• Title/Summary/Keyword: water corrosion

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The Development of Buried Type Reference Electrode Using Porous Ceramic(${\alpha}-Al_{2}O_{3}$) (다공성 세라믹(${\alpha}-Al_{2}O_{3}$)를 이용한 지중 매설형 기준전극)

  • Bae, Jeong-Hyo;Ha, Yoon-Cheol;Ha, Tae-Hyun;Lee, Hyun-Goo;Kim, Dae-Kyeong
    • Proceedings of the KIEE Conference
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    • 2005.11a
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    • pp.145-147
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    • 2005
  • In present, most of metallic structures(gas pipeline, oil pipeline, water pipeline, etc) are running parallel with subway and power line in seoul. Moreover subway system and power line make a stray current due to electrical corrosion on metallic structures. The owner of metallic structures has a burden of responsibility for the protection of corrosion and the prevention against big accident such as gas explosion or soil pollution and so on. So, they have to measure and analyze the data about P/S(Pipe to Soil) potential due to stray current of subway system. So, we have developed the Real-time Wireless Remote Monitoring System for Stray Current of Subway System. In this system, the permanent buried type reference electrode is necessary. In this paper, results of development of buried type reference electrode using porous ceramic$({\alpha}-Al_{2}O_{3})$ are presented.

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Effect of Temperature on Dissolution and Adsorption of Iron Oxide (온도 변화에 따른 철산화물의 용해 및 흡착 특성)

  • 안현경;이인형
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.3 no.3
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    • pp.198-202
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    • 2002
  • Ethanolamine (ETA), instead of ammonia, increases pH in the secondary system water and inhibits the corrosion of iron, which improves the integrity of the steam generator tubes. The different physicochemical properties of ETA from ammonia provide the different effect on the dissolution and adsorption of corrosion products entering the steam generator and thus on the hideout returns of ionic impurities in the steam generator sludge pile. The objective of this study was to investigate those properties with increasing temperature. ETA is more adsorbed onto the iron oxides, which increases the solubility of them and also lowers the hideout returns due to the reduced impurities adsorbed.

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The Influences of Water Vapor/Hydrogen Ratio, Gas-Flow Rate and Antimony on the Surface Oxidation of Trip Steels

  • Kwon, Youjong;Zhu, Jingxi;Sohn, Il-Ryong;Sridhar, Seetharaman
    • Corrosion Science and Technology
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    • v.10 no.6
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    • pp.189-193
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    • 2011
  • In the current paper, we are reporting the results from an investigation of the surface and sub-surface oxidation of a TRIP steel containing 2 wt.% Mn and 0.5 wt.% Al with and without 0.03 wt.% Sb. The oxidizing conditions in the gas were successively varied in terms of the linear gas flow-rate and dew-point, from conditions were gas-phase mass transport limited conditions prevailed, to those were solid state processes became the rate determining conditions. It was found, that at sufficient low oxidizing conditions (defined as flow-rate/dew-point), the metal surfaces were clear of any external oxides, and as the oxidizing conditions were increased, Mn- and Si- oxide nodules formed along with magnetite. As the oxidizing conditions were increased further, a dense magnetite layer was present. The limits of the various regions were experimentally quantified and a proposed hypothesis for their occurrences is presented. No obvious effect of Sb was noted in this micro-structural research of the oxides that results from the various conditions investigated in this study.

Effects of Outside Repair Welding on the Crack Growth in the Surge Nozzle Weld on the Hot Leg Side in a Nuclear Power Plant (외면 보수 용접이 원전 고온관 밀림노즐에서의 결함성장에 미치는 영향)

  • Na, Kyung-Hwan;Yun, Eun-Sub;Park, Young-Sheop
    • Journal of Welding and Joining
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    • v.29 no.2
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    • pp.34-39
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    • 2011
  • Nickel-based austenitic alloys such as Alloy 82 and 182 had been employed as the weld metals in nuclear power plants (NPPs) due to their high corrosion resistance as well as good mechanical properties. However, since the 2000s, the occurrence of primary water stress corrosion cracking has been reported in conjunction with these alloys in domestic and oversea NPPs. In the present work, we assumed an imaginary crack at the inner surface of a surge nozzle weld that had previously experienced the outside repair welding, and constructed its finite element model. Finite element analysis was performed with respect to the heat transfer, and then to the residual stress for obtaining the total applied stress distributions. These stress distributions were finally converted to the stress intensity factors for estimating crack growth rate. From the comparison of crack growth rate curves for the cases of no repair welding and outside repair welding, it was found that the outside repair welding did not exhibit negative effect on the crack growth for the surge nozzle under consideration in this work; in both cases, the cracks stopped growing before they became the through-wall cracks.

