• Journal of the Korean Geotechnical Society
• /
• v.29 no.1
• /
• pp.93-107
• /
• 2013

Thermal conduction of the particulate composites or granular materials can be widely used in porous materials and geotechnical engineering. And it has continued to develop "effective thermal conductivity" of medium by modeling energy relationship among particles in medium. This study focuses on the development of the effective thermal conductivity at the unsaturated conditions of soils using the modified network model approach assisted by synthetic 3D random packed systems (DEM method, Discrete Element Method) at the particle scale. To verify the network model, three kinds of glass beads and the Jumunjin sand are used to obtain experimental values at various unsaturated conditions. The PPE (Pressure Plate Extractor) test is then performed to obtain SWCC (Soil-Water Characteristic Curve) of soil samples. In the modified network model, SWCC is used to adjust the equivalent radius of thermal cylinder at contact area between particles. And cutoff range parameter to define the effective zone is also adjusted according to the SWCC at given conditions. From a series of laboratory tests and the proposed network model, the modified network model which adopts a SWCC shows a good agreement in modeling thermal conductivity of granular soils at given conditions. And an empirical correlation between the fraction of the mean radius (${\chi}$) and thermal conductivity at given saturated condition is provided, which can be used to expect thermal conductivity of the granular soils, to estimate thermal conductivity of granular soils.

• The Journal of Advanced Prosthodontics
• /
• v.10 no.5
• /
• pp.374-380
• /
• 2018

PURPOSE. The effect of silica-based glass-ceramic liners on the tensile bond strength between zirconia and resin-based luting agent was evaluated and compared with the effect of 10-methacryloyloxydecyl dihydrogen phosphate (MDP)-containing primers. MATERIALS AND METHODS. Titanium abutments and zirconia crowns (n = 60) were fabricated, and the adhesive surfaces of the specimens were treated by airborne-particle abrasion. The specimens were divided into 5 groups based on surface treatment: a control group, 2 primer groups (MP: Monobond Plus; ZP: Z Prime Plus), and 2 liner groups (PL: P-containing Liner; PFL: P-free Liner). All specimens were cemented with self-adhesive resin-based luting agent. After 24-hour water storage and thermocycling (5,000 cycles, $5^{\circ}C/55^{\circ}C$), the tensile bond strength was measured using a universal testing machine. Failure mode analysis and elemental analysis on the bonding interface were performed. The data were analyzed using Kruskal-Wallis test, Dunn's post hoc test, and Fisher's exact test. RESULTS. The liner groups and primer groups showed significantly higher tensile bond strengths than that of the control group (P<.05). PFL showed a significantly higher tensile bond strength than the primer groups (P<.05). The percentage of mixed failure was higher in the primer groups than in the control group (P<.001), and all the specimens showed mixed failure in the liner groups (P<.001). A chemical reaction area was observed at the bonding interface between zirconia and liner. CONCLUSION. The application of liner significantly increased the tensile bond strength between zirconia and resin-based luting agent. PFL was more effective than MDP-containing primers in improving the tensile bond strength with the resin-based luting agent.

• Journal of Korean Tunnelling and Underground Space Association
• /
• v.22 no.5
• /
• pp.485-500
• /
• 2020

Due to various advantages such as small facilities, ease of construction and so on, the grouting technology which is widely used in construction field has developed remarkably compared with the past. However, the efforts to improve the homogeneity of quality, long-term durability and environmental problems have been continued. In recent years, new grouting method has been developed in order to solve problems such as low strength, durability and leaching phenomenon of liquid glass (sodium silicate) grouting material in Korea. A newly developed method integrates the injection material with the ground by the self-healing material of crystallization growth type. For this reason, it is known that improvement of the durability and water quality of the ground, prevention of leaching, and environment friendliness can be expected. The present study applied a newly developed method to test sites and verified its effect such as injection range, improvement effect, waterproofing performance and so on. Standard penetration test, field permeability test, borehole shear test, pressuremeter test and pH test were conducted, and the results were compared between before and after developed method application. As results of tests, the field applicability and improvement effect of developed method were proved to be excellent.

