• Title/Summary/Keyword: waste sludge

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Separation and Recovery of Rare Earth Elements from Phosphor Sludge of Waste Fluorescent Lamp by Pneumatic Classification and Sulfuric Acidic Leaching

  • Takahashi, Touru;Takano, Aketomi;Saitoh, Takayuki;Nagano, Nobuhiro;Hirai, Shinji;Shimakage, Kazuyoshi
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.421-426
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    • 2001
  • The pneumatic classification and acidic leaching behaviors of phosphor sludge have been examined to establish the recycling system of rare earth components contained in waste fluorescent lamp. At first, separation characteristic of rare earth components and calcium phosphate in phosphor sludge was investigated by pneumatic classification. After pneumatic classification of phosphor sludge, rare earth components were leached in various acidic solutions and sodium hydroxide solution. For recovery of soluble component in leaching solution, rare earth components were separated as hydroxide and oxalate precipitations. The experimental results obtained are summarized as follows: (1) In classification process, rare earth components in phosphor sludge were concentrated to 29.3% from 13.3%, and its yield was 32.9%. (2) In leaching process, sulfuric acid solution was more effective one as a leaching solvent of rare earth component than other solutions. Y and Eu components in phosphor sludge were dissolved in sulfuric acid solution of 1.5 k㏖/㎥, and other rare earth components were rarely dissolved in leaching solution. Leaching degrees of Y and Eu were respectively 92% and 98% in the following optimum leaching conditions; sulfuric acid concentration is 1.5 k㏖/㎥ , leaching temperature 343 K, leaching time 3.6 ks and pulp concentration 30 kg/㎥. (3) Y and Eu components of phosphor sludge contained in waste fluorescent lamp were, effectively recovered by three processes of pneumatic classification, sulfuric acid leaching and oxalate precipitation methods. Their recovery was finally about 65 %, and its purity was 98.2%.

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Evaluation of Low-temperature Thermal Pre-treatment and Biogas Characteristics using Waste Activated Sludge (잉여슬러지를 이용한 저온 열적전처리 및 바이오 가스 특성 평가)

  • Choi, Jae-Hoon;Jeong, Seong-Yeob;Kim, Ji-Tae
    • Journal of Korean Society on Water Environment
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    • v.35 no.4
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    • pp.299-307
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    • 2019
  • The purpose of this study was to investigate the effect of low temperature thermal pre-treatment on biodegradation of waste activated sludge for anaerobic digestion as a countermeasure for increasing sludge generation. The experimental condition was accomplished in 2 %, 4 %, and 6 % TS concentration, and $70^{\circ}C$, $80^{\circ}C$, $90^{\circ}C$ of temperature for a maximum of 120 minutes retention time. Then, it was followed by analysis of physical/chemical properties, BMP test and composition of biogas. The biogas characteristic was evaluated by applying the modified Gomperz model. As a result, solubility of dissolved substrate, such as $SCOD_{Cr}$, soluble carbohydrate, and soluble protein, and biogas production increased as temperature increased. Solubilization efficiency at $90^{\circ}C$ was 18.4 %, 17.03 % and 16.88% in 2 %, 4 %, and 6 % TS concentration respectively. Also, solubilization rates of carbohydrate and protein similarly increased. BMP test results also showed that methane production in excess sludge increased to 0.194, 0.187 and $0.182m^3/kg$ VS. respectively, and lag phase decreased to 0.145, 0.220, 0.351 day due to acceleration of the hydrolysis step. Consequently, low-temperature thermal pre-treatment could increase biodegradability of sludge, positively affecting biogas production and sludge reduction.

The Evaluation of Scum Recyclability from Waste Sludge in Linerboard Mills (라이너지 제조공정 탈수 슬러지의 scum 재이용 가능성 평가)

  • Kang, Kwang-Ho;Kim, Hyoung-Jin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.40 no.3
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    • pp.42-47
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    • 2008
  • For the purpose of reduction of production cost in the industrial papermaking process, the use of waste paper has been more and more increased as a fibrous raw material, and the closed system of white water became closed more than ever. "Scum" indicates the floated sludge by a flotation during primary wastewater treatment process in paper mills. If the scum is used as the raw material, it could reduce both the raw material and solid waste treatment cost with even small quantity. In this study, the element survey and the toxicity measurement was carried out for recycling scum. A load factor of stock preparation process in paper mills was measured by somerville screen. Physical properties of paper sheet containing the accepted scum from the stock of AOCC or KOCC were evaluated. The result of this study shows that recycling scum has potential to be used in paper making system. It also might be able to reduce the required energy used by the pressing or drainage process, the raw material cost, and solid waste treatment cost due to the recycling of scum.

