• Title/Summary/Keyword: water absorption property

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Characterization of ZnO/TiO2 Nanocomposites Prepared via the Sol-Gel Method

  • Hellen, Nalumaga;Park, Hyun;Kim, Kyung-Nam
    • Journal of the Korean Ceramic Society
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    • v.55 no.2
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    • pp.140-144
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    • 2018
  • $ZnO/TiO_2$ nanocomposites were synthesized via a modified sol-gel technique by incorporating 30 and 70 wt% $TiO_2$ nanopowder into a ZnO sol-gel matrix. Zinc acetate dihydrate was used as the ZnO precursor and de-ionized water as the solvent, while titanium oxysulfate was employed for the synthesis of $TiO_2$ nanopowder. The synthesized $ZnO/TiO_2$ nanocomposites were characterized by x-ray diffraction, UV-vis spectroscopy, scanning electron microscopy, and transmission electron microscopy. The $ZnO/TiO_2$ nanocomposites showed both the ZnO (wurtzite) and $TiO_2$ (anatase) phases. The average ZnO crystallite size of the $ZnO/TiO_2$ nanocomposites was found to be about 26.3 nm. The TEM results confirmed that spherical $TiO_2$ particles were embedded in the ZnO matrix. $TiO_2$ particles attached onto the rod-like ZnO particles were also observed. The $ZnO/TiO_2$ nanocomposites exhibited optical absorption properties superior to those of pure ZnO and $TiO_2$.

Watertightness and Crack Reduction Property of Concrete added Fluosilicate Salt Based Inorganic Compound for Watertight Concrete (수밀 콘크리트용 규불화염계 무기 조성물을 첨가한 콘크리트 수밀성 및 균열저감 특성)

  • Kim Da-Su;Khil Bae-Su;Choi Se-Jin;Park Min-Yong;Lee Seong-Yeon;Yeo Byung-Chul
    • Proceedings of the Korean Institute of Building Construction Conference
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    • v.y2004m10
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    • pp.33-38
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    • 2004
  • This study was performed to know watertightness and reduction effect and crack occurred by hydration heat, restraint of multiplication of hydration heat, through mechanical test, strength test and crack control test using fluosilicate salt based inorganic compound made from by-product during phosphoric acid manufacturing process. Mix proportions for experiment were modulated at 0.45 of water to cement ratio and $0.5-2.0\%$ of adding ratio of fluosilicate salt based inorganic compound. Evaluation for watertightness of concrete was carried out permeability, absorption test and porosity analysis. Effect of crack reduction was evaluated by length, drying shrinkage as well as stress change of hardened concrete at unrestraint/restraint state and also elucidated crack pattern on the concrete surface. It is ascertained that characteristics of crack resistance and watertightness for concrete was improved by an adequate addition of fluosilicate salt based inorganic compound.

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Comparison of Physicochemical Properties of Korean and Australian Wheat Flours Used to Make Korean Salted Noodles

  • Kim, In-Sook;Binns, Colin;Yun, Hon;Quail, Ken;Lee, Chi-Ho
    • Food Science and Biotechnology
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    • v.16 no.2
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    • pp.275-280
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    • 2007
  • The effect of using Korean wheat flour versus Australian wheat flour on noodle quality as a result of differing physical and chemical properties of the flours was investigated. The results provided appropriate technical information for selection of wheat varieties to produce high quality Korean salted noodles. Noodle quality was quantified based on measurement of the appearance and texture of noodles. When consumer preference tests were conducted, a firmer and more elastic texture was preferred for Korean white salted noodles, however, when appearance was included in the consumer tests, noodles made with Australian wheat were favored over Korean wheats. Korean flour was found to produce firmer and more elastic noodles, whereas Australian flour produced brighter, creamier colored noodles. In flour quality tests, Korean flours were found to have a higher setback viscosity and lower swelling power than Australian flour. Additionally, Korean flours had higher water absorption values. Protein content of flour was an important parameter affecting the firmness of Korean noodles, whereas setback viscosity and swelling power were the major determinants of elasticity. Overall, the important parameters for determination of the quality of Korean salted noodles were high setback viscosity, low swelling power, and high protein content.

