• Proceedings of the KSEEG Conference
• /
• 2007.04a
• /
• pp.475-477
• /
• 2007

See Full Text

• Proceedings of the Korea Water Resources Association Conference
• /
• 2023.05a
• /
• pp.247-247
• /
• 2023

Coastal lagoons play a crucial role in water exchange, water quality, and biodiversity. It is essential to monitor and understand the dynamics of hydrogeochemistry in lagoon water and its groundwater to preserve and sustainably manage the groundwater-dependent ecosystems like coastal lagoons. This study investigated the spatial and temporal hydrogeochemical characteristics of coastal lagoon (Songjiho) and groundwater on the east coast of Korea. The concentrations of major ions, water isotopes, and nutrients (nitrogen and dissolved organic carbon) in lagoon water and groundwater were periodically monitored for one year. The study revealed that major ions and total dissolved solids (TDS) concentration were higher at deeper depths of aquifers and closer to the coastal area. The hydrogeochemical characteristics of coastal lagoon and groundwater chemistry were classified into two types, Ca-Mg-HCO₃ and Na-Cl, based on their spatial location from inland to coastal area. Moreover, the hydrogeochemical characteristics of coastal lagoons and groundwater varied significantly depending on the season. During the wet season, the increased precipitation and evaporation lead to changes in water chemistry. As a result, the total organic carbon (TOC) of coastal lagoons increases during this season, likely due to increased runoff by rainfall whereas the variation of chemical compositions in the lagoon and groundwater were not significant because there is reduced precipitation, resulting in stable water levels and during the dry season. The study emphasizes the impact of spatial distribution and seasonal changes in precipitation, evaporation, and river discharge on the hydrogeochemical characteristics of the coastal aquifer and lagoon system. Understanding these impacts is crucial for managing and protecting coastal lagoons and groundwater resources.

• Economic and Environmental Geology
• /
• v.49 no.3
• /
• pp.167-179
• /
• 2016

Water quality of Oseepchun, Dogye area, was investigated quantitatively for its origin and hydrogeochemistry in relation to the influence of groundwater. Groundwater appears to be the principal source of Oseepchun from the water-quality monitoring data including redox potentials, composition of dissolved ions and their correlations, hydrogen and oxygen stable isotopic ratios, and the distribution and occurrence of contaminants. Water-quality type of the surface water was grouped by the water-rock interactions as $Ca-HCO_3$ type originated from carbonated bed-rocks in the Joseon Supergroup, (Ca, Mg)-$SO_4$ type related with dissolution of surfide minerals in coal beds of Pyeongan Supergroup, and (Ca, Mg)-($HCO_3$, $SO_4$) type of the mixed one. Locally water pollution occurs by high $SO_4$ from mine drainage and $NO_3$ from waste-treatment facility. Intensive precipitation in summer has no effect on the water type of Oseepchun, but increases the inflow of nitrate and chloride originated from land surface. Results of this study direct that groundwater-surface water interaction is intimate, and thus surface-water resource management should begin with groundwater characterization.

• Economic and Environmental Geology
• /
• v.34 no.2
• /
• pp.175-192
• /
• 2001

We have collected hydrogeochemical data of shallow groundwaters in the Uljin area located at eastern coastal area of Korea. Geostatistical analysis (ANOVA test, cluster analysis, and factor analysis) of the collected data sets was pert'onned, in order to evaluate both the spatial and/or temporal variation of water quality data and the groundwater contamination, as weJl as the principal reactions occurring in the aquifer. Results of the ANOVA test show that regional water chemistry are not significantly changed spatially in eight watersheds. However, some ions such as $Ca^{2+}$, $HCO_{3}^{-}$ and $SO_{4}^{2-}$ show a meaningful watershed variation. Water chemistry variation according to sampling time (season) is not shown, except for $SO_{4}^{2-}$. The cluster analysis shows that significant water chemistry variation is eXplained by the distance from the coast. Factor analysis indicates that the water chemistry is changed according to various factors as follows: in the order of decreasing importance, water-rock interaction (mainly, carbonate dissolution), sea-salt spraying, and then contamination by fertilizers and agrochemicals.

