• Title/Summary/Keyword: waste slag

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An Experimental Study on Alkali-Silica Reaction of Mortar Containing Waste Glass and By-products (폐유리 및 산업부산물을 혼입한 모르터의 ASR에 관한 실험적 연구)

  • Lee, Bong-Chun;Kwon, Hyuk-Joon;Kim, Jeong-Hwan;Lee, Jun;Park, Seung-Bum
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.11a
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    • pp.93-98
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    • 2001
  • Using waste glass in concrete can cause crack and strength loss by the expansion of alkali-silica reaction(ASR). In this study, ASR expansion and properties of strength were analyzed in terms of clear waste glass grading, and by-products(fly ash, blast-furnace slag) and by-products content for reduction ASR expansion due to waste glass. In this accelerated ASTM C 1260 test of waste glass, pessimum grading can be found. Also, when the by-products are used with waste glass, there is an effect on reduction of expansion and strength loss due to ASR between the alkali in the cement paste and the silