• Title/Summary/Keyword: water corrosion

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Functional graphene sheets-TiO2 nanocomposites and their photocatalytic performance for wastewater treatment

  • R. Aitbelale;A. Timesli;A. Sahibed-dine
    • Advances in nano research
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    • v.15 no.4
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    • pp.295-304
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    • 2023
  • In this paper, a powerful photocatalyst based on carbon nanocomposite is developed in order to obtain a new material applicable in water treatment and especially for the discoloration of effluents used in the textile industry. For that, TiO2-graphene nanocomposites have been successfully synthesized by a mixture of Functionalized Graphene Sheet (FGS) and tetrachlorotitanium complexes to form FGS-TiO2 nanocomposite. In the presence of an anionic surfactant, we used a new chemical process to functionalize graphene sheets in order to make them an excellent medium for blocking and preventing the aggregation of TiO2 nanoparticles. The components of these nanocomposites are characterized by means of X-ray diffraction (XRD), Fourier Transform Infrared Spectroscopy (FT-IR), Scanning Electron Microscopy (SEM) and Transmission Electron Microscopy (TEM), which confirms the successful formation of the FGS-TiO2 nanocomposite. It was found that the TiO2 nanoparticles were dispersed uniformly on the graphene plane which possesses better charge separation capability than pure TiO2. The FGS-TiO2 nanocomposites exhibited higher photocatalytic activity compared to pure TiO2 for the removal of three dyes: such as Methylene Blue (MB), Bromophenol Blue (BB) and Alizarin Red-S (AR) in water. The removal process was fast and more efficient with FGS-TiO2 nanocomposite in daylight (in the absence of UV irradiation) compared to pure TiO2 nanoparticles without and under UV in all pH range.

Susceptibility of Stress Corrosion Crack Initiation of Type 304 SS in Simulated Primary Water Environment of PWR (원전 1차 계통수 모사환경에서 Type 304 스테인리스강의 응력부식균열개시 민감도)

  • Sung-Hwan Cho;Sung-Woo Kim;Jong-Yeon Lee
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.20 no.1
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    • pp.25-31
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    • 2024
  • The core shroud of rector vessel internals (RVI) of OPR1000 and ARP1400 is made of Type 304 stainless steel (SS) by bending and welding process that may induce high deformation and residual stress in manufacturing. This work aims to evaluate the susceptibility of stress corrosion crack (SCC) initiation of bent parts of RVI in high temperature primary water environment. For SCC initiation test, tensile specimens were fabricated from the 90 degree bent plate of Type 304 SS (DT specimen), that is an archived part of a Korean APR1400. After the SCC initiation test, the specimen surface was thoroughly examined by optical and scanning electron microscopy, and compared to the specimen fabricated from the as-received plate of Type 304 SS (AR specimen). The surface observation revealed that SCC initiated on the AR specimen surface in typical intergranular (IG) mode, while SCC on the DT specimen occurred in transgrannular mode as well as IG mode. It was also found that the size and number of SCC on the DT specimen were larger than that on the AR specimen. This was attributable to a strain-hardening during the bending process. To compare the susceptibility of SCC initiation, total crack density (TCD) was calculated from the total crack length divided by the measured area of AR and DT specimens. TCD of DT specimen was 4.6 times higher than AR specimen in average, indicating that higher possibility of degradation of bent parts of RVI for a long-term operation.

Development of Innovative Light Water Reactor Nuclear Fuel Using 3D Printing Technology (3 차원 프린팅 기술을 이용한 신개념 경수로 핵연료 기술 개발에 관한 연구)

  • Kim, Hyo Chan;Kim, Hyun Gil;Yang, Yong Sik
    • Journal of the Korean Society for Precision Engineering
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    • v.33 no.4
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    • pp.279-286
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    • 2016
  • To enhance the safety of nuclear reactors after the Fukushima accident, researchers are developing various types of accident tolerant fuel (ATF) to increase the coping time and reduce the generation of hydrogen by oxidation. Coated cladding, an ATF concept, can be a promising technology in view of its commercialization. We applied 3D printing technology to the fabrication of coated cladding as well as of coated pellets. Direct metal tooling (DMT) in 3D printing technologies can create a coated layer on the tubular cladding surface, which maintains stability during corrosion, creep, and wear in the reactor. A 3D laser coating apparatus was built, and parameter studies were carried out. To coat pellets with erbium using this apparatus, we undertook preliminary experiments involving metal pellets. The adhesion test showed that the coated layer can be maintained at near fracture strength.

Long Term Operation of Microfiltration as a Pretreatment for Seawater Reverse Osmosis Processes (정밀여과를 이용한 역삼투법 해수담수화 전처리 공정의 장기운전 특성)

  • Kim, Su-Han;Kim, Chung-H.;Kang, Suk-H.;Lim, Jae-L.
    • Journal of Korean Society of Water and Wastewater
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    • v.24 no.6
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    • pp.735-741
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    • 2010
  • A pilot test was carried out to investigate the long term operation characteristics of Microfiltration (MF) system as a pretreatment for seawater reverse osmosis (SWRO) processes for two years. A commercialized MF module with pressurized operation type was used to filter seawater to remove particles which can foul reverse osmosis (RO) membrane. Silt Density Index (SDI) values of filtered seawater by the MF system were ranged from 0.14 to 1.79, which meet the SDI standard for RO feed water as depicted in previous literatures. Although the tested seawater is quite clean (i.e., dissolved organic cabon (DOC) concentration and turbidity were about 1 mg/l and less than 1 NTU, respectively) enough not to foul the MF membrane, steep increase in trans-membrane pressure (TMP) with a constant flux were observed over a whole operation period. A set of operation and water analysis data implies that the steep increase in TMP was resulted from iron and maganese fouling by the combination of metal corrosion by seawater and oxidation state by aeration and residual chlorine.

Cycle simulation of a triple effect LiBr/water absorption chiller (삼중효용 LiBr/물 흡수식 냉방기의 사이클 시뮬레이션)

  • 조광운;정시영;정은수
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.10 no.1
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    • pp.79-87
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    • 1998
  • Basic design of a 50USRT(175㎾) triple effect absorption chiller driven by hot gas has been carried out for both parallel and series flow cycles. Parallel flow cycle showed higher COP, however, the temperature in the generator was also higher than that in series flow cycle. Dynamic operation behavior of a parallel flow system at off-design conditions, such as the change in heat transfer medium temperature or the construction change of the system components, has been investigated in detail. It was found that the cooling capacity was seriously decreased by reducing hot gas flow rate and UA-value in the high temperature generator. However, the system COP was improved, because thermal load in the system components was reduced. The COP and the cooling capacity was found to be improved as cooling water temperature decreased or chilled water temperature increased. The optimum ratio of solution distribution could be suggested by considering the COP, the cooling capacity and the highest temperature in the system, which is critical for corrosion.

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Paint Removal of Airplane & Water Jet Application

  • Xue, Sheng-Xiong;Chen, Zheng-Wen;Ren, Qi-Le;Su, Ji-Xin;Han, Cai-Hong;Pang, lei
    • International Journal of Fluid Machinery and Systems
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    • v.7 no.3
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    • pp.125-129
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    • 2014
  • The paint removal and recoating are the very important process in airplane maintenance. The traditional technology is to use the chemical way corroding the paint with paint remover. For changing the defects, corrosion & pollution & manual working, of the traditional technology, the physical process which removes the paint of airplane with 250MPa/250kW ultra-high pressure rotary water jetting though the surface cleaner installed on the six axes robot is studied. The paint layer of airplane is very thin and close. The contradiction of water jetting paint removal is to remove the paint layer wholly and not damage the surface of airplane. In order to solve the contradiction, the best working condition must be reached through tests. The paint removal efficiency with ultra-high pressure and move speed of not damaged to the surface. The move speed of this test is about 2m/min, and the paint removal efficiency is about $30{\sim}40m^2/h$, and the paint removal active area is 85-90%. No-repeat and no-omit are the base requests of the robot program. The physical paint removal technology will be applied in airplane maintenance, and will face the safety detection of application permission.

A Study for the Effect of Liquid Droplet Impingement Erosion on the Loss of Pipe Flow Materials (배관 재질 손상에 미치는 액적충돌침식의 영향에 대한 연구)

  • Kim, Kyung Hoon;Cho, Yun Su;Kim, Hyung Joon
    • Journal of ILASS-Korea
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    • v.18 no.1
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    • pp.9-15
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    • 2013
  • Wall thinning of pipeline in power plants occurs mainly by flow acceleration corrosion (FAC), cavitation erosion (C/E), liquid droplet impingement erosion (LDIE). Wall thinning by FAC and C/E has been well investigated; however, LDIE in plant industries has rarely been studied due to the experimental difficulty of setting up a long injection of highly-pressurized air. In this study, we designed a long-term experimental system for LDIE and investigate the behavior of LDIE for three kinds of materials (A106B, SS400, A6061). The main control parameter was the air-water ratio (${\alpha}$), which was defined as the volumetric ratio of water to air (0.79, 1.00, 1.72). In order to clearly understand LDIE, the spraying velocity (${\nu}$) of liquid droplets was controled larger then 160 m/s and the experiments were performed for 15 days. Therefore, this research focuses relation between erosion rate and air-water ratio on the various pipe-flow materials. NPP(nuclear power plant)'s LDIE prediction theory and management technique were drawn from the obtained data.

Fatigue crack growth characteristics of nitrogen-alloyed type 347 stainless steel under operating conditions of a pressurized water reactor

  • Min, Ki-Deuk;Hong, Seokmin;Kim, Dae-Whan;Lee, Bong-Sang;Kim, Seon-Jin
    • Nuclear Engineering and Technology
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    • v.49 no.4
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    • pp.752-759
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    • 2017
  • The fatigue crack growth behavior of Type 347 (S347) and Type 347N (S347N) stainless steel was evaluated under the operating conditions of a pressurized water reactor (PWR). These two materials showed different fatigue crack growth rates (FCGRs) according to the changes in dissolved oxygen content and frequency. Under the simulated PWR conditions for normal operation, the FCGR of S347N was lower than that of S347 and insensitive to the changes in PWR water conditions. The higher yield strength and better corrosion resistance of the nitrogen-alloyed Type 347 stainless steel might be a main cause of slower FCGR and more stable properties against changes in environmental conditions.

Optimum design and performance of marine sea water pump with impeller using CFRP (CFRP 임펠러를 사용한 선박용 해수펌프의 최적설계와 성능특성)

  • Jeong, Seon Yong;Rhi, Seok Ho;Seo, Hyoung Seock;Lee, Kye Bock
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.11
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    • pp.7878-7884
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    • 2015
  • Marine sea water pump with impeller using carbon fiber block was developed to prevent the impeller corrosion by the salinity. A numerical analysis was carried out in order to optimize the impeller and volute design for marine sea water pump and to investigate the sensitivity of the related parameters(impeller thickness, surface roughness) using CFD commercial code. The impeller thickness is limited because of the weight. Since the impeller using the carbon fiber lights, the thickness which has a maximum efficiency can be used. The results show that the surface roughness leads to an 7% reduction in pump efficiency.

Durability studies on concrete with partial replacement of cement and fine aggregates by fly ash and tailing material

  • Sunil, B.M.;Manjunatha, L.S.;Yaragalb, Subhash C.
    • Advances in concrete construction
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    • v.5 no.6
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    • pp.671-683
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    • 2017
  • Commonly used concrete in general, consists of cement, fine aggregate, coarse aggregate and water. Natural river sand is the most commonly used material as fine aggregate in concrete. One of the important requirements of concrete is that it should be durable under certain conditions of exposure. The durability of concrete is defined as its ability to resist weathering action, chemical attack or any other process of deterioration. Durable concrete will retain its original form, quality and serviceability when exposed to its environment. Deterioration can occur in various forms such as alkali aggregate expansion, freeze-thaw expansion, salt scaling by de-icing salts, shrinkage, attack on the reinforcement due to carbonation, sulphate attack on exposure to ground water, sea water attack and corrosion caused by salts. Addition of admixtures may control these effects. In this paper, an attempt has been made to replace part of fine aggregate by tailing material and part of cement by fly ash to improve the durability of concrete. The various durability tests performed were chemical attack tests such as sulphate attack, chloride attack and acid attack test and water absorption test. The concrete blend with 35% Tailing Material (TM) in place of river sand and 20% Fly Ash (FA) in place of OPC, has exhibited higher durability characteristics.