• Journal of Soil and Groundwater Environment
• /
• v.11 no.3
• /
• pp.20-30
• /
• 2006

Hydrogeochemistry of deep geothermal water (temperature: $42.2-47.9^{\circ}C$) at Heunghae, Pohang was evaluated using core logging, temperature and electrical conductivity (EC) logging before and after pumping tests, chemical analysis of geothermal water with depth, and observation of water quality variations during pumping tests. The geology of the area is composed of highly fractured marine sedimentary rocks. The hydrogeochemistry of geothermal water varies with drilling depth, distance from the coast, and pumping duration. According to the temperature and EC variations during 4 times of pumping tests, main aquifer of the area is considered as the fractured zones (540 to 900 m) developed in rhyolitic rocks. The high content of Na and $HCO_3$ in geothermal water can be explained by the inflow of deep groundwater from inland regulated by dissolution of silicates and carbonates. High TDS, Na and Cl concentrations indicate that the geothermal water was also strongly affected by seawater. The molar ratios of Na:Cl ($0.88{\sim}2.14$) and Br:Cl ($21.0{\sim}24.9{\times}10^{-4}$) deviate from those of seawater (0.84 and $34.7{\times}10^{-4}$, respectively), suggesting that water-rock interaction also plays an important role in the formation of water quality.

• Journal of Environmental Science International
• /
• v.21 no.10
• /
• pp.1171-1179
• /
• 2012

Headwaters initiate material export to downstream environments. A nested headwater study examined the flux of dissolved constituents and water from a perennial stream and four ephemeral/intermittent streams in the Upper Gulf Coastal Plain of Mississippi. Water was collected during storm and baseflow conditions. Multiple linear regression was used to model constituent concentration and calculate flux. Event was the major source of water discharged from the ephemeral and intermittent streams however, baseflow was the major source for water discharged by the perennial stream during events. The perennial stream had an area weighted average yields of 10.1, 0.01, 1.03, 0.65 kg/ha/yr of DON (dissolved organic nitrogen), $NO_3^-$-N, $NH_4^+$-N and $PO_4^{-3}$, respectively while large variabilities existed between the ephemeral and intermittent streams. These findings highlight the importance of headwaters in protecting the low order drainage basins as a key to water quality within perennial streams.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
• /
• 2000.11a
• /
• pp.232-236
• /
• 2000

Multi-regression statistical analyses were applied for the water quality data of shallow alluvial ground water (n = 47) collected from the Youngdeok area, in order to quantitatively generalize the natural (non-anthropogenic) causes of regional water quality variation. Seven samples having the high contamination index ( $C_{a}$ > 3) reflect the striong effects by anthropogenic activity. Most of the alluvial groundwaters have acquired their quality primarily due to the dissolution of carbonate minerals. The results of multi-regression analysis show that chlorine is mainly derived from seawater effect. Sulfur isotopic compositions of dissolved sulfur and the S $O_4$/Cl ratio also enable us to discriminate the samples (n = 18) which are affected by atmospheric input of marine aerosol (sea-spray) and also by mixing between freshwater and seawater. Hydrogen and oxygen isotope data of the samples collected lie close to the local meteoric water line obtained from nearby Pohang city but has lower slope (5.45) on the $\delta$D-$^{18}$ O plot, indicating that alluvial groundwater was recharged from infiltrated meteoric water which has undergone some degree of kinetic evaporation. The estimated initial isotopic composition of the recharged water ($\delta$D = -74.8$^{0}$ /$_{00}$, $\delta$$^{18}$ O = -10.8$^{[-1000]}$ /$_{[-1000]}$ ) suggests that the alluvial ground water recharge largely occurs during summer storm events.s.s.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
• /
• 2003.09a
• /
• pp.519-519
• /
• 2003

