• Title/Summary/Keyword: water corrosion

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A Study for Physical Properties and Corrosion for Metals after Softening of Wood (포화염수 삶음 처리가 목재의 물리적 특성 및 금속 부식에 미치는 영향)

  • Park, Jin Young;Kim, Soo Chul
    • Journal of Conservation Science
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    • v.35 no.6
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    • pp.621-630
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    • 2019
  • A woodblock softening process using saltwater was investigated in order to reduce the cracks and distortion caused by the woodblock-making process and to make the woodblock softer and sculpturing easier. Although anatomical studies of woodblocks have been ongoing for years, little work has been done on softening treatments using natural materials. Hence, the purpose of this paper is to investigate the change in the physical properties of wood treated with saturated brine and the effect of salt on metal nails found embedded in woodblocks. After boiling for twelve h each in water and saturated brine, the saltwater-boiled specimens have longer drying times than the water-boiled specimens. Further, it was observed that salt particles penetrated the cells in the wood. As a result of exposing the copper and iron nails, which were stuck in each specimen, to a high humidity environment, the weight of the saltwater-boiled specimens increased due to the hygroscopicity of the salt. Corrosion of the nails also occurred. This result is similar to the problem that appears on the edge of a woodblock. In conclusion, it was shown that salt in the wood cells affects the corrosion of metal embedded in the wood.

Study on the Resistance for Atmospheric Corrosion of Conventional Epoxy Resins applied to the Restoration of Iron Relics (철기 유물 복원에 사용되는 에폭시 수지 내후성 연구)

  • Lee, Sang-Jin;Kwon, Jeong-Soon;Nam, Byeong-Jik;Ahn, Byung-Chan
    • Journal of Conservation Science
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    • v.21
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    • pp.41-48
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    • 2007
  • The resistance for atmospheric corrosion of the conventional 5 epoxy resins (Araldite rapid, Araldite AW 106, Araldite SV 427, Devcon, and CDK), those were used to restoration of the iron relics, were investigated in this study. Temperature, UV light, and water were chosen for the factors of the atmospheric corrosion. The drastic voluminous changes of the epoxy resins were found at the temperature range between $40^{\circ}C$ and $70^{\circ}C$ After UV exposure, the colors of the epoxy resins were severely changed. In case of the indoor exposure the chroma value(${\Delta}E$) of the resins were less than 2, which showed a little changes of the colors. The result of the water contact angle test was Araldite rapid>AW 106>Devcon>SV 427>CDK. Although the contact angles of the resins were reduced by UV exposure, SV 427 was stable comparatively.

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The Development of Estimation Model for Iron Compound Originated from Anaerobic Microbial Corrosion (혐기성 미생물부식에 의해 생성되는 철화합물 추정식 개발)

  • Jeon, Seok-Jun
    • Journal of Korean Society on Water Environment
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    • v.18 no.4
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    • pp.379-386
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    • 2002
  • In this study, estimation model for iron compound originated from upflow, anaerobic fixed bed reactor, which treats sewage domestic wastewater, was developed. The estimation model was formulated by a mathematical expression which was based on the mass balance. Below the HRT of 60 minute, sulfide concentration combining with iron $FeS_2$ is the highest because the maximum sulfate consumption rate $V_{maxS}$ and half-saturation constant of sulfate $K_{mS}$ exert an important effect on the estimation model as temperature was increased. But increment of $FeS_2$ concentration is weakened above the HRT of 60 minutes and represent the lowest value at the HRT of 108 minutes. It implies that liquid phase distribution ratio of sulfide ${\alpha}r$ becomes lower as temperature was increased. While phosphorus concentration combining with iron $Fe_3(PO_4)_3$ is increased as HRT and temperature are increased, which is affected by phosphorus removal rate constant $k_p$. As the result of estimating the iron concentrations of corrosion by the model, the concentration of iron corrosion is higher than any other at the HRT of 108 minute and $20^{\circ}C$. The predicted values were compared with measured ones at different HRT(13.5, 27, 54, 108 min) and temperature(20, 25, $30^{\circ}C$). The experimental data could be fitted with the simulated curves. Therefore, the mathematical expression could be applicable to design full-scale wastewater treatment plants.

