• Corrosion Science and Technology
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• v.19 no.2
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• pp.89-99
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• 2020

The inhibition of pitting corrosion failure of copper sprinkler tubes in wet sprinkler systems was studied. First, an apparatus and technology for removing air in the sprinkler tubes by vacuum pumping and then filling the tubes with water were developed. Using this apparatus and technology, three methods for inhibiting the pitting corrosion of the copper sprinkler tubes installed in several apartment complexes were tested. The first one was filling the sprinkler tubes with water bubbled by high-pressure nitrogen gas to reduce the dissolved oxygen concentration to lower than 2 ppm. In the second method, the dissolved oxygen concentration of water was further reduced to lower than 0.01 ppm by sodium sulfite. In the third method, the sprinkler tubes were filled with benzotriazole (BTAH) dissolved in water. The third method was the most effective, reducing the failure frequency of the sprinkler tubes due to pitting corrosion by more than 80%. X-ray photoelectron spectroscopy analyses confirmed that a Cu-BTA layer was well coated on the inside surface of the corrosion pit, protecting it from corrosion. A potentiodynamic polarization test showed that BTAH should be very effective in reducing the corrosion rate of copper in the acidic environment of the corrosion pit.

• Journal of Korean Society of Water and Wastewater
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• v.22 no.3
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• pp.379-387
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• 2008

The pH & alkalinity adjustment method by lime and carbon dioxide($CO_2$) for corrosion control in water distribution system was investigated to evaluate the corrosion characteristics of metal pipes, such as galvanized iron, copper, stainless steel, and carbon steel. When the pH in sand filtered and ozone+GAC treated water was increased with lime and $CO_2$ from 7.5 to 8.0, the concentration of residual chlorine decreased at higher pH and longer reaction time; the concentration of trihalomethane increased. The corrosion rate of coupons with corrosion control using lime and carbon dioxide was showed much smaller than those without corrosion control using pilot-scale simulated distribution system. The galvanized iron was corroded much faster than carbon steel, copper, and stainless steel. Especially, copper and stainless steel coupons were hardly corroded. The galvanized iron and carbon steel coupons with corrosion control were produced the corrosion products less than those without corrosion control by the results of environmental scanning electron microscope(ESEM) and energy dispersive x-ray spectroscopy(EDS) analyses. The galvanized iron coupon with pH and alkalinity adjustment by lime and carbon dioxide was detected about 30 percent of zinc, when the carbon steel was detected about 30 percent of calcium by calcium carbonate products formation. For the results of X-ray diffraction(XRD) analyses, the goethite(${\alpha}$-FeOOH) was identified as primary corrosion product of galvanized iron without corrosion control, while the Zinc oxide(ZnO) was found on corrosion products of galvanized iron coupon with corrosion control as the results of EDS analyses. However, the carbon steel corrosion products regardless of corrosion control were composed predominantly of maghemite(${\gamma}-Fe_2O_3$) and hematite(${\alpha}-Fe_2O_3$).

• Journal of Korean Society of Water and Wastewater
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• v.25 no.5
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• pp.707-717
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• 2011

Replacement of old water distribution pipes for protecting water quality induced by pipe corrosion requires enormous budget. Even after the replacement, however, corrosion can occur again at any times and, therefore, inhibitive measure of the corrosion will be not only economical but needed to diminish the consumers' distrust on tap water quality. In 2008, National Environmental Research Institute did a survey on 8 major drinking water source and proposed to establish the Langelier Saturation Index(LI) as a corrosion index in Drinking Water Quality Criteria. Among the water industries of Korea, K-Water is the only one that set up the level of pH over 7.0 and LI above -1.5 on yearly average basis. However, no systematic regulation including LI to inhibit the corrosive tendency has been established yet. In this paper, LI values out of 31 drinking water treatment plants were analyzed and two-stage control of LI value as a measure of corrosive tendency of water is proposed. Primarily, water treatment facilities may operate the system at a target LI value below -1.5. Following the investigation on the effect caused by adjusting the LI value on water quality and corrosiveness, it will be desirable to improve LI value below -1.0 in the long run. In addition to the LI, supplemental use of Larson's modified ratio (LMR) which incorporates hydraulic detention time will be necessary. Several methods to prove the inhibitive effect of improving the LI value on water quality have been also suggested.

• Journal of Korean Society of Water and Wastewater
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• v.26 no.1
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• pp.97-106
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• 2012

To investigate the application of corrosion inhibitor on water supply pipes, turbidity, magnitude of corrosion, composition of scale and concentration of metals from an old steel pipe were analysed under inhibitor addition. The concentration of turbidity, iron and copper from the pipes under inhibitor application was 12 ~ 14% of the case which no inhibitor was applied, which suggests the application of inhibitor was very effective for internal corrosion control. In addition, SEM, EDX, XRD and XRF test results showed that application of inhibitor was effective for the decrease of iron concentration and increase of oxygen, phosphorus and calcium concentration, which suggested the existence of protective layer. Therefore, the occurrence of red water will be significantly decreased when inhibitor was applied to the old steel pipes.

• Proceedings of the KIEE Conference
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• 2003.11c
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• pp.637-640
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• 2003

The owner of water pipeline has a burden of responsibility for the protection of corrosion and the prevention against leakage of water. So, they have been installed a CP(Cathodic Protection) System in oder to protect corrosion. And they also have been measured and analyzed the data about P/S(Pipe to Soil) potential of water pipeline. The P/S potential is basic data of evaluation for water pipeline corrosion. In this paper, results of development about remote wireless corrosion monitoring system for water pipe line are presented briefly.

