• Title/Summary/Keyword: water corrosion

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Effect of oxide film on ECT detectability of surface IGSCC in laboratory-degraded alloy 600 steam generator tubing

  • Lee, Tae Hyun;Ryu, Kyung Ha;Kim, Hong Deok;Hwang, Il Soon;Kim, Ji Hyun;Lee, Min Ho;Choi, Sungyeol
    • Nuclear Engineering and Technology
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    • v.51 no.5
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    • pp.1381-1389
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    • 2019
  • Stress corrosion cracking (SCC) widely found in both primary and secondary sides of steam generator (SG) tubing in pressurized water reactors (PWR) has become an important safety issue. Using eddy-current tests (ECTs), non-destructive evaluations are performed for the integrity management of SG tubes against intergranular SCC. To enhance the reliability of ECT, this study investigates the effects of oxide films on ECT's detection capabilities for SCC in laboratory-degraded SG tubing in high temperature and high pressure aqueous environment.

An Experimental Study on Development of Physical Properties and Durability of Concrete Spread with Inorganic Antibiotics (무기질 항균제 도포에 의한 콘크리트의 경화성상 및 내구성상 향상에 관한 실험적 연구)

  • Kim, Moo-Han;Khil, Bae-Su;Kim, Jae-Hwan;Cho, Bong-Suk;Lee, Eui-Bae
    • Journal of the Korea Institute of Building Construction
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    • v.5 no.3 s.17
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    • pp.75-82
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    • 2005
  • Sewage facilities are positively necessary for environment improvement such as rainwater removal, sewage disposal, preservation of the quality of water and health of the citizens in present-day. Meanwhile, a deterioration of the concrete sewer pipe is increasing rapidly due to the chemical and physical attack and especially biochemical attack that is to say biodeterioration. So, in advanced countries, prediction techniques and corrosion inhibition system for sewer concrete are developed and are being applied. Also, antibiotics were developed already but application of that is low because it is not economical and has no practical use. But, in domestic, countermeasures for the corrosion of sewage concrete are not sufficient and biochemical attack is not reflected in those essentially. In this study, to prevent biochemical corrosion of the sewer concrete, surface of the concrete was spread with liquefied inorganic antibiotics and then its engineering properties were experimentally investigated. As a result, compressive strength of the specimen spread with antibiotics were similar to those of non spread, Both bond strength and abrasion amount of the specimen spread with antibiotics were inferior to non spread. Properties of absorption and air permeability of the specimen spread with antibiotics were superior to non spread. Finally, carbonation depth, chloride ion penetration depth and weight change ration of the specimen spread with antibiotics were smaller than non spread.

Syntheses of Novel Sol-Gel Precursor Containing Anti-corrosive Functional Group and Their Uses in Organic-Inorganic Hybrid Coatings (내부식성이 우수한 졸-젤 전구체의 합성 및 이를 함유하는 유무기 하이브리드 코팅재)

  • Han, Mi-Jeong;Mang, Ji-Young;Seo, Ji-Yeon
    • Polymer(Korea)
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    • v.34 no.5
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    • pp.405-409
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    • 2010
  • New sol-gel precursors having the ability to protect iron against corrosion were synthesized and used to prepare organic-inorganic hybrid coatings based on epoxy. Bisphenol A epoxy was modified with 3-isocyanatopropyltriethoxysilane to improve the compatibility, and water and HCl were used as catalysts for sol-gel process. Various coating formulations were prepared depending on the type of sol-gel precursors and the amount of each ingredient, and cast on iron substrates by dip-coating and thermally cured. Corrosion protection properties of coated iron were studied by a salt spray test and electrochemical impedance spectroscopy under 0.1 M NaCl electrolyte. Hybrid coatings containing anticorrosive functional group exhibited excellent corrosion protection on iron, compared to that of typical hybrid coatings. From electrochemical impedance spectroscopy, the hybrid coatings containing anticorrosive functional group could maintaine the initial impedance after 500 h, while the impedance of hybrid coatings without them started to decrease after 24 h.