• Journal of the Korean Wood Science and Technology
• /
• v.36 no.4
• /
• pp.19-25
• /
• 2008

This study was carried out to investigate the bending strength properties of the unreinforced glulam beams and the GFRP laminated glulam beams according to the volume ratio of GFRP. The 7-layer glulam beams ($10cm(b){\times}14cm(h){\times}180cm(l)$) were manufactured, using Larch (Larix kaempferi Carr.) laminae ($2cm(h){\times}10cm(b){\times}360cm(l)$), which were dried to the moisture content of 8% and specific gravity of 0.54. GPRP of 0.1 and 0.3 cm was reinforced between the outmost layer of bottom and next layer. When the glulam beams were reinforced with GFRP at the volume ratio of 0.7% and 2.1%, respectively, the bending strength was increased by 12% and 28%, respectively, in the reinforced beams than in control glulam beams. Also, the GFRP reinforced layer of the glulam beams with GFRP laminations blocked the progression of rupture, and the unbroken part held about 90% of the bending strength. In the results of glue joints test, the block shear strength is higher than $7.1N/mm^2$, the standard of KS F3021, and in the result of delamination, the adhesive strength is good as the water soaking and boiling delamination was less than 5%.

• Korean Journal of Materials Research
• /
• v.4 no.3
• /
• pp.319-328
• /
• 1994

Aluminium and titanium precursors containing $\beta$-diketonate ligands were used for the synthesis of polymeric sols of alumina and titania by sol-gel methods. To prepare polymeric sols by solgel processing, we synthesized modified precursors having chelating organic ligands. With these precursors it was found to be possible to control both hydrolysis and polycondensation reaction rates which resulted in ultrafine particles few nms of average size. The optimum molar ratio of acid to alkoxide for alumina sol was 0.3-0.4 and that of water to alkoxide &as 1. On the other hand, the corresponding ratios for titania sol were found be 0.25-0.20 and 1 respectively. Dynamic light scattering measurements indicated that the average particle size in both sols was in the order of few nms. SEM photographs were taken to observe crack-free and smooth surfaces of coated membranes after sintering at $450^{\circ}C$. Alumina coated membrane on a slide glass had about 4-4.5$\mu \textrm{m}$, thickness and titania coated one had 2-2.5$\mu \textrm{m}$, thickness. And according to TEM photographs, the grain size of titania was smaller than 30nm and that of alumina was in the range of few $\AA$s to 2nms. An X-ray diffraction study revealed that alumina was $\gamma$ phase and titania was anatase crystal.

• Journal of Adhesion and Interface
• /
• v.17 no.2
• /
• pp.49-55
• /
• 2016

In this study, we designed an environment friendly, water-based adhesive using the acrylic emulsion method as a replacement for solvent-based adhesives, which are most commonly used in layered laminates for flexible food packaging. We designed adhesives with different combinations of anionic, non-ionic, and phosphoric ester surfactants, and with different concentrations of chain transfer agent (CTA). We also examined the effect of the degree of cross-linking by synthesizing and comparing 8 test group adhesives with different types of functional monomers. Additionally, we synthesized 2 other test group pressure-sensitive adhesives (PSA) using styrene/alpha-methyl styrene/acrylic acid (SAA) semipolymer dispersing agents (with molecular weights of 13,000 g/mol and 8,600 g/mol, respectively) to replace the conventional surfactants. We evaluated whether the 10 test group pressure-sensitive adhesives met the basic physical property criteria required for flexible food packaging by carrying out a physical analysis of their glass transition temperature (Tg), particle size, adhesion, and molecular weight. In our test, 2 test group adhesives manufactured with the combination of anionic and non-ionic surfactants, CTA concentration of 0.2%, and functional monomers of hydroxyethyl acrylate (HEA) and glycidyl methacrylate (GMA) demonstrated molecular weight and flexibility suitable for flexible packaging, with low adhesiveness and small particle size.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2016.02a
• /
• pp.320-320
• /
• 2016

Nanocrystalline Carbon thin films have numerous applications in different areas such as mechanical, biotechnology and optoelectronic devices due to attractive properties like high excellent hardness, low friction coefficient, good chemical inertness, low surface roughness, non-toxic and biocompatibility. In this work, we studied the comparison of pure DC power and pulsed DC power in plasma sputtering process of carbon thin films synthesis. Using a close field unbalanced magnetron sputtering system, films were deposited on glass and Si wafer substrates by varying the power density and pulsed DC frequency variations. The plasma characteristics has been studied using the I-V discharge characteristics and optical emission spectroscopy. The films properties were studied using Raman spectroscopy, Hall effect measurement, contact angle measurement. Through the Raman results, ID/IG ratio was found to be increased by increasing either of DC power density and pulsed DC frequency. Film deposition rate, measured by Alpha step measurement, increased with increasing DC power density and decreased with pulsed DC frequency. The electrical resistivity results show that the resistivity increased with increasing DC power density and pulsed DC frequency. The film surface energy was estimated using the calculated values of contact angle of DI water and di-iodo-methane. Our results exhibit a tailoring of surface energies from 52.69 to $55.42mJ/m^2$ by controlling the plasma parameters.

