• Title/Summary/Keyword: water corrosion

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Behavior of Stress Corrosion Cracking in Structural Steel under Acid Fog Environment (산성안개하에서 기계·구조용강의 응력부식균열 거동)

  • Lim, Yong Ho;Kim, Min-Gun
    • Journal of Industrial Technology
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    • v.17
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    • pp.291-295
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    • 1997
  • The tests of stress corrosion cracking in structural carbon steel were carried out under the conditions of acid fog and general water. As the result of measurement SCC rupture time under acid fog was observed to be much shorter than that of general water at the same stress level. Therefore, acid fog drops the SCC strength in structural carbon steel due to strong corrosion. In the SCC process by acid fog, crack initiation was caused by pit corrosion and local stress concentration, and distinctive feature of crack growth shows branching since crack grows to the corrosion direction. Moreover, corrosion products were observed by clevage corrosion on the crack surfaces.

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The Effect of Corrosion Inhibitors Influencing on the Corrosion of Reinforced Steel in Mortar Specimen Immersed in Sea Water for Seven Years (해수중 7년간 침지된 몰탈시험편의 철근부식에 미치는 부식억제제의 효과)

  • 정진아;남진각;문경만;이명훈;김기준
    • Proceedings of the Korea Concrete Institute Conference
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    • 1998.10c
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    • pp.211-216
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    • 1998
  • Recently the shortage of good aggregate has encouraged the use of sea sand in construction field, and the corrosion damage of the reinforced steel in concrete structures has been increased due to chlorides from sea sand and deicing salt. Therefore, a number of researchs are proceeding to prevent the corrosion of the reinforced steel in concrete, especially in marine environments. This study focused on the effect of corrosion inhibitors to evaluate protection characteristics for mortar specimens containing clorides. Corrosion behaviors have been investigated by half-cell potential measurement, linear polarization method, AC impedance method, and cyclic polarization test after immersing in sea water for 7 years. A possitive effect of a corrosion inhibitor has been obtained.

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Influences of Gas and Solid Particle on the Cavitation Erosion-Corrosion (케비테이션 침식-부식에 미치는 기체와 고체입자의 영향)

  • Lim, Uh-Joh;Beak, Suk-Jong;Hwang, Jae-Ho
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.29 no.2
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    • pp.124-131
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    • 1993
  • Recently. with the rapid development in large sea water systems. there occurs much interest in the study of erosion-corrosion. In this study. the mild steel(SB41) was tested by using of a erosion-corrosion test apparatus with fountain-jet and was investigated under the environments of liquid, air-liquid 2 phase flow and solid particle-liquid 2 phase flow. Main results obtained are as follows : 1. The weight loss by corrosion-erosion in air-liquid 2 phase flow are more increased than that in only liquid solution. 2. Effect of air-liquid 2 phase flow on corrosion-erosion sensitivity becomes more sensitive in natural seawater than that in distilled water. 3. The corrosion potential by corrosion-erosion in air-liquid and solid particle-liquid 2 phase flow becomes noble than that of only liquid solution.

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Effects of Different Paints on Steel Rods Anticorrosion of Reinforced Concrete in Salt Water (해수에서 철근콘크리트의 철근 방식에 대한 도료의 효과)

  • 이신호;고재군
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.25 no.2
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    • pp.67-75
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    • 1983
  • The objectives of this paper were to measure the bond strengths of reinforced concrete in which the steel rods were coated with five different kinds of anticorrosion paints, and to compare their prevention effects in salt water. The paints used in the study were epoxy resin I . II . III, Z.R. P., and silicone resin, which were applied at rates recommended by the manufacturers. The bond strengths were measured on the 7-, 14-, and 28-th days after molding. Corrosion conditions of coated steel plate under fresh water, seawater, 10 % salt water, and 20% salt water, were inspected every month during four months test peoriods, respectively. The results obtained from tests are summarized as follows: 1. Paint-coating may reduce the bond strengths of reinforced concrete. Silicone resin paint showed some 20% reduction in the strength compared to those without the paint. However, the other paints seemed not to significantly affect the strength. 2. Picture analyses showed that epoxy resin I and II significantly prevented corrosion steel plates in seawater. Epoxy resin I and silicone resin coating did not do a good job in corrosion prevention. Z.R. P. paint was found to be moderate as preventive coating paint. 3. Varying soluble salt contents had little effects on the corrosion prevention of tested paints. 4. Epoxy resin I and II were found to be appropriate as a coating material to prevent the corrosion of steel rods in seawater. Z.R.P. may also be used for the purpose.