Stability Analysis of Green Revetment Media Using Hydraulic Model (수리모형을 이용한 호안녹화기반재의 수리적 안정성 분석)

  • Kwon, Hyo Jin;Kim, Sung Hee;Koo, Bon Hak
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.16 no.4
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    • pp.15-26
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    • 2013
  • In recent years, river maintenance projects using natural methods have been continuously implemented in urban areas and methods emphasizing ecology are being developed and constructed in revetment areas. However, there is insufficient technical review on the hydraulic stability of those revetment methods during the event of flood. Therefore, a hydraulic analysis is necessary for the stream where revetments are applied. This study was conducted to develop an objective test method for the hydraulic stability of green revetment media. For this purpose, hydraulic model tests were performed for the green base materials for revetments. Tests were conducted using experimental devices for the hydraulic model which were installed to simulate the rapid current during the flood. Loss of soil by the hydraulic condition was compared and analyzed with that of dry green revetment media, and the evaluations were made on the corrosion resistance, tractive force, and contractile force. Test results showed that green revetment media had higher corrosion resistance in non-vegetation condition compared to dry green revetment media, and the loss of base materials by the rooting of vegetation showed significant reduction by the vegetation. In addition, results of the allowable tractive force of the base material indicated it is relatively stable in vegetation condition but scouring can occur in non-vegetation condition. Therefore, the development of vegetation in revetment areas is anticipated to be effective for the stability of revetment areas by reducing external forces interacting with the corrosion resistance and stream bank. The green revetment media in expected to contribute to the stability of revetment areas.

The study on corrosion fatigue and cathodic protection of the steel plates used for the shipbuilding (조선용강재의 부식피로와 전기방식에 관한 연구)

  • 전대희;김원녕;이의호
    • Journal of Advanced Marine Engineering and Technology
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    • v.9 no.2
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    • pp.126-142
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    • 1985
  • The plane bending corrosiion fatigue test for the welded metal parats was performed in the air and in the natural sea water with and without applying cathodic protection. The specimens tested were the weld of SM41 steel plates, SM58 steel plates and of SM41 to SM58, which were all prepared by submerged arc welding. The main results obtained from the experiment are summarized as follows: (1) In case with SM41 and SM58 steel plates, lower value of impact strength, higher value of hardness and more noble electrode potential were observed in the welded metal part than in the HAZ and base metal. Also the lowest hardness zone in the HAZ was observed with SM58 which was not found with SM41. In case with weld specimen of SM41 to SM58, the impact strength and the electrode potential of the welded metal part showed again the lowest and most noble value but the hardness value was located between those of SM41 and SM58 base metal. (2) In the fatigue test, the specimens tested in the air and under the cathodic protection were both cracked in a purely mechanical mode, but the specimens tested without cathodic protection were cracked by the combination of mechanical fracture and electro-chemical corrosion. (3) The corrosion fatigue limit of the welded metal parts of the specimen was increased by the cathodic protection. As the protection potential was varied down to -800 mV vs. SCE the fatigue limit was increased to the value tested in the air, and the maximum fatigue limit appeared at the -1, 000 - -1, 200 mV vs. SCE. However, as the protection potential was further decreased below -1, 200 mV vs.SCE, the fatigue limit of weld of SM58 and of SM41-SM58 joining was decreased but the limit was almost constant in the case of weld of SM41. (4) It is suggested that when designing steel ship the corrosion fatigue limit of welded metal parts should be stressed as a designing strength of the structure of steel ship in addition to the conventional basis considering simply tensile strength of steel and safety factor.

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A Study on the Removal Method of Radioactive Corrosion Product using its Magnetic Property (방사성 부식생성물의 자기적 성질을 이용한 제거방법에 대한 연구)

  • 송민철;공태영;이건재
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.1 no.1
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    • pp.73-79
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    • 2003
  • In a pressurized water reactor, radioactive corrosion products (CRUD) in primary coolant system are one of the major sources for the occupational radiation exposure of the personnel in a nuclear power plant. Through the recent trend of long term fuel cycle in a nuclear power Plant, radioactive corrosion products deposited in reactor core for a long time are also the cause of Axial Offset Anomaly (AOA) having m effect on reactor power by the hideout of boron. CRUD consist primarily of magnetite, nickel ferrite, cobalt ferrite, and so on. They have the characteristic of strong magnetism. Therefore it is performed the conceptual design to develop the filter which removes the CRUD by magnetic field that is generated by an arrangement of permanent and electric magnets. Contrary to the conventional filter, the proposed filter does not interrupt the fluid flow, so there is little pressure drop and it can be used continuously. It is expected to be applied as one of the technologies for removal of the CRUB.

