3
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• pp.110-115
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• 2009

At the onset of corrosion of steel in concrete, hydrogen ions usually evolve in the process of electrochemical reaction, thereby decreasing the pH of the pore solution, which can be buffered by cement hydration products, as being representatively illustrated by calcium hydroxide. Hence, a fall in the pH is dependent on properties of cement hydration (i.e. hydration products and degree of hydration). The present study tested acid neutralization capacity (ANC) of cementitious binders of OPC(Ordinary Portland Cement), 30% PFA(Pulverized Fuel Ash), 60% GGBS(Ground Granulated Blast Furnace Slag), 10% SF(Silica Fume) to quantify the resistance of cement matrix to a pH fall. Cement pastes were cast at 0.4 of a free W/C ratio with 1.5% chlorides by weight of binder in cast. Powder samples obtained crushed and ground specimen after 200 days of curing were diluted in still water combined with different levels of 1M nitric acid solution, ranging from 0.5 to 20 mol/kg. Then, the pH of diluted solution was monitored until any further change in the pH did not take place. It was seen that the pH of the diluted solution gradually decreased as the molar amount of nitric acid increased. At some particular values of the pH, however, a decrease in the pH was marginal, which can be expressed in the peak resistances to a pH fall in the ANC curve. The peaks occurred at the variations in the pH, depending on binder type, but commonly at about 12.5 in the pH, indicate a resistance of precipitated calcium hydroxide. The measurement of water soluble chloride at the end of test showed that the amount of free chloride was significantly increased at the pH corresponding to the peaks in the ANC curve, which may reflect the adsorption of hydration products to chlorides.

• Nuclear Engineering and Technology
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• v.56 no.7
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• pp.2828-2834
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• 2024

This research intends to recycle bone and incorporate it into concrete for radiation shielding application using Phy-X/PSD software. Cement, sand and granite were mixed in proportion of 0.5 kg:1 kg:1 kg to obtain sample A. Other concretes composing of cement, sand, granite and bone ash was in proportion 0.45 kg:1 kg:1 kg:0.05 kg, 0.1 kg:1 kg:1 kg:0.4 kg and 0.35 kg:1 kg:1 kg:0.15 kg to obtain samples B, C and D respectively. 0.5 water-to-cement (W/C) ratio was adopted throughout the mixes because the control mix contain the normal water quantity for normal hydration of cement. Replacing the bone ash for the cement in the fabricated concretes enhances their densities where the fabricated concretes' density decreased from 2.33 g/cm³ to 2.22 g/cm³ by raising the reinforcing bones fly ash concentration from 0 to 0.15 kg. Additionally, increasing the bones fly ash concentration within the fabricated concretes increases their linear attenuation coefficient (LAC) where the fabricated concretes' μ values at 0.662 MeV reach 0.181 cm^-1, 0.178 cm^-1, 0.174 cm^-1, and 0.171 cm^-1, respectively for concretes A, B, C, and D. The use of other local materials is recommended, as it improves waste management being the major aim of the sustainable development goal.

• Journal of the Korean Institute of Rural Architecture
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• v.21 no.2
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• pp.35-42
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• 2019

There are 17,427 reservoirs in Korea, of which about 96% were built before the mid 1980s. Therefore, aging is severe and reinforcement are necessary. In addition, aged reservoirs, which are more than 50 years old, account for 70% of the total. Therefore, there is a problem such as the collapse of the reservoir and the decrease of the storage capacity due to progress of aging with time. The grouting method using cement is mainly used as maintenance and reinforcement method of old reservoir. However, the grouting method using cement has engineering and environmental problems. In order to solve the engineering and environmental problems of cement grouting method, an eco-friendly grouting material was developed that mixes circular resource grouting binder, high molar ratio sodium silicate and colloidal silica. The engineering and environmental properties of the developed injection materials were evaluated by conducting gel time, homo-gel strength, sea water resistance test and environmental stability evaluation. Also, examined the possibility of replacing OPC existing aged reservoir reinforcement methods. As a result, it was found out that it was better than the conventional cement method in terms of engineering and environment. However, since this study is the result of laboratory test, it is necessary of verify the application at field of aged reservoir.

• Journal of the Korean Recycled Construction Resources Institute
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• v.10 no.3
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• pp.335-342
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• 2022

In this study, self-healing hybrid capsules were prepared by mixing self-healing solid capsules and self-healing microcapsules using inorganic materials as core materials. Self-healing hybrid capsules were mixed with 3 % according to the composition ratio of 3:7, 5:5, and 7:3 based on the mass of the cement to prepare a self-healing cement composite material. The healing properties of crack self-healing hybrid capsules were evaluated through hydrostatic water permeability test and surface crack monitoring. It was found that the self-healing hybrid capsules prepared by mixing the composition ratio of the self-healing solid capsules and the self-healing microcapsules at 7:3 has a great effect on improving the crack self-healing performance.

• Korean Journal of Agricultural Science
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• v.15 no.1
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• pp.82-94
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• 1988

This study was performed to obtain the basic data which can be applied to use of foaming mortars. The results obtained were summarized as follows ; 1. The lowest water-cement ratios were shown at the mixing ratio of 1 : 1. But, it was gradually increased in poorer mixing ratio and decreased in more addition of foaming agent. The water-cement ratios were decreased up to 1.6-53.1% by mix-foaming type and 4.4-24.1% by pre-foamed type than cement mortar. 2. The highest bulk densities were shown at the mixing ratio of 1 : 1. But, it was gradually decreased in poorer mixing ratio and more addition of foaming agent. The decreasing rates of bulk densities were increased in richer mixing ratio and more addition of foaming agent. 3. The bulk densities were decreased up to 38.8-55.9% by mix-foaming type and 9.7-23.6% by pre-foamed type than cement mortar. 4. The lowest absorption rates were shown at the mixing ratio of 1 : 1. But, it was gradually increased in poorer mixing ratio and more addition of foaming agent. The increasing rates of absorption rates were increased in richer mixing ratio and more addition of foaming agent. 5. Absorption rates when immersed in 72hours were shown up to 3.41-5.85 times greater by mix-foaming type and 1.05-1.55 times greater by pre-foamed type than those of cement mortar. it was significantly higher at the early stage of immersed time than cement mortar. 6. The highest strengths were shown at the mixing ratio of 1 : 1. But, it was gradually decreased in poorer mixing ratio and more addition of foaming agent. The decreasing rates of strengths were increased in poorer mixing ratio and more addition of foaming agent. 7. The strengths were decreased up to 77.0-92.8% by mix-foaming type and 36.7-74.4% by pre-foamed type than cement mortar. 8. The lowest air contents were shown at the mixing ratio of 1 : 1. But, it was gradually increased in poorer mixing ratio and more addition of foaming agent. The increasing rates of air contents were increased in richer mixing ratio and more addition of foaming agent. 9. Air contents were shown up to 26.0-63.8 times greater by mix-foaming type and 5.8-17.7 times greater by pre-foamed type than those of cement mortar. 10. The correlations between bulk density, absorption rate, compressive strength and air content were highly significant. The multiple regression equations of bulk density, absorption rate, compressive strength, tensile strength, bending strength and air content were computed depending on a function of mixing ratio and addition of foaming agent. They were generally highly significant.

• Journal of the Korean Geosynthetics Society
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• v.20 no.4
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• pp.19-32
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• 2021

In this study, evaluation and consideration of domestic/overseas design, construction, and quality control performed by the authors on the deep cement mixing method were performed, and improvements for the development of the DCM method were suggested in the future. As a result of this study, it was found that the cross-sectional area correction for strength is required during the laboratory test of mix proportion, and caution is required because the extrapolation method may lead to different results from the actual one. Applicable design methods should be selected in consideration of both the improvement ratio and the type of improvement during design, and it was confirmed that the allowable compressive strength to which the safety factor was applied refers to the standard value for stability review and not the design parameters. In the case of the stress concentration ratio, rather than applying a conventional value, it was possible to perform economical design by calculating the experimental and theoretical stress concentration ratio reflecting the design conditions. In the case where pre-boring is expected during construction, if the increased water content is not large compared to the original, there were cases where a major problem did not occur even if the result that did not consider the increase in water content was used. In addition, it was confirmed that when the ratio of the top treatment length to the improved length is high, a small amount of design cement contents per unit length can be injected during construction. In the case of quality control, it was evaluated that D/4~2D/4 for single-axis and D/4 point for multi-axis were optimal for coring of grouting mixtures. As an item for quality control, it is judged that the standard that considers the TCR along with the unconfined compressive strength of grouting mixtures is more suitable for the domestic situation.

• Advances in concrete construction
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• v.5 no.1
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• pp.31-48
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• 2017

Supplementary cementitious materials (SCM) have turned out to be a vital portion of extraordinary strength and performance concrete. Metakaolin (MK) is one of SCM material is acquired by calcinations of kaolinite. Universally utilised as pozzolanic material in concrete to enhance mechanical and durability properties. This study investigates the fresh and hardened properties of conventional concrete (CC) and self compacting concrete (SCC) by partially replacing cement with MK in diverse percentages. In CC and SCC, partial replacement of cement with MK varies from 5-20%. Fresh concrete properties of CC are conducted by slump test and compaction factor tests and for SCC, slump flow, T500, J-Ring, L-Box, V-Funnel and U-Box tests. Hardened concrete characteristics are investigated by compressive, split tensile and flexural strengths at age of 7, 28 and 90 days of curing under water. Carbonation depth, water absorption and density of MK based CC and SCC was also computed. Fresh concrete test results indicated that increase in MK replacement increases workability of concrete in a constant w/b ratio. Also, outcomes reveal that concrete integrating MK had greater compressive, flexural and split tensile strengths. Optimum replacement level of MK for cement was 10%, which increased mechanical properties and robustness properties of concrete.

• Proceedings of the Korea Concrete Institute Conference
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• 2002.10a
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• pp.531-536
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• 2002

Silica fume influences concrete diffusivity and permeability as well as strength by densifying the microstructure of the interfacial transition zone (ITZ) of high strength concrete, by reducing the capillary porosity of cement paste and by producing less diffusible and permeable pozzolanic CSH gel than CSH gel of conventional cement hydration. This paper presents a procedure to predict the chloride ion diffusivity and water permeability of the high strength concrete containing silica fume. Water binder ratio, silica fume addition, degree of hydration and volume fraction of aggregates are considered as the major factors influencing concrete diffusivity and permeability in the procedure. Analytical results using the procedure are shown and verified with other data.

• Proceedings of the Korean Society of Agricultural Engineers Conference
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• 2003.10a
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• pp.395-398
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• 2003

This study is performed to evaluate the engineering properties of cement mortar with hwangtoh and fly ash The absorption ratio is in the range of $5.22{\sim}13.16%\;and\;8.53{\sim}13.29%$ at the curing age 14 and 28 days, respectively. The compressive strength is in the range of $92{\sim}458kgf/cm^2\;and\;88{\sim}316kgf/cm^2$ in water and dry cruing at the curing age 28days, respectively. The bending strength and dynamic modulus of elasticity are shown in similar tendency in water and dry curing.