• 제목/요약/키워드: waste-water

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축산폐수(畜産廢水) 처리시(處理時) 전기전도도(電氣傳導度)를 기준(基準)한 천연(天然) Zeolite의 교환시기(交換時期) 결정(決定) (Determination of Refreshing Time of Natural Zeolite Used for Livestock Waste Water Clearing Based on Electrical Conductivity)

  • 최정;서영진;이동훈
    • 한국토양비료학회지
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    • 제29권2호
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    • pp.130-136
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    • 1996
  • EC(Electrical conductivity) meter를 이용(利用)하여 폐수(廢水) 처리제(處理劑)로 사용(使用)된 천연(天然) Zeolite의 교환시기(交換時期)를 쉽고 간편(簡便)하게 결정(決定)하고자 상징액(上澄液)의 EC변화(變化)와 Zeolite에 의한 이온의 흡착반응(吸着反應)과의 관계(關係)를 조사(調査)하였다. 용액중(溶液中)의 양이온이 Zeolite에 흡착(吸着)됨에 따라 상징액(上澄液)의 EC는 흡착평형(吸着平衡) 시(時)까지 감소(減少)하였으며 그 이후(以後)는 일정(一定)한 EC를 유지(維持)하였다. 시료량(試料量) 및 첨가용액(添加溶液)의 농도(濃度)가 증가(增加)할수록 $NH_4{^{+}}$$K^+$의 흡착량(吸着量)이 많아져서 용액(溶液)의 EC는 크게 감소(減少)하였다. Na-Zeolite가 Ca-Zeolite보다 $NH_4{^{+}}$$K^+$의 흡착량(吸着量)은 많았으나 $Na^+$의 탈착속도(脫着速度)가 $Ca^{2+}$ 보다 빠르고 용이(容易)하기 때문에 EC의 변화(變化)는 적었다. 실제(實際) 축산폐수(畜産廢水)에서도 Zeolite에 의한 흡착반응(吸着反應)이 진행(進行)됨에 따라 용액(溶液)의 EC가 감소(減少)하였고 그 경향(傾向)은 혼합한 용액(溶液)에서와 비슷하였다. 동일농도(同一濃度)의 용액(溶液)을 계속 첨가(添加)하여 반응(反應)을 조사(調査)한 결과(結果) 축산폐수와 혼합폐수 모두 4회(回)의 처리(處理)로 흡착포화상태(吸着飽和狀態)에 도달(到達)했으며 이때의 상징액(上澄液)의 EC는 첫 축산폐수(畜産廢水)의 EC와 같아졌기에 이때를 Zeolite 교환시기(交換時期)로 결정(決定)하여야 할 것이다.

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발효에 의한 수소생산의 경제성 평가 (Economic Evaluation of Hydrogen Production by Fermentation)

  • 김봉진;김종욱;박상용
    • 한국수소및신에너지학회논문집
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    • 제19권2호
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    • pp.145-155
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    • 2008
  • This paper deals with an economic evaluation of hydrogen production by fermentation. We evaluate the economic feasibility of domestic hydrogen production by fermentation utilizing glucose and waste water sludge in terms of hydrogen production prices. In addition, we make some sensitivity analysis of hydrogen prices by changing the values of input factors such as the price of glucose, the capital cost of the hydrogen production system, and the hydrogen production yields. The estimated hydrogen prices of the two-step dark-light hydrogen production by fermentation utilizing glucose was $5,347won/kgH_2$, and the single-step hydrogen production by anaerobic fermentation utilizing waste water sludge was $4,255won/kgH_2$, respectively. It is expected that the hydrogen production price by anaerobic fermentation can be reduced if we produce methane or hydrogen utilizing by-products such as alcohols and organic acids, or the government imposes some legal regulations on the treatment of waste water sludge.

變形된 活性汚泥法과 톱밥 土壤濾過法을 利用한 畜産廢水處理에 關한 硏究 (Study on the Livestock Waste Water Treatment by the Modified Activated-Sludge Process and Sawdust-Soil Filter Method)

  • 전병수;곽정훈;탁태영
    • 한국축산시설환경학회지
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    • 제1권1호
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    • pp.77-82
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    • 1995
  • In order to investigate the purification effects of livestock waste water, Modified Activated-Sludge Process(MASP) containing marine silica and volcanic ash-rock as the contact media and Sawdust-Soil Filter Method were used. The results obtained are as follows: 1. MASP which treated two metric tons' livestock waste water a day decreased BOD by 97.5% from 4,400.0mg/I to 108.8mg/I and SS by 98.0% from 5,335.0mg/I to 111.0mg/I. 2. MASP decreased BOD by 93.9% from 2,549.1mg/I to 156.6mg/I and SS by 96.3% from 3,521.9mg/I to 132.0mg/I when ten metric ton's livestock waste water was treated a day. 3. BOD and SS were decreased by 83.4% from 45.1mg/I to 7.5mg/I and by 83.4% from 47.5mg/I to 7.9mg/I when the supernatant layer treated by MASP was purified by Sawdust-Soil Filter Method.

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자동화된 Liquid Phase Microextraction(LPME)를 이용한 폐수 중 12종의 클로로페놀 분석 (Analysis of 12 chlorophenols in waste-water using automated liquid phase microextracion (LPME) device)

  • 김석중;조현우;명승운
    • 분석과학
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    • 제20권1호
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    • pp.70-77
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    • 2007
  • 클로로페놀 12종을 폐수로부터 LPME법을 사용하여 추출하였고, GC/MS로 분석하였다. 최적의 추출조건을 확립하기 위해 추출용매의 종류, 시료의 양, pH, 염석 효과, 플런저 왕복 횟수 및 속도를 고려하여 최적의 조건을 확립하였다. 그 결과, 직선성이 0.9913에서 0.9999를 가지는 12가지의 검정곡선을 얻을 수 있었고, 검출한계와 정량한계도 2,3,4,5-테트라클로로페놀과 펜타클로로페놀(0.05-500 ng/mL)을 제외하고 0.05~10.0 ng/mL범위에서 얻을 수 있었다. 실제 폐수에서 4-클로로-3-메틸페놀(784 ng/mL)을 확인할 수 있었다.

하천 수질관리 시스템에서 최적화를 위한 유전알고리즘의 개발 (Development of a Genetic Algorithm for the optimization in River Water Quality Management System)

  • 성기석;조재현
    • 한국경영과학회:학술대회논문집
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    • 한국경영과학회 2001년도 추계학술대회 논문집
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    • pp.203-206
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    • 2001
  • Finding the optimal solution in the river water quality management system is very hard with the non-linearity of the water quality model. Many suggested methods for that using the linear programming, non-linear programming and dynamic programming, are failed to give an optimal solution of sufficient accuracy and satisfaction. We studied a method to find a solution optimizing the river water quality management in the aspect of the efficiency and the cost of the waste water treatment facilities satisfying the water Quality goals. In the suggested method, we use the QUAL2E water quality model and the genetic algorithm. A brief result of the project to optimize the water quality management in the Youngsan river is presented.

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돈사폐수의 세정산발효시 온도와 전처리의 영향 (Effect of Temperature and Pre-treatment for Elutriated Acidogenic Fermentation of Piggery Waste)

  • 배진연;민경석
    • 한국물환경학회지
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    • 제21권1호
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    • pp.34-39
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    • 2005
  • The performance of elutriated acid fermentation with slurry-type piggery waste was investigated, especially to evaluate the effects of temperature and pre-treatment. In the first phase, the acid elutriation reactor with piggery waste after centrifugation operated at both mesophilic and thermophilic conditions to evaluate the effect of temperature. Solubilization yield($gVFAs/gSCOD_{prod.}$) and acidification rate($gVFAs/gSCOD_{prod.}$) in the thermophilic digestion were 0.45 and 0.55, which were higher than those of the mesophilic digestion, 0.25 and 0.45. In addition, the acid elutriation reactor at thermophilic temperature is more effective in removing e-coli. In the second phase, the acid elutriation reactor was fed with piggery waste before centrifugation. With piggery wastes before centrifugation, the solubilization yield and the acidificaton rate were 0.40 and 0.80, respectively, which were higher than the rates using piggery waste after centrifugation at both mesophilic and thermophilic conditions. The higher sludge volume reduction of 80% benefits sludge management. Furthermore, economical advantages can be achieved by removing the pre-treatment process, such as centrifugation. Consequently, the treatment with piggery waste before centrifugation proved to be effective. Also, the optimum temperature condition was estimated at mesophilic or thermophilic conditions, considering solubilization yields and acidification rates, though the system should be heated.

수정된 MLE 공정을 이용한 Full-Scale에서의 돈사분뇨처리 (Piggery Waste Treatment using Improved MLE Process in Full-Scale)

  • 황인수;민경석
    • 한국물환경학회지
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    • 제22권5호
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    • pp.895-904
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    • 2006
  • The improved MLE (modified Ludzack-Ettinger) process was operated for piggery waste treatment in full-scale public livestock waste treatment plant. The treated waste from bioreactor was suitable for the strict effluent standard of 200 mgCOD/L and 60 mgTN/L as it was dewatered chemically without settling tank and passed through filtration process. Though this treatment method produced a great deal of sludge ($6.4m^3\;per\;m^3$ dewatered piggery waste) it was able to accomplish predominant effluent quality by removing non-biodegradable COD and color without advanced oxidation process as ozone, fenton and etc.. The nitrogen removal efficiency of bioreactor was rapidly declined from March to May (from 0.016 to 0.005 kgN/kgVSS-day) when disinfection is in earnest as well as from warm season when reactor temperature rises higher than $35^{\circ}C$(from 0.016 to 0.008 kgN/kgVSS-day). This study proves that counterplanes for infection residuals, bioreactor temperature and dewatering sludge reduction are necessary for piggery waste treatment.

방사성고화체로 부터의 Co, Cs침출에 대한 표준시험법의 상호비교 (Comparative Evaluation of Various Standard Methods in Leaching Test of Radioactive Waste Form)

  • 김기홍;유영걸;정경기;홍권표;이락희;정의영;고덕준;김헌
    • 한국방사성폐기물학회:학술대회논문집
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    • 한국방사성폐기물학회 2003년도 가을 학술논문집
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    • pp.21-31
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    • 2003
  • IAEA, FT-04-020, ANS 16.1의 침출시험법을 각각 수행하여 얻은 시험결과를 이용하여 상호비교 평가하였다. 붕산을 함유한 파라핀 및 시멘트 고화체에서의 Co-60과 Cs-137의 침출지수는 6이상이었으나 고화매질과 탈염수의 종류에 따라 상반되는 침출거동을 보였다. 침출수로 합성해수와 탈염수를 사용하였을 경우 Co는 시멘트 고화체에서는 합성해수, 파라핀 고화체에서는 탈염수에서 침출이 높았다. 반면에 Cs의 침출정도는 시멘트에서는 탈염수, 파라핀에서는 합성해수에서 높았다. Co의 침출분율은 시멘트 고화체에서 IAEA > ANS > FT의 순으로 높았으며, 반대로 파라핀 고화체에서는 이의 역순이었다.

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낮은 물비를 갖수용성 합성 절삭유의 재사용을 위한 한외여과 연구는 콘크리트 제품에 대한 폐주물사의 적용 (Application of Waste Foundry Sand for Concrete-Based Products of Low Water Ratio)

  • 김진만;조성현;곽은구
    • 청정기술
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    • 제8권3호
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    • pp.129-139
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    • 2002
  • This is the study for recycling waste foundry sand. Authors studied about main subject of grading of aggregate and three experimental items such as physical properties of waste foundry sand, optimum grading for concrete products of low water ratio, and quality variations of concrete products according to substitution proportion of fine aggregate as waste foundry sand. We were convinced of following results by experimental study. The first was that waste foundry sand was not fit as the aggregate for concrete because of bad qualities such as grading, unit weight, solid volume and passing 0.08 mm seive, so it is proper to composition using with other fine aggregetes. The second was that optimum grading is fineness modulus of 2.77 to 3.28 And the last is that optimum condition about substitution proportion as waste foundry sand is 10% fine aggregate.

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