The Effect of Burn-out Temperature and Cooling Rate on the Microstructure and Corrosion Behavior of Dental Casting Gold Alloy (치과용 합금 주조 시의 소환온도와 주조 후 냉각방법이 미세조직과 부식거동에 미치는 영향)

  • Lee, Sang-Hyeok;Ham, Duck-Sun;Kim, Hak-Kwan;Jang, Ju-Woong;Kim, Myung-Ho
    • Journal of Technologic Dentistry
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    • v.22 no.1
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    • pp.69-78
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    • 2000
  • The microstructure and corrosion behavior of commercially dental casting gold alloys were investigated to clarify the effect of burn-out temperature and cooling rate. In the case of water quenching after casting, only the αphase, which is typical dendritic microstructure of golda alloy, was detected. However, the precipitates along the grain boundary were detected only at the slow cooling rate and they increased inversely proportional to the burn-out temperature. This might be due to the time difference which solute atom could diffuse. EPMA and SEM results also demonstrated that the precipitate should be lamellar structure consisted of Ag rich phase(${\alpha}_1$) and Cu rich phase (${\alpha}_2$). In terms of corrosion, the galvanic coupling was formed due to the difference of composition between precipitates and matrix at the slow cooling rate. In the case of water quenching, the critical current density($i_p$) which indicate the degree of corrosion was lowest at $650^{\circ}C$ and below the burnout temperature, $i_p$ increased with it because of the effect of grain boundary segregation. But above the temperature, $i_p$ increased with it. This may be due to the strain field effect by residual thermal stress.

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The Stress Corrosion Cracking Resistance of Heat Treated STS304 Stainless Steel Welded Metal (304 스테인리스강 용접금속의 열처리에 따른 응력부식균열)

  • Cho, D.H.;Kim, H.R.;Nam, T.W.
    • Journal of the Korean Society for Heat Treatment
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    • v.9 no.1
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    • pp.34-44
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    • 1996
  • Austenite stainless steel was produced by arc welding with current 650A, voltage 50V and welding speed 10cm/min. It was post-welded and then heat treated at $1,050^{\circ}C$ for 120min. And then it was immersed in water or in air. The microstructural changes, ferrite contents, mechanical properties, and stress corrosion cracking(SCC) were investigated. The SCC was studied in 42wt% boiling $MgCl_2$($140^{\circ}C$) under the constant stress using SCC elongation curve. The results showed that; 1. The as-welded spedimen seemed to increase ${\delta}$-ferrite content largely, and revealed continuous network of lathy and vermicular type. The post-welded heat treatment changed the morphologies of ferrite from continuous type to island type. 2. The as-welded, air and water quenched specimens had the ${\delta}$-ferrite content 9.7%, 3.2% and 2.1% respectively. We also showed that ${\delta}$-ferrite was Cr-rich and Ni-poor by EPMA. 3. The time of failure on the SCC was measured and it was used for corrosion elongation curve. The condition of SCC was investigated under $35kgf/mm^2$ load and the results were as follows; 4. The intergranullar cracking by stress corrosion was most distinct in weld metal while the transgranular cracking occurred in the air cooled specimen.

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A Study on the Allowable Crack Width of RC Beam with Corrosive Environment (염해환경에서의 RC보의 허용 균열폭 산정에 관한 연구)

  • Kim, Dongbaek;Kwon, Soondong;An, Kwanghee
    • Journal of the Society of Disaster Information
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    • v.11 no.2
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    • pp.253-261
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    • 2015
  • Deterioration of reinforced concrete structures in corrosive environment is tend to be accelerated due to ingress of aggressive ion such as chloride ion. Chloride-induced corrosion is affected by various factors such as cover concrete qualities, width of existing cracks, and cover depth of concrete. However, the allowable crack width of RC structure in design code does not consider the concrete material properties and conditions of construction except the cover depth. In this paper, an equation for allowable crack width is proposed to consider the cover concrete quality, crack width, and cover depth. Crack width, cover depth, and water-cement ratio of concrete are selected as influencing factors on corrosion of reinforcement for rapid chloride tests. From test results, the relationships between the factors and corrosion are derived. Finally, the equation for allowable crack width is derived in terms of concrete compressive strength and cover depth. The presented equation is verified by comparative calculations with design code variables.