Properties of Lightweight Foamed Concrete According to the Replacement Ratio of Waste Concrete Sludge and Variation of Foam Ratio (폐콘크리트슬러지 대체율과 기포혼입률 변화에 따른 경량기포콘크리트의 특성)

  • Lee, Jung-Goo;Kim, Jae-Won;Choi, Hun-Gug;Kang, Cheol;Lee, Do-Heun;Kim, Jin-Man
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2007.11a
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    • pp.53-56
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    • 2007
  • Recently, waste concrete emission has been increased by acceleration of urban development and the rapid growth of redevelopment projects, so recycling of waste concrete is actively progressed, But the usage is limited to a lower value added such as the roadbed material etc. To produce the high quality recycled aggregate, breaking and washing process is added to the existing process and inevitably increases the occurrence of particle, because old mortal is included in the recycled aggregate. Therefore, this study purpose is analysis the properties of lightweight foamed concrete made by waste concrete sludge which is the by-product from produce the recycled aggregate. In result, possibility of manufacture of lightweight foamed concrete which gives equal performance compared with ALC was detect(scope of density : $0.5{\sim}0.6$, scope of compressive strength : $3.5{\sim}4.0MPa$). And scope of porosity is as follow ; total porosity : $27{\sim}30%$, open porosity : $1{\sim}5%$

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Ultrasonic Pretreatment for Thermophilic Aerobic Digestion in Industrial Waste Activated Sludge Treatment

  • Kim, Young-Kee;Kwak, Myung-Shin;Lee, Won-Hong;Park, Jeong-Woo
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.5 no.6
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    • pp.469-474
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    • 2000
  • In order to enhance the degradation efficiency of waste activated sludge (WAS) by thermophilic aerobic digestion, an ultrasonic pretreatment was examined. It was observed that ultrasonic pretreatment increased the solubilization of organic matter in the WAS and that the solubilization ratio of the organics increased during the first 30 min but did not extensively increase thereafter. Therefore, a pretreatment time of 30 min was determined to be the economical pretreatment time from the experimental results. From the digestion experiments, which was conducted using the WAS collected from an oil refinery plant in Inchon, Korea, investigating the effects of an ultrasonic pretreatment on thermophilic aerobic digestion, it was confirmed that the proposed ultrasonic pretreatment was effective at enhancing the release of the cellular components in WAS and the degradation of released components in the thermophilic aerobic digestion.

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The Effect of Cement Admixtures on Solidification of Tannery Sludge based Cement Method (피혁슬러지 고형화시 시멘트 혼화제의 영향)

  • 주소영;박상찬;전태성;손종렬;김태영
    • Journal of environmental and Sanitary engineering
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    • v.18 no.4
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    • pp.36-44
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    • 2003
  • The cement-based system among S/S(Solidification/Stabilization) is widely used to treat hazardous wastes. In this study, tannery sludge was solidified to evaluate the stabilization effects of using admixtures in the cement-based S/S. Fly ash as substitute also used to increase the strength of the S/S of hazardous waste. The compressive strength measurement and leaching experiment of chromium metal of solidified mortar were carried out to compare and evaluate the physical and chemical characteristics of solidified hazardous waste sludge. From the result of this study, there was increased of compressive strength by using AEW-3(early-hardening AE water reducing agent), and leaching concentration of chromium became low enough to satisfy the regulatory criteria. The successful solidification for the organic contaminant and heavy metal in hazardous waste should enable to treat by cement-based system using early-hardening AE water reducing admixture and fly ash as substituted cement.