We performed a hydrochemical study on a total of 89 bedrock groundwaters collected from preexisting wells (30 to 300 m deep) in the Boeun area. Hydrochemical data showed significant variations in the area, due to varying degrees of anthropogenic pollution. The waters were mostly enriched in Ca and HCO$_3$ but locally contained significant concentrations of anthropogenic constituents in the general order of Cl >NO$_3$>SO$_4$. In particular, about 11% of the examined wells exceeded the drinking water standard with respect to nitrate. We consider that aquifers in the area are locally highly susceptible to the contamination related to agricultural activities. Diagrams showing the relationships between the summation of cations (∑cations) and the concentration of several anions with different origin (natural versus anthropogenic) were used to estimate the relative role of anthropogenic contamination. A good correlation was observed for the relationship between ∑cations and bicarbonate, indicating that water-rock interaction (namely, hydrolysis of silicate minerals) is most important to control the water quality. Thus, we made an assumption that the equivalent of dissolved cations for a water should be equal to the alkalinity, if the chemistry were controlled solely by a set of natural weathering reactions. If we excluded the equivalent quantities of cations and bicarbonate (natural origin) from the acquired data for each sample, the remainder therefore could be considered to reflect the degree of anthropogenic contamination. Finally, we performed a multiple regression approach for hydrochemical data using the ∑cations as a dependent variable and the concentration data of each anion (natural or anthropogenic) as an independent variable. Using this approach, we could estimate the relative roles of anthropogenic and natural processes. Rather than the conventional evaluation scheme based on water quality criteria, this approach will be more useful and reasonable for the evaluation of groundwater quality in a specific region and also can be used for planning appropriate protection and remedial actions.

• Economic and Environmental Geology
• /
• v.33 no.3
• /
• pp.181-193
• /
• 2000

This study was undertaken to evaluate the drinking water quality based on physicochemical properties and chemical compositions of the supply water in the Daedeok Campus, and to verify the analytical reliabilities of ICP-MS and IC equipped in the Central Research Facilities at Chungnam National University , Korea. The supply water belongs to $Ca^{2+}-({HCO_3}^-+{SO_4}^{2-})$type, whereas the original water from the Daecheong lake belongs to $(Ca^{2+}-(Mg^{2+})-{HCO_3}^-$ type. Generally, temperature (14.1$^{\circ}C$), pH (6.95), Eh (0 mV), electrical conductivity (117${\mu}$S/cm) and TDS (86.975mg/l) of supply water were higher than those of original lake water . Results using WATEQ4F revealed that potentially toxic ions of the supply water might exist mainly as free metals ($M^{2+}$) and a small amount as ${CO_3}^{2-}$ and $OH^-$ complexes. Also, the water composition belongs to the kaolinite field. Calculated average enrichment indies of the supply water normalized to lake water for anions, mamor cations, toxic cations and total ions are 1.05 , 1.56, 13.05 and 1.17 , respectively. Those values of the ground water in the Daedeok Campus showed 1.71, 4.78, 5.71 and 2.49 , respectively. However , contents of all constituents of these water are within the drinking water standard. All samples were filtered before the chemical analysis. Pale yellow or yellowish brown colored materials of colloidal particles coated the filter paper to thickness of 0.02 to 0.2mm. these are mainly Fe-Cy-Zn compounds with traces of Ni and Pb, the net weights of which compounds range from 0.01to 3.20mg/l. Most elements did not show any conceivable filtering effect of Cu, Fe and Zn. Especially, mean concentration of total Fe decreased considerably from 168.52${\mu}g$/lto 42.58${\mu}g$/l by filtering .

• Journal of Soil and Groundwater Environment
• /
• v.29 no.3
• /
• pp.1-13
• /
• 2024

This study investigated the hydrogeochemical and microbiological characteristics of freshwater on Ulleung Island, a volcanic island in the Ulleung Basin on the East Coast of Korea. The shallow groundwater (CSW, NRGW) and the surface water (SISW) samples are classified as Na-HCO₃ type, reflecting an alkaline rock type and an oxidizing environment due to the influence of a highly permeable pyroclastic rock layer. In contrast, the deep groundwater sample (DMW) is classified as Ca-HCO₃ type, suggesting the influence of deep-sourced carbon dioxide and reducing conditions. Microbial communities in the water samples are generally dominated by Proteobacteria, with the relative abundance of major genera varying depending on water quality and environmental conditions. Network analysis reveals the ecological characteristics of microbial communities adapted to specific environments. The presence of pathogenic genera in the shallow groundwater suggests potential groundwater contamination, necessitating appropriate management to ensure its use as drinking water or domestic water. The findings of this study provide valuable insights into the ecological characteristics of Ulleung Island's groundwater resources and can inform future groundwater management strategies.