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Electrochemical Migration Characteristics of Sn-3.0Ag-0.5Cu Solder Alloy in NaBr and NaF Solutions (NaBr 및 NaF 용액에 대한 Sn-3.0Ag-0.5Cu 솔더 합금의 Electrochemical Migration 특성)

  • Jung, Ja-Young;Jang, Eun-Jung;Yoo, Young-Ran;Lee, Shin-Bok;Kim, Young-Sik;Joo, Young-Chang;Chung, Tai-Joo;Lee, Kyu-Hwan;Park, Young-Bae
    • Journal of Welding and Joining
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    • v.25 no.3
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    • pp.57-63
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    • 2007
  • Electrochemical migration characteristics of Pb-free solder alloys are quantitatively correlated with corrosion characteristics in harsh environment conditions. In-situ water drop test and corrosion resistance test for Sn-3.0Ag-0.5Cu solder alloys were carried out in NaBr and NaF solutions to obtain the electrochemical migration lifetime and pitting potential, respectively. Sn-3.0Ag-0.5Cu solder alloy shows similar ionization and electrochemical migration behavior with pure Sn because of Ag and Cu do not migrate due to the formation of resistant intermetallic compounds inside solder itself. Electrochemical migration lifetime in NaBr is longer than in NaF, which seems to be closely related to higher pitting potential in NaBr than NaF solution. Therefore, it was revealed that electrochemical migration lifetime of Sn-3.0Ag-0.5Cu solder alloys showed good correlation to the corrosion resistance, and also the initial ionization step at anode side is believed to be the rate-determining step during electrochemical migration of Pb-free solders in these environments.

Effect of Texture on the Corrosion and Wear Behaviors of 0.04% Gd-Duplex Stainless Steels (0.04% Gd-이상 스테인레스 강의 부식 및 마모성에 대한 집합조직 효과)

  • Baek, Yeol;Choe, Yong;Mun, Byeong-Mun;Son, Dong-Seong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2014.11a
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    • pp.212-212
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    • 2014
  • 0.04% Gd-duplex stainless steels (Gd-DSTSs) for neutron absorbing materials were inert arc-melted and poured into a Y-shape block with the size of $100{\times}100{\times}20[mm]$. The Gd-DSTS was hot rolled at $1200^{\circ}C$ followed by cold rolling to have 33% reduction. The average grain sizes of the rolling (RD), transverse (TD) and short transverse (ST) directions were 6, 7, $11{\mu}m$, respectively. The micro-hardnesses of the RD, TD and ST directions were 258.5, 292.3, 314.7 $H_V$, respectively. Corrosion potential and corrosion rate of the cold rolled Gd-duplex stainless steel in aerated artificial sea water and 0.1M $H_2SO_4$ solution were $0.2216V_{SHE}$, $0.0106A/cm^2$, $-0.0825V_{SHE}$, $0.0168A/cm^2$ for RD, $0.2210V_{SHE}$, $0.0077A/cm^2$, $0.0817V_{SHE}$, $0.0092A/cm^2$ for TD, $0.1056V_{SHE}$, $0.0059A/cm^2$, $0.0475V_{SHE}$, $0.0069A/cm^2$ for ST, respectively. The corrosion behavior depended on the texture, which were due to mainly grain boundary and minorly crystallographic texture. Friction coefficient and wear resistance were 2.07 and 0.48 mm, respectively.

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Effect of Milled Glass Fibers on Corrosion Resistance of PSC Grout Mortar (초단유리섬유가 PSC 그라우트의 부식저항성능에 미치는 영향)

  • Moon, Do-Young;Kim, Sang-Woon;Kim, Dong-Joo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.19 no.6
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    • pp.37-45
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    • 2015
  • In this experimental study, effect of milled glass fibers was investigated on corrosion resistance of PSC grout mortar. In order to check whether the mortar mixture with milled glass fibers satisfy the required properties as a PSC grout, time of flow, bleeding and compressive strength measured. The corrosion resistance were investigated through chloride ion migration test, mortar absorption test and surface resistivity measurement. It is confirmed that all proportions with milled glass fibers have better corrosion resistance than that with only OPC binder. Time of flow was reduced but the bleeding was increased to unacceptable level by using milled glass fibers. Consequently, the mix proportion with milled glass fibers for a PSC grout should be modified to have lower water/binder ratio.

Analysis of chloride penetration in the marine concrete pier (해양환경 콘크리트 교각의 염소이온 침투해석)

  • Kim, Ki-Hyun;Cha, Soo-Won;Jang, Sung-Yup;Park, Byoung-Sun;Chang, Sung-Pil
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.549-552
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    • 2008
  • Corrosion of reinforcing steel is prohibited under normal condition by the alkalinity of the pore water in the concrete. But the probability of steel corrosion becomes higher when the chloride ions are introduced into the concrete. Steel corrosion is decisive factor for the determination of service life of the marine concrete structures because chloride ions are abundant in the sea. In this paper, chloride penetration analysis for the rectangular pier in the marine environment is performed considering the diffusion movement of chlorides. Result reveals that the chloride concentration in the corner bar is higher than that of in the side bar with rectangular pier. Also the time to the specified accumulation of chloride in the corner bar is much shorter than that in the side bar. Because the corrosion initiation time of corner bar is half as much as that of side bar, service life for the rectangular pier in marine environment should be determined with respect to the coner bar.

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