Applicability of Air Cooling Heat-treatment for a Duplex Stainless Steel Casting (2상 스테인레스 주강의 공냉 열처리 적용 가능성)

  • Kim, Bong-Whan;Yang, Sik;Shin, Je-Sik;Lee, Sang-Mok;Moon, Byung-Moon
    • Journal of Korea Foundry Society
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    • v.26 no.1
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    • pp.17-26
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    • 2006
  • The substitution of cooling method from water quenching to air cooling after solution heat treatment was aimed for the development of a convenient and economical heat treatment process of duplex stainless steels without deterioration of mechanical and corrosion resistant properties for the industry. In order to achieve this goal, the mechanical properties and corrosion properties of a ASTM A890-4A duplex stainless steel were systematically investigated as functions of casting condition and cooling method after solution heat treatment. A 3-stepped sand mold and a permanent Y-block mold were used to check the effects of solidification structure and cooling rate after solution heat treatment. The microstructural characteristics such as the ferrite/austenite phase ratio and the precipitation behavior of ${\sigma}$ phase and carbides were investigated by combined analysis of OM and SEM-EDX with an aid of TTT diagram. Hardness and tension test were performed to evaluate the mechanical properties. Impact property at $-40^{\circ}C$ and corrosion resistance were also examined to check the possibility of the industrial application of this basic study. Throughout this investigation, air-cooling method was proved to effectively substitute for water-quenching process after the solution heat treatment, when the duplex stainless steel was sand mold cast with a thickness below 15 mm or permanent mold cast with a thickness below 20 mm.

Development of New Code Case "Mitigation of PWSCC and CISCC in ASME Code Section III Components by the Advanced Surface Stress Improvement Technology (일차수응력부식균열(PWSCC) 및 염화이온부식균열(CISCC) 저감용 표면개질기술 적용을 위한 코드케이스 개발)

  • Cho, Sungwoo;Pyun, Youngsik;Mohr, Nick;Tatman, Jon;Broussard, John;Collin, Jean;Yi, Wongeun;Oh, Eunjong;Jang, Donghyun;Koo, Gyeong Hoi;Hwang, Seong Sik;Choi, Sun Woong;Hong, Hyun UK
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.15 no.1
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    • pp.28-32
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    • 2019
  • In nuclear power plant operation and spent fuel canisters, it is necessary to provide a sound technical basis for the safety and security of long-term operation and storage respectively. Recently, the peening technology is being discussed and the technology will be adopted to ASME Section III, Division 1, Subsection NX (2019 Edition). The peening is prohibited in current edition, but it will be approved in 2019 Edition and adopted. However, Surface stress improvement techniques such as the peening is used to mitigate SCC susceptible in operating nuclear plants. Although the peening will be approved to ASME CODE, there are no performance criteria listed in the 2019 edition. The Korean International Working Group (KIWG) formed a new Task Group named "Advanced Surface Stress Improved Technology". The task group will develop a CODE CASE to address PWSCC(Primary Water Stress Corrosion Cracking) and CISCC(Chloride Induced Stress Corrosion Cracking) for new ASME Section III components. TG-ASSIT was started to make peening performance criteria for ASME Section III (new fabrication) applications. The objective of TG-ASSIT is to gain consensus among the relevant Code groups that requirements/mitigation have been met.

Effect of Solution Temperature on the Cavitation Degradation Properties of Epoxy Coatings for Seawater Piping

  • Jeon, J.M.;Yoo, Y.R.;Jeong, M.J.;Kim, Y.C.;Kim, Y.S.
    • Corrosion Science and Technology
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    • v.20 no.6
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    • pp.335-346
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    • 2021
  • Since epoxy resin coating shows excellent properties in formability, adhesion, and corrosion resistance, they have been extensively used in many industries. However, various types of damages in the epoxy coated tube within a relative short time have been reported due to cavitation erosion, liquid impingement, variation of temperature and pressure. Nevertheless, there has been little research on the effect of temperature on the cavitation degradation of epoxy coatings. Therefore, this work used an ultrasonic cavitation tester to focus on the effect of solution temperature on the cavitation properties of 3 kinds of epoxy coatings in 3.5% NaCl. The cavitation properties were discussed basis on the material properties and environmental aspects. As the solution temperature increased, even though with large fluctuation, the cavitation degradation rates of A and B coatings were reduced rapidly, but the rate of C coating was decreased gradually. In addition to the cushioning effect, the reason that the cavitation degradation rate reduced with solution temperature was partly related to the brittle fracture and water absorptivity of the epoxy coatings, and the water density, but was little related to the shape and composition of the compound in the coatings or the phase transition of the epoxy coating.