• Title/Summary/Keyword: water corrosion

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A Study on Steel Properties for Floating Photovoltaic System Structure (수상태양광 구조물의 강재특성에 관한 연구)

  • Choi, Young-Kwan
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.8
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    • pp.5400-5405
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    • 2014
  • For the development of a floating photovoltaic system, materials with light weight and high tensile strength must be applied to reduce the burden on buoyancy, and material characteristics with high resistance to corrosion in water environment is required. Accordingly, a new high strength steel material with improved strength, durability, manufacturability, and weldability that are appropriate for floating photovoltaic system structures is needed. This paper reports the results of a mechanical load test and steel corrosion test on general steel (SS400) and high strength steel (POSH 690) for the selection of an appropriate steel material for a floating photovoltaic system. The results of a test on new high strength steel revealed excellent mechanical performance compared to general steel. The new steel material was manufactured for use in an actual site, and the weight was reduced by approximately 30~40% compared to existing general steel.

Effects of Proton Irradiation on the Microstructure and Surface Oxidation Characteristics of Type 316 Stainless Steel (양성자 조사가 316 스테인리스강의 미세조직과 표면산화 특성에 미치는 영향)

  • Lim, Yun-Soo;Kim, Dong-Jin;Hwang, Seong Sik;Choi, Min Jae;Cho, Sung Whan
    • Corrosion Science and Technology
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    • v.20 no.3
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    • pp.158-168
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    • 2021
  • Austenitic 316 stainless steel was irradiated with protons accelerated by an energy of 2 MeV at 360 ℃, the various defects induced by this proton irradiation were characterized with microscopic equipment. In our observations irradiation defects such as dislocations and micro-voids were clearly revealed. The typical irradiation defects observed differed according to depth, indicating the evolution of irradiation defects follows the characteristics of radiation damage profiles that depend on depth. Surface oxidation tests were conducted under the simulated primary water conditions of a pressurized water reactor (PWR) to understand the role irradiation defects play in surface oxidation behavior and also to investigate the resultant irradiation assisted stress corrosion cracking (IASCC) susceptibility that occurs after exposure to PWR primary water. We found that Cr and Fe became depleted while Ni was enriched at the grain boundary beneath the surface oxidation layer both in the non-irradiated and proton-irradiated specimens. However, the degree of Cr/Fe depletion and Ni enrichment was much higher in the proton-irradiated sample than in the non-irradiated one owing to radiation-induced segregation and the irradiation defects. The microstructural and microchemical changes induced by proton irradiation all appear to significantly increase the susceptibility of austenitic 316 stainless steel to IASCC.

Environmentally-Assisted Cracking of Austenitic Alloys in a PWR Environment (PWR 환경에서의 오스테나이트계 합금의 환경조장균열)

  • Hong, Jong-Dae;Jang, Hun;Jang, Changheui
    • CORROSION AND PROTECTION
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    • v.12 no.1
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    • pp.30-38
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    • 2013
  • Austenitic stainless steels and Ni-base alloys are widely used as structural materials for major components and piping system in pressurized water reactors (PWRs). These austenitic alloys are known to be susceptible to environmental assisted cracking (EAC), such as environmentally-assisted fatigue (EAF) and primary water stress corrosion cracking (PWSCC) during long-term exposure to PWR primary water environment. In this paper, the current understanding on the phenomena and mechanisms of these EAC are briefly introduced using experimental results and literature review. The mechanisms for EAF and PWSCC for austenitic stainless steels and Ni-base alloys are discussed. Currently, austenitic stainless steels are known to be more susceptible to EAF, while less susceptible to PWSCC than Ni-base alloys. The possible explanations to such behaviors are proposed and discussed in view of the role of hydrogen and internal oxidation.