• Polymer(Korea)
• /
• v.36 no.3
• /
• pp.380-392
• /
• 2012

Four kinds of N,O-hydroxypropyl chitosans (HPCTOs) with degree of substitution(DS) and molar substitution (MS) ranging from 2.47 to 2.52 and 4.9 to 7.8, respectively were synthesized, and their molecular chracteristics and thermotropic and lyotropic liquid crystalline properties were investigated. MS was exceedingly larger than DS, showing that in the later stages of reaction, propylene oxide was preferentially added to the side chains rather than the main chain. All the derivatives formed thermotropic cholesteric phases. The glass and clearing temperatures were decreased with increasing MS. The optical pitches (${\lambda}_m$'s) of the thermotropic cholesteric phases increased with temperature. However, the ${\lambda}_m$'s of the derivatives at the same temperature increased with increasing MS. Solutions of HPCTOs in water, methanol, ethanol, acetic acid, and formic acid containing more than 30 wt% polymer also formed cholesteic phases whose ${\lambda}_m$'s decreased exponentially with increasing polymer concentration. The concentration dependence of ${\lambda}_m$ of HPCTO solutions, however, highly depended on the nature of the solvent and MS. The thermotropic and lyotropic mesophase properties of HPCTOs were significantly different from those reported for hydroxypropyl celluloses. The results indicate that the secondary amino group in the C-2 position plays an important role on the formation, stabilization, and temperature and concentration dependencies of ${\lambda}_m$ of the cholesteric mesophase.

• Journal of the Korea Concrete Institute
• /
• v.25 no.3
• /
• pp.261-269
• /
• 2013

In this study, it was developed eco-friendly inorganic binding material concrete using ground granulated blast furnace slag and alkali activator (water glass, sodium hydroxides). Eight reinforced concrete beam using inoganic binding material concrete were constructed and tested under monotonic loading. The major variables were mixture ratio of alkali activator, type of admixture and admixture. Experimental programs were carried out to improve and evaluate the flexural performance of such test specimens, such as the load-displacement, the failure mode, the maximum load carrying capacity, and ductility capacity. All the specimens were modeled in scale-down size. The eco-friendly concrete using inorganic binding material encouraged alkali activation reaction was rapidly hardening speed and showed possibility as a high strength concrete. Also, the RC beams using new materials showed similar behavior and failed similarly with RC beam used portland cement. It is thought that eco-friendly inorganic binding material concrete can be used with construction material and product as a basic research to replace cement concrete. If there is application to structures in PC member as well as production of 2nd concrete product, it could be improved the productivity and reduction of construction duration etc.

• Journal of the Korean Wood Science and Technology
• /
• v.43 no.6
• /
• pp.868-875
• /
• 2015

In order to replace existing slit type steel plate on the wooden structure joint, the FRP-reinforced laminated plates were produced. Four types of FRP-reinforced laminated plates were produced according to the type of reinforcement and adhesive, and before applying to the joint, the adhesion performance test according to KSF 3021 and KSF 2160 and the Compact Tension (CT) type fracture toughness test specified in ASTM D5045-99 were carried out. As a result of adhesion performance test, all GFRP textile, GFRP sheet, and GFRP Textile-Sheet type FRP-reinforced laminated plates satisfied the requirement of soaking delamination percentage with smaller than 5% based on KS standard. However, aramid type specimen satisfied the standard as the soaking delamination percentage of 4.8% but it did not satisfied the standard as the water proof soaking delamination percentage of 70%. As a result of fracture toughness test, the volume ratio of reinforcement to timber became 23% so that the strength of FRP-reinforced laminated plates increased by two to four times in comparison to the control specimen. It was confirmed that the GFRP Textile-Sheet type specimen was most resistant to the fracture most since the ratio of stress intensity factor compared with that of the control increased to 61% owing to the parallel arrangement of glass fiber to the load. As a result of tensile shear strength test using FRP-reinforced laminated plates and nonmetal dowels, it is about 12% lower than metal connectors.