A Study on the Crystalline Boron Analysis in CRUD in Spent Fuel Cladding Using EPMA X-ray Images

  • Jung, Yang Hong;Baik, Seung-Je;Jin, Young-Gwan
    • Corrosion Science and Technology
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    • v.19 no.1
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    • pp.1-7
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    • 2020
  • Chalk River Unidentified Deposits (CRUDs) were collected from the Korean pressurized water reactor (PWR) plant (A, B, and C) where the axial offset anomaly (AOA) occurred. AOA, also known as a CRUD-induced power shift, is one of the key issues in maintaining stable PWR plant operations. CRUDs were sampled from spent nuclear fuel rods and analyzed using an electron probe micro-analyzer (EPMA). This paper describes the characteristics of boron-deposits from the CRUDs sampled from twice-burnt assemblies from the Korean PWR. The primary coolant of a PWR contains boron and lithium. It is known that boron deposition occurs in a thick CRUD layer under substantial sub-cooled nucleate boiling (SNB). The results of this study are summarized as follows. Boron was not found at the locations where the existence was confirmed in simulated CRUDs, in other words, the cladding and CRUD boundaries. Nevertheless, we clearly observed the presence of boron and confirmed that boron existed as a lump in crystalline form. In addition, the study confirmed that CRUD existed in a crystal form with a unique size of about 10 ㎛.

Determination of the repair grout volume to fill voids in external post-tensioned tendons

  • Im, Seok Been;Hurlebaus, Stefan
    • Structural Engineering and Mechanics
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    • v.42 no.1
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    • pp.25-38
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    • 2012
  • Recently, investigated failures of external post-tensioned (PT) tendons have called attention to the corrosion of strands in PT bridges, and the prevention of ongoing corrosion is required to secure their structural integrity. Since voids inside ducts can be a source for the ingress of water or deleterious chemicals, the vacuum grouting (VG) method and a volumeter for estimating amount of repair grouts were employed to fill voided ducts. However, the VG method is expensive and time-consuming for infield application because it requires an air-tight condition of entire ducts. Thus, latest research assessed three different repair grouting methods, and the pressure vacuum grouting (PVG) method was recommended in the field because it showed good filling capability in voided ducts and did not require an air-tight condition. Thus, a new method is required to estimate the volume of repair grouts because the PVG method is not applied in air-tight ducts. This research assesses the relationship between voided areas on ducts identified with soundings and required grout volume for repair using experimental results. The results show that the proposed equations and assumptions for estimating repair grout volume provide a sufficient amount of repair grouts for filling voided ducts.

A Study on the Fluid Mixing Analysis for Proving Shell Wall Thinning of a Feedwater Heater (급수가열기 동체 감육 현상 규명을 위한 유동해석 연구)

  • Kim, Kyung-Hoon;Hwang, Kyeong-Mo;Kim, Sang-Nyung
    • Journal of ILASS-Korea
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    • v.9 no.4
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    • pp.24-30
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    • 2004
  • Feedwater flowing tube side of number 5 high pressure feedwatrr heaters was heated by extracting steam from high pressure turbine and draining water from moisture separators and number 6 high pressure feedwater heaters and supplied into steam generators. Because the extracting steam from the high pressure turbine is two phase fluid of high temperature, high pressure, and high speed and flows to inverse direction after impinging to impingement baffle. the shell wall of the number 5 high pressure feedwater heater may be affected by flow accelerated corrosion. On May 14, 1999, Point Beach Nuclear Plant (PBNP) with operating at full power experienced a steam leak from rupture of shell side of number 4B feedwater heater. Also, d domestic nuclear power plant experienced a severe wall thinning of shell side of number 5A and 5B feedwater heaters. This paper describes the fluid mixing analysis study using PHOENICS code in order to get at the root of the shell wall thinning of the feedwater heaters. The sections included in the fluid mixing analysis model are around the number 5h feedwater heater shell including the extracting pipeline. To identify the relation between the local velocities and wall thinning. the local velocities according to the analysis results were compared with the distribution of the shell wall thickness by ultrasonic test.

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Prediction of RC structure service life from field long term chloride diffusion

  • Safehian, Majid;Ramezanianpour, Ali Akbar
    • Computers and Concrete
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    • v.15 no.4
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    • pp.589-606
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    • 2015
  • It is well-documented that the major deterioration of coastal RC structures is chloride-induced corrosion. Therefore, regional investigations are necessary for durability based design and evaluation of the proposed service life prdiction models. In this paper, four reinforced concrete jetties exposed to severe marine environment were monitored to assess the long term chloride penetration at 6 months to 96 months. Also, some accelerated durability tests were performed on standard samples in laboratory. As a result, two time-dependent equations are proposed for basic parameters of chloride diffusion into concrete and then the corrosion initiation time is estimated by a developed probabilistic service life model Also, two famous service life prediction models are compared using chloride profiles obtained from structures after about 40 years in the tidal exposure conditions. The results confirm that the influence of concrete quality on diffusion coefficients is related to the concrete pore structure and the time dependence is due to chemical reactions of sea water ions with hydration products which lead a reduction in pore structure. Also, proper attention to the durability properties of concrete may extend the service life of marine structures greater than fifty years, even in harsh environments.

Simulation Based Investigation of Focusing Phased Array Ultrasound in Dissimilar Metal Welds

  • Kim, Hun-Hee;Kim, Hak-Joon;Song, Sung-Jin;Kim, Kyung-Cho;Kim, Yong-Buem
    • Nuclear Engineering and Technology
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    • v.48 no.1
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    • pp.228-235
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    • 2016
  • Flaws at dissimilar metal welds (DMWs), such as reactor coolant systems components, Control Rod Drive Mechanism (CRDM), Bottom Mounted Instrumentation (BMI) etc., in nuclear power plants have been found. Notably, primary water stress corrosion cracking (PWSCC) in the DMWs could cause significant reliability problems at nuclear power plants. Therefore, phased array ultrasound is widely used for inspecting surface break cracks and stress corrosion cracks in DMWs. However, inspection of DMWs using phased array ultrasound has a relatively low probability of detection of cracks, because the crystalline structure of welds causes distortion and splitting of the ultrasonic beams which propagates anisotropic medium. Therefore, advanced evaluation techniques of phased array ultrasound are needed for improvement in the probability of detection of flaws in DMWs. Thus, in this study, an investigation of focusing and steering phased array ultrasound in DMWs was carried out using a time reversal technique, and an adaptive focusing technique based on finite element method (FEM) simulation. Also, evaluation of focusing performance of three different focusing techniques was performed by comparing amplitude of phased array ultrasonic signals scattered from the targeted flaw with three different time delays.

Shell Wall Thinning and Mitigation Plan and Design Modification of a Feedwater Heater Impingement Baffle (급수가열기 동체 감육 현상과 완화 방안 및 충격판 설계개선)

  • Kim, Kyung-Hoon;Hwang, Kyeong-Mo;Park, Sang-Hoon
    • Journal of the Korean Society for Precision Engineering
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    • v.27 no.6
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    • pp.55-63
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    • 2010
  • Feedwater heaters of many nuclear power plants have recently experienced severe wall thinning damage, which will increase as operating time progresses. Several nuclear power plants in Korea have experienced wall thinning damage in the area around the impingement baffle inside feedwater heater installed downstream of the turbine extraction stream line. At that point, the extract steam from the turbine is two phase fluid at high temperature, high pressure, and high speed. Since it flows to reverse direction after impinging the impingement baffle, the shell wall of feedwater heaters may be affected by flow-accelerated corrosion. In this paper, to compare degree of shell wall thinning mitigation rate to squared type with mitigation rate of other type baffle plate, three different types of impingement baffle plate-squared, curved and mitigating type-applied inside the shell. With these comparison data, this paper describes operation of experiments and numerical analysis which is composed similar condition with real feed water heater. And flow visualization is operated for verification of experiments and numerical analysis. In conclusion, this study shows that mitigating type baffle plate is more effective than other baffle plate about prevention of pressure concentration and pressure value decrease.