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CORROSION BEHAVIOR OF AUSTENITIC AND FERRITIC STEELS IN SUPERCRITICAL WATER

  • Luo, Xin;Tang, Rui;Long, Chongsheng;Miao, Zhi;Peng, Qian;Li, Cong
    • Nuclear Engineering and Technology
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    • v.40 no.2
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    • pp.147-154
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    • 2008
  • The general corrosion behavior of austenitic and ferritic steels(316L, 304, N controlled 304L, and 410) in supercritical water is investigated in this paper. After exposure to deaerated supercritical water at $480^{\circ}C$/25 MPa for up to 500 h, the four steels studied were characterized using gravimetry, scanning electron microscopy/energy dispersive X-ray spectroscopy(SEM/EDS), X-ray photoelectron spectroscopy(XPS), and X-ray diffraction(XRD). The results show that the 316L steel with a higher Cr and Ni content has the best corrosion-resistance performance among the steels tested. In addition to the oxide layer mixed with $Fe_{3}O_{4}$ and $(Fe,Cr)_{3}O_{4}$ that formed on all the samples, a $Fe_{3}O_{4}$ loose outer layer was observed on the 410 steel. The corrosion mechanism of stainless steels in supercritical water is discussed based on the above results.

The Analysis of Electrical Conduction and Corrosion Phenomena in HVDC Cooling System and the Optimized Design of the Heat Sink of the Semiconductor Devices (HVDC 냉각시스템의 전기전도현상 및 부식현상 기술 분석과 스위칭 소자의 방열판 최적 설계 검토)

  • Kim, Chan-Ki;Park, Chang-Hwan;Kim, Jang-Mok
    • The Transactions of the Korean Institute of Power Electronics
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    • v.22 no.6
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    • pp.484-495
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    • 2017
  • In HVDC thyristor valves, more than 95% of heat loss occurs in snubber resistors and valve reactors. In order to dissipate the heat from the valves and to suppress the electrolytic current, water with a high heat capacity and a low conductivity of less than 0.2 uS/cm must be used as a refrigerant of the heat sink. The cooling parts must also be arranged to reduce the electrolytic current, whereas the pipe that supplies water to the thyristor heat sink must have the same electric potential as the valve. Corrosion is mainly caused by electrochemical reactions and the influence of water quality and leakage current. This paper identifies the refrigerants involved in the ionization, electrical conductivity, and corrosion in HVDC thyristor valves. A method for preventing corrosion is then introduced. The design of the heat sink with an excellent heat radiation is also analyzed in detail.

Estimation of Concrete Cover Failure Time Considering the Corrosion Rate in Reinforced Concrete Structures (철근 부식속도 예측식을 이용한 철근 피복 파괴 시간 추정)

  • Jang, Bong-Seok
    • Journal of the Korea Concrete Institute
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    • v.18 no.2 s.92
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    • pp.233-238
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    • 2006
  • In lifetime estimation, the FEM analysis method is proposed for predicting corrosion failure time of concrete structures exposed to sea-water. This study shows that the corrosion rate of rebar in artificial pore solution can be transferred to the corrosion rate of rebar in concrete using the relationship between pore volume and concrete volume by Jennings' model. And this study considered the pitting corrosion effects of reinforcement bar on corrosion failure analysis, rebar size to cover depth and nonlinear crack analysis. These analysis results have good accordance with the experimental results of Williamson's work. This methodology can be applied to lifetime prediction procedure of reinforced concrete structures and also gives more reasonable results of concrete cover failure time estimation of reinforced concrete structures exposed to sea-water.