Dyeing Properties of Nylon 66 Nano Fiber with High Molecular Mass Acid Dyes

  • Lee Kwon Sun;Lee Beom Soo;Park Young Hwan;Park Yoon Chul;Kim Yong Min;Jeong Sung Hoon;Kim Sung Dong
    • Fibers and Polymers
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    • v.6 no.1
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    • pp.35-41
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    • 2005
  • Research and development of nano fiber products is very active over the world. Physical characteristics and dyeing properties of nylon 66 nano fiber were investigated in this study. X-ray diffraction, DSC, analysis of amino end group, and water absorption were performed to get information concerning physical properties of nano fiber. Nylon 66 nano fiber was dyed with high molecular mass acid dyes. Effects of dyeing temperature, pH of dyeing solution, and concentration of acid dyes on dyeing properties such as rate of dyeing and the extent of exhaustion, were examined and compared to those of regu­lar fiber. It was found that nano fiber adsorbed acid dyes at lower temperature, got rapidly dyed, and its extents of exhaustion at specific dyeing temperature were higher than regular fiber. It was also observed that nano fiber could adsorb a large amount of acid dye without a significant loss in the extent of exhaustion. Washing fastness of the dyed nano fiber was lower by $1/2\~1$ grade, light fastness by 1 grade than the dyed regular fiber.

Improvement of Physical Property of Autoclaved Light-Weight Concrete Using Admixtures and Chemical Reactants (혼화재 및 화학반응제를 혼입한 경량기포콘크리트의 물성 개선)

  • Song, Hun
    • Journal of The Korean Digital Architecture Interior Association
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    • v.12 no.4
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    • pp.87-95
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    • 2012
  • Autoclaved lightweight concrete (ALC), also known as autoclaved aerated concrete (AAC), is a lightweight, precast building material that simultaneously provides structure, insulation. ALC is a unique building material. Because of its cellular nature, it is lightweight, self-insulating, as well as sound and fireproof. ALC products include blocks, wall panels, floor and roof panels, and lintels. Recently, the use of ALC has became increasingly popular. However, ALC have high water absorption, low compressive strength and popout the origin of the low surface strength in its properties. Thus, this study is to improve the fundamental strength by controls of increasing of admixtures and chemical reactants. Admixtures make use of meta kaolin and silica fume, chemical reactants make use of sodium silicate and sodium hydroxide. From the test result, the ALC using admixtures and chemical reactants have a good fundamental properties compared with plain ALC. These good fundamental properties is caused by the admixtures and chemical reactants of ALC by the reason of the micro filling effect and chemical binding of C-S-H gel, tobermolite and quartz.

Fluorescence Quenching of Norfloxacin by Divalent Transition Metal Cations

  • Park, Hyoung-Ryun;Seo, Jung-Ja;Shin, Sung-Chul;Lee, Hyeong-Su;Bark, Ki-Min
    • Bulletin of the Korean Chemical Society
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    • v.28 no.9
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    • pp.1573-1578
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    • 2007
  • Fluorescence quenching of norfloxacin (NOR) by Cu2+, Ni2+, Co2+ and Mn2+ was studied in water. The change in the fluorescence intensity and lifetime was measured as a function of quencher concentration at various temperatures. According to the Stern-Volmer plots, the NOR was quenched both by collisions and complex formation with the same quencher. However, the static quenching had a more important effect on the emission. Large static and dynamic quenching constants support significant ion-dipole and orbital-orbital interactions between NOR and cations. The both quenching constants by Cu2+ were the largest among quenchers. Also, quenching mechanism of Cu2+ was somewhat different. The change in the absorption spectra due to the quencher provided information on static quenching. The fluorescence of NOR was relatively insensitive to both the dynamic and static quenching compared with other quinolone antibiotics. This property can be explained by the twisted intramolecular charge transfer.