Biosorption of Rhodamine B onto Waste Activated Sludge: Equilibrium and Kinetic Modelling (폐 활성슬러지를 이용한 Rhodamine B의 생체흡착:흡착평혀여 및 흡착속도 모델링)

  • Lee Chang-Han;Ahn Kab-Hwan
    • Journal of Environmental Science International
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    • v.14 no.9
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    • pp.881-888
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    • 2005
  • The biosorption of dye, Rhodamine B(Rh-B), onto waste activated sludge was investigated. The biosorption capacity and contact time were shown as a simulation of dye adsorption equilibrium and kinetics models. We observed that biosorption of Rh-B occurred rapidly less than 4 hr. These experimental data could be better fitted by a pseudo-second-order rate equation than a pseudo-first-order rate equation. The equilibrium dependence between biosorption capacity and initial concentration of Rh-B was estimated and it was found that the equilibrium data of biosorption were fitted by four kinds of model such as Langmuir, Freundlich, Redlich-Peterson, and Koble-Corrigan model. The average percentage errors, $\varepsilon(\%)$, observed between experimental and predicted values by above each model were $21.19\%,\;9.97\%,\;10.10\%\;and\;11.76\%$, respectively, indicating that Freundlich and Redlich-Peterson model could be fitted more accrately than other models.

Investigation on the biodegradation of VOCs in soil, sewage sludge, and food waste compost (토양.하수 슬러지.음식물 쓰레기 퇴비내에서의 휘발성 유기화합물(VOCs)의 기체상 생분해에 관한 연구)

  • 김혜진;이은영;박재우
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2000.05a
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    • pp.11-14
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    • 2000
  • Wastewater sludge and composted food wastes were examined as the alternatives of a landfill cover for soils to eliminate the emission of VOCs. The benefit of these alternatives is in their high sorption capacity, which is 5 to 50 times higher than natural soils. After sorption is finished, biodegradation is an important mechanism in decrease of VOCs concentration. In order to investigate appropriate VOCs degradation condition, biodegradation batch experiment is being conducted with isolated strain X9-c. Both benzene and TCE were degraded only in soil with 12%(water volume/sorbent volumn) water condition. When the water condition varied from 12 to 48% in compost, optimum water conditions of composted food waste was 36%.

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Optimum Operation of Thermophilic Aerobic Digestion Process for Waste Activated Sludge Minimization

  • Kim, Young-Kee;Choi, Jeong-Woo
    • Journal of Microbiology and Biotechnology
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    • v.12 no.4
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    • pp.683-686
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    • 2002
  • To achieve optimum operation of a thermophilic aerobic digestion (TAD) process for waste activated sludge (WAS), TAD experiments using Bacillus stearothermophilus (ATCC 31197) were carried out to investigate the optimum concentration of dissolved oxygen (DO). TAD reactors were operated at DO concentrations of 0, 1, 2, 3, 4, and 5 ppm, and the results showed that the WAS could be successfully degraded by a TAD system operated with a DO concentration of 1 ppm and above. When the TAD system with an optimum additive (2 mM Ca ion), selected from a previous study, and 1 ppm DO concentration were combined with a thermal pretreatment ($121^{\circ}C$, 10 min), the results exhibited upgraded total suspended solids and an enhanced protein degradation.

Applicability of inorganic waste as binder at manufacturing of Light weight aggregates using high content sewage sludge (하수슬러지 인공경량골재 제조를 위한 무기계 폐기물의 점결제 적용성 평가)

  • Kim, Dug-Mo;Mun, Kyoung-Ju;Soh, Yang-Seob
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05b
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    • pp.157-160
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    • 2005
  • The purpose of this study is to efficiently treat the sewage sludge discharged from sewage treatment plants and evaluate the feasibility of the manufacture of lightweight aggregates(LWA) using a large quantity of sewage sludge and inorganic waste binder ;f1y-ash, waste-stone, tailing, phosphogypsum. Then they were burned in different soak temperatures from 1190$^{circ}C$ to 1290$^{circ}C$ with fixed soak time and heating rate at 5 minutes and 20$^{circ}C$/min respectively in order to produce lightweight aggregate (LWA). Experiment were generated to evaluate the quality of LWA as well as the relationship between burning condition and product's quality.

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