Effects of Diverse Water Pipe Materials on Bacterial Communities and Water Quality in the Annular Reactor

  • Jang, Hyun-Jung;Choi, Young-June;Ka, Jong-Ok
    • Journal of Microbiology and Biotechnology
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    • v.21 no.2
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    • pp.115-123
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    • 2011
  • To investigate the effects of pipe materials on biofilm accumulation and water quality, an annular reactor with the sample coupons of four pipe materials (steel, copper, stainless steel, and polyvinyl chloride) was operated under hydraulic conditions similar to a real plumbing system for 15 months. The bacterial concentrations were substantially increased in the steel and copper reactors with progression of corrosion, whereas those in stainless steel (STS) and polyvinyl chloride (PVC) reactors were affected mainly by water temperature. The heterotrophic plate count (HPC) of biofilms was about 100 times higher on steel pipe than other pipes throughout the experiment, with the STS pipe showing the lowest bacterial number at the end of the operation. Analysis of the 16S rDNA sequences of 176 cultivated isolates revealed that 66.5% was Proteobacteria and the others included unclassified bacteria, Actinobacteria, and Bacilli. Regardless of the pipe materials, Sphingomonas was the predominant species in all biofilms. PCR-DGGE analysis showed that steel pipe exhibited the highest bacterial diversity among the metallic pipes, and the DGGE profile of biofilm on PVC showed three additional bands not detected from the profiles of the metallic materials. Environmental scanning electron microscopy showed that corrosion level and biofilm accumulation were the least in the STS coupon. These results suggest that the STS pipe is the best material for plumbing systems in terms of the microbiological aspects of water quality.

Development of Hybrid (Sb/Ca) Flooded Lead-Acid Battery for Minimizing Water Loss (감액 특성 향상을 위한 하이브리드(Sb/Ca) 액식 연축전지 개발)

  • Song, Seung Yun;Lim, Tae Seop;Kim, Sung Jun;Jung, Yeon-Gil;Yang, SeungCheol
    • Korean Journal of Materials Research
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    • v.32 no.3
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    • pp.146-152
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    • 2022
  • One disadvantage of deep cycle flooded lead-acid batteries is increasing water loss caused by use of (+) Pb-Sb / (-) Pb-Sb alloy grid. Water loss is generated by the emission of hydrogen gas from the (-) electrode during battery charging. In this paper, we maintain cycle life aspect through the development of hybrid flooded lead-acid batteries to which a (+) Pb-Sb / (-) Pb-Ca grid is applied and deal with the improvement of water loss. The amount of water loss compared to that of the (-) Pb-Sb grid decreased when Ca was added to the (-) Pb grid. For the (-) Pb-Ca grid, it was confirmed that the time to reach 0.0 V, at which water decomposition occurs, was increased compared to that of the (-) Pb-Sb grid at the NPV (Negative Potential Voltage). In the cycle life test conducted with the BCI (Battery Council International) standard, compared to the (+) Pb-Ca grid, the (+) Pb-Sb grid increased the life cycle of the batteries and the (+) Pb-Ca grid showed an early end of life due to PbO corrosion layer generation, as determined through SEM / EDS and Tear Down analysis. In conclusion, by addition of Sb to (+) Pb grid and Ca to (-) Pb grid, we developed a hybrid flooded lead-acid battery that meets user requirements to improve water loss characteristics and preserve cycle life characteristics.

An Experimental Study on the Permeability Evaluation of Metal Spray System by Concrete Surface Treatment (콘크리트 표면처리방법에 따른 금속용사 피막의 투수성 평가에 관한 실험적 연구)

  • Park, Jin-Ho;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2015.11a
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    • pp.34-35
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    • 2015
  • Recently, introduction of Advanced water treatment facilities has been increasing due to serious domestic water pollution. Ozone is a strong oxidizing materials in the advanced water treatment facilities. However, due to such a strong oxidation, Ozone eroded waterproofing/corrosion on the concrete surface and caused performance degradation. Therefore, in this study, permeability experiment of metal spraying system by concrete surface treatment was conducted.

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Deterioration of Concrete Columns under Sea-Water and Strengthening Analysis (해수중 콘크리트 기둥의 열화 및 보강성능해석)

  • 김규엽;송하원;변근주
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.11a
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    • pp.1169-1174
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    • 2001
  • In this study, the behavior of deteriorated concrete columns under sea-water before and after strengthening with glass fiber composite and the change of behavior by the deterioration of strengthening material are analyzed. In the analysis, the characteristics of concrete deteriorated in sea-water, preloading effect, and corrosion of steel are considered. The result of analysis is verified by the comparison with the experimental data. Using constitutive equations of the concrete and corroded steel, load-moment interaction curves of both deteriorated and strengthened concrete column are derived.

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Feasibility of icephobicity induced by self-propelling condensed water droplets

  • Lee, Hyung-Seok;Lee, Kyu Hwan;Park, Hyun Sun;Claessond, Per M.;Yun, Sang H.
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2015.11a
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    • pp.199-200
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    • 2015
  • 실리콘 기판위에 Gecko의 피부를 모사한 다층의 나노, 마이크로 구조표면에서 일어나는 응결된 water vapor droplets의 coalescence에 기인하는 surface energy의 kinetic energy의 변환을 통하여 발생하는 water droplets의 self-propelling을 이용한 빙점하에서 dynamic wetting 성질의 관찰을 통해서 얼음 방지, 지연, 또는 얼음 부착성 최소화 표면의 구현 가능성을 보여준다.

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A study on the Properties of Composite Systems Using Polymer-Modified Mortar and Epoxy Resins for Waterproofing and Anti-Corrosion of Concrete Structures (시멘트 혼입 폴리머와 에폭시수지를 복합한 수처리 콘크리트구조물용 방수방식재료의 성능평가에 관한 연구)

  • Bae Kee-Sun;Jang Sung-Joo;Oh Sang-Keun
    • Journal of the Korea Concrete Institute
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    • v.17 no.1 s.85
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    • pp.3-10
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    • 2005
  • The purpose of this study is to investigate the properties of composite systems using polymer cement and epoxy resins for waterproofing and anti-corrosion to concrete structures such as water supply facilities and sewage-works. For the waterproofing and anti-corrosion of concrete structures, there can be required various properties such as absorption capacity and water permeability, adhesion and tensile strength, hair crack-resistance, impact-resistance, repeated low and high temperature test and chemical resistance, soundness for drinking water, soundness for drinking water and etc. In this study these engineering properties of composite systems using polymer-modified mortar and epoxy resins were examined and could be confirmed to satisfy the guidelines of KS. Especially, it was turn out that the adhesion properties was excellent and high crack-resistance up to 1.49 mm will be perform.

LABORATORY STUDIES ON MIC OF AISI TYPE 304 STAINLESS STEEL USING BACTERIA ISOLATED FROM A W ASTEWATER TREATMENT SYSTEM

  • Sreekumari, Kurissery R.;Kyozo, Hirotani;Katsuya, Akamatsu;Takashi, Imamichi;Yasushi, Kikuchi
    • Proceedings of the KWS Conference
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    • 2002.10a
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    • pp.260-265
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    • 2002
  • Microbiologically influenced Corrosion (MIC) is one of the most deleterious effects of metal microbe interactions. When a fresh metal surface comes in contact with a non-sterile fluid, biofilm formation is ensued. This might result in the initiation of corrosion. The sites and materials where MIC is implicated are versatile. Industries such as shipping, power generation, chemical etc are reported to be affected. The rapid and unexpected failure of AISI type 304 stainless steel was investigated in the laboratory by simulation studies for a period of 4 months. Slime and water samples from the failure site were screened for corrosion causing bacteria. Both aerobic and anaerobic nora were enumerated and identified using PCR techniques. Pseudomonas sp. and Bacillus sp. were the most common aerobic bacteria isolated from the water and slime samples, whilst sulfate reducing bacteria (SRB) were the major anaerobic bacteria. The aerobic bacteria were used for the corrosion experiments in the laboratory. Coupon exposure studies were conducted using a very dilute (0.1%V/V) nutrient broth medium. The coupons after retrieval were observed under a Scanning Electron Microscope (SEM) for the presence of MIC pits. Compared to sterile controls, metal coupons exposed to Pseudomonas sp and Bacillus sp. showed the initiation of severe pitting corrosion. However, amongst these two strains, Psudomonas sp. caused pits in a very short span of 14 days. Towards the end of the experiment, severe pitting was observed in both the cases. The detailed observation of pits showed they vary both in number and shapes. Whilst the coupons exposed to Bacillus sp. showed widely spread scales like pits, those exposed to Pseudomonas sp. showed smaller and circular pits, which had grown in number and size by the end of the experiment. From these results it is inferred that the rapid and unexpected failure of 304 SS might be due to MIC. Pseudonwnas sp. could be considered as the major responsible bacteria that could initiate pits in the metallic structures. As the appearance of pits was different in both the tested strains, it was thought that the mechanisms of pit formation are different. Experiments on these lines are being continued.

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