Quality Improvement of Dumpling Shell Based on Rice Flour by Addition of Potato Starch and HPMC (감자전분과 HPMC 첨가수준에 따른 쌀가루 만두피의 품질특성)

  • Kang, Yi-Rang;Han, Jung-Ah
    • Korean journal of food and cookery science
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    • v.31 no.6
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    • pp.696-702
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    • 2015
  • Rice dumpling shells were prepared with different levels of hydrocolloids, such as hydroxypropyl methyl cellulose (HPMC), and potato starch. After steaming, the physical, sensory, and cooking properties of the shells were measured. Increasing the amount of potato starch decreased the pasting temperature and increased the peak viscosity. With the addition of hydrocolloids, water absorption and cooking loss for the rice dumpling shells decreased significantly. For the textural properties, the rice dumpling shells with hydrocolloids showed lower hardness and higher springiness than the control, and especially, 10% potato starch and 3% HPMC addition (P10H3) improved the texture of the rice dumpling shells the most. The sensory results seemed to be affected more by the addition of potato starch than HPMC, and over 15% addition of potato starch significantly decreased the quality of the rice dumpling shells. By addition of adequate amount of hydrocolloids (3% HPMC and 10% potato starch), the sensory quality of rice dumpling shells can be effectively improved.

Mechanical Properties of Steam Cured High-Strength Steel Fiber-Reinforced Concrete with High-Volume Blast Furnace Slag

  • Yang, Jun-Mo;Yoo, Doo-Yeol;Kim, You-Chan;Yoon, Young-Soo
    • International Journal of Concrete Structures and Materials
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    • v.11 no.2
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    • pp.391-401
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    • 2017
  • In this study, the effects of water-to-binder (W/B) ratio and replacement ratio of blast furnace slag (BFS) on the compressive strength of concrete were first investigated to determine an optimized mixture. Then, using the optimized high-strength concrete (HSC) mixture, hooked steel fibers with various aspect ratios and volume fractions were used as additives and the resulting mechanical properties under compression and flexure were evaluated. Test results indicated that replacement ratios of BFS from 50 to 60% were optimal in maximizing the compressive strength of steam-cured HSCs with various W/B ratios. The use of hooked steel fibers with the aspect ratio of 80 led to better mechanical performance under both compression and flexure than those with the aspect ratio of 65. By increasing the fiber aspect ratio from 65 to 80, the hooked steel fiber volume content could be reduced by 0.25% without any significant deterioration of energy absorption capacity. Lastly, complete material models of steel-fiber-reinforced HSCs were proposed for structural design from Lee's model and the RILEM TC 162-TDF recommendations.

Bone Body Production and Red Color Body Development Using the Bone Body (본소지 제조와 그것을 이용한 붉은 색소지 개발)

  • Choi, Soo-Nyong;Lee, Yong-Seok;Lee, Byung-Ha
    • Journal of the Korean Ceramic Society
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    • v.43 no.10 s.293
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    • pp.601-606
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    • 2006
  • For the purpose of development of red color stain body, bone body which can be fired at 1180$^{\circ}C$ and has a higher degree of whiteness and transmission was developed and a property experiment depending on the content of $Fe_2O_3$ was performed. For manufacturing this body, 9% addition of bone ash to commercialized white body resulted in the best whiteness and proper physical characteristics. In an experiment of oxidized iron addition using this body as a basis, red color stain body fired up to 1150$^{\circ}C$ following the addition of 6% oxidized iron showed physical characteristics such as 5.4R color closer to theory color, 0.08% water absorption rate, 9.1% shrinkage, and 1861 kgf/$cm^2$ bending strength, which implies that this body is suitable for red color stain body.

Manufacturing of Ultra-light Ceramsite from Slate Wastes in Shangri-la, China

  • Li, Zhen;Zhang, Haodong;Zhao, Pengshan;He, Xiaoyun;Duan, Xiaowei
    • Journal of the Korean Ceramic Society
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    • v.55 no.1
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    • pp.36-43
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    • 2018
  • The physical and chemical analyses of mineral waste such as moisture content, water absorption, freezing-thawing resisting sexual, chemical composition and crystal structure were investigated. In the technological process of crushing, screening, molding, drying, preheating, sintering and cooling, many parameters were changed to eliminate the influence of freeze thaw stability and the ball billets were processed into slate ceramsites eventually. Adopting orthogonal experiment and range analysis, the optimal technology parameters were confirmed as preheating temperature of $300^{\circ}C$ for 25 minutes and sintering temperature of $1230^{\circ}C$ for 20 minutes. Slate wastes in Shangri-la could foam and expand without any additive. The ultra-light ceramsite could be directly used as building aggregate, since the analysis results of its leaching toxicity were eligible. Besides, effects of sintering temperature on physical property and crystal phase were also explored in this study.