Variation of Corrosion Properties on the Steel Surface by Environmental Changes in Shihwa Lake (시화호 환경 변화에 따른 강재 표면의 부식특성 변화)

  • Park, Jun-Mu;Lee, Seung-Hyo;Woo, Sang-Kyun;Chu, In-Yeop;Lee, Myeong-Hoon
    • Journal of Surface Science and Engineering
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    • v.51 no.5
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    • pp.316-324
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    • 2018
  • Harsh seawater environment is subdivided into marine atmosphere, splash zone, tidal zone, submerged zone and bottom of sea depending on the exposed part. Since corrosion rate depends on the conditions of the exposed parts, proper protection and maintenance for each parts are essential for long-term use of steel structures in seawater environment. For steel structures which were installed in Shiwha Lake, a special maintenance system is required to guarantee its long-term durability and safety. As the tidal power plant has recently been operated, the salinity has risen due to the rapid influx of seawater upstream into Sihwa Lake and the corrosion tendency of the structure is variable according to the water level fluctuation. In this study, corrosion properties of steel structures under water level fluctuation was evaluated by corrosion rate measurement, visual inspection and natural potential measurement and their durability and life management were discussed in view of the effect of variation in of seawater level fluctuations in Shihwa Lake.

Corrosion Properties of Reinforced Concrete with Types of Surface Cover and Covering Depth under the Combined Deterioration Environments (복합열화 환경하에서 표면피복종류 및 피복두께에 따른 철근콘크리트의 부식특성)

  • Kim, Moo-Han;Kwon, Young-Jin;Kim, Young-Ro;Kim, Jae-Hwan;Jang, Jong-Ho;Cho, Bong-Suk
    • Journal of the Korea Institute of Building Construction
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    • v.4 no.1
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    • pp.119-126
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    • 2004
  • Generally, reinforced concrete is one of the most commonly used structural materials and it prevents corrosion of steel bar by high pH of interior, But, as time elapsed, reinforced concrete structure become deteriorated by many of combined deterioration factors and environmental conditions. And, there are large number of deteriorate mechanism of the reinforced concrete structure and it acts complexly. It is recognized that steel bar corrosion is the main distress behind the present concern regarding concrete durability. In this study, to institute combined deterioration environments, established acceleration condition and cycle for combined deterioration environments has a resemblance to environments which are real structures placed. After that to confirm corrosion properties of reinforced concrete due to permeability with covering depth and types of surface cover under combined deterioration environments, measured carbonation velocity coefficients, chloride ion diffusion coefficients, water absorption coefficients, air permeability coefficients and electric potential, corrosion area ratio, weight reduction, corrosion velocity of steel bar. The results showed that an increase in age also decrease carbonation velocity coefficients, increase Chloride ion diffusion coefficients and increases water absorption coefficients. As well, an increase in age also increases corrosion of steel bar. Data on the development of corrosion velocity of steel bar with types of surface cover made with none, organic B, organic A, inorganic B, and inorganic A is shown. As well, permeability and corrosion velocity of steel bar with covering depth is superior to 10mm than 20mm. And it is confirmed permeability and corrosion properties of steel bar are closely related.

Analysis of Pipe Wall-thinning Caused by Water Chemistry Change in Secondary System of Nuclear Power Plant (원전 2차계통의 수화학 변화가 배관감육에 미치는 영향 분석)

  • Yun, Hun;Hwang, Kyeongmo;Moon, Seung-Jae
    • Corrosion Science and Technology
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    • v.14 no.6
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    • pp.325-330
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    • 2015
  • Pipe wall-thinning by flow-accelerated corrosion (FAC) is a significant and costly damage of secondary system piping in nuclear power plants (NPPs). All NPPs have their management programs to ensure pipe integrity from wall-thinning. This study analyzed the pipe wall-thinning caused by changing the amine, which is used for adjusting the water chemistry in the secondary system of NPPs. The pH change was analyzed according to the addition of amine. Then, the wear rate calculated in two different amines was compared at the steam cycle in NPPs. As a result, increasing the pH at operating temperature (Hot pH) can reduce the rate of FAC damage significantly. Wall-thinning is affected by amine characteristics depending on temperature and quality of water.