• Corrosion Science and Technology
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• v.3 no.6
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• pp.245-250
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• 2004

A series of classical G109 type concrete specimens was exposed to cyclic wet and dry ponding with 15 w/o NaCl solution for approximately five years. Mix design variables included 1) three cement alkalinities (EqA of 0.97, 0.52, and 0.36) and 2) three water-cement ratios (0.50, 0.41, and 0.37). To determine the corrosion initiation time, corrosion potential and macro-cell current between top and bottom bars were monitored. Subsequent to corrosion initiation, specimens were autopsied and visually inspected. Concrete powder samples were collected from top rebar trace and chloride concentration was measured. Also, time-to-corrosion, $T_i$, for specimens of the individual mix designs was represented using Weibull analysis. Time-to-corrosion was a distributed parameter; and because of this, corrosion initiation of four identical specimens for each mix varied, often over a relatively wide range. Specimens fabricated using the lowest water cement ratio and the highest alkalinity cement exhibited the longest time-to-corrosion initiation and the highest chloride threshold levels. Time-to-corrosion did not increase monotonically with cement alkalinity, however, presumably as a consequence of relatively high $Cl^-$ binding in the lower pore water pH range. The chloride threshold level, $Cl_{th}$, increased with increasing $T_i$ and, consequently, was greatest for the highest cement alkalinity specimens.

• Corrosion Science and Technology
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• v.19 no.2
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• pp.66-74
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• 2020

In this paper, the author's team has carried out a comparative experimental study on the corrosion characteristics of Q235 steel commonly used in large-scale storage tanks under the specific bottom water environment found with Russian and Daqing crude oil. It was found that there is a certain degree of uniform or local corrosion on the tank floor depending on the kind of bottom water. The bottom water corrosion of Daqing crude oil is a uniform corrosion caused by carbon dioxide. While the Russian crude oil bottom water corrosion is clearly local corrosion caused by co-corrosion of carbon dioxide and hydrogen sulfide, here the corrosion rate is obviously higher than that caused by Daqing crude oil. There are two modes of storage tank inspection and maintenance that have been currently adopted by Chinese refining and chemical enterprises: a regular inspection mode and a API581-2016 risk-based detection mode. These modes have been effectively combined to form an intelligent tank inspection and maintenance mode, software tools to support this intelligent inspection and maintenance management have been developed.

• Corrosion Science and Technology
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• v.11 no.4
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• pp.151-156
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• 2012

The cavity formed by the ultrasonic generation in the fluid with the application of water cavitation peening collides into the metal surface. At this time, the surface modification effect such as the work hardening presents by the compressive residual stress formed due to the localized plastic deformation. In this investigation, the water cavitation peening technology in the distilled water with the lapse of time was applied to 5052-O aluminum alloy for aluminum ship of a high value. So, the optimum water cavitation peening time on the effect for surface hardening and anti-corrosion property was investigated. Consequently, the water cavitatin peening time on excellent hardness and corrosion resistance characteristic presented 3.5 min. and 5.0 min, respectively. The surface hardness in the optimum water cavitation peening time was improved approximately 45% compared to the non-WCPed condition. In addition, corrosion current density was decreased.

• Corrosion Science and Technology
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• v.2 no.2
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• pp.88-92
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• 2003

The technique for in situ simultaneous measurements of IR-RAS and QCM, which has been developed for investigation of corrosion in gaseous environments, was employed to study the effects of an extremely thin water layer on the corrosion rate. An evaporated copper film on a QCM element was exposed to air containing water vapor and $SO_2$, and time-resolved IR-RAS spectra were measured and mass gains were simultaneously followed with QCM. The tested ranges of relative humidity (RH) and concentration of $SO_2$ were 60% - 90% and 1 - 20 ppm, respectively. On the basis of 2D-IR analysis, the corrosion products were determined to be Chevreul's salt ($CuSO_3Cu_2SO_3{\cdot}2H_2O$) and $CuSO_4{\cdot}5H_2O$. By constructing curves of the relations between band intensities of IR spectra and mass gains of QCM for the corrosion products, the time variations in each product were determined from spectral experiments on copper plates. The thicknesses of physically adsorbed water layers in course of the corrosion process were also determined from water band intensities. The results showed that the thickness of the physically adsorbed water layer increased with increase in RH, and it also increased with increase in accumulation of corrosion products. The latter is probably due to the capillary effect of the corrosion products.

• Journal of Korean Society on Water Environment
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• v.24 no.6
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• pp.701-708
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• 2008

As a countermeasure for reduction of corrosion in the delivery and distribution pipes used for tap water, materials for the pipelines in-houses and the effect of water quality on corrosivity of water pipelines were investigated in the distribution system of Han river. As the corrosion index at 6 water purification facilities of Han river, average Langelier Saturation Index (LI) of raw and finished water were -1.0 and -1.4 respectively and average Larson Index (LR) were 9.5 and 9.9, respectively. And also corrosion potential showed corrosivity in finished water (-431~-462 mV) as well as raw water (-426~-447 mV). This results indicate that tap water quality of han river have corrosivity. To understand the corrosivity effect in pipe material used for premise distribution system, water quality of stagnant tap water and tap water were analyzed and the differences between them were calculated. The difference concentration of iron, copper and zinc were $12.9{\mu}g/L$, $31.0{\mu}g/L$ and $45.0{\mu}g/L$ respectively in galvanized steel pipe for use more than 15 years and showed highest concentration. As a result, the control to corrosivity in the water pipelines, corrosivity control treatment in the water purification system can be applied. In advance it is necessary to monitor corrosivity of water quality using corrosive index because corrosivity may differ from the seasonal and regional characteristics and water chemicals dosage. For the future the guideline for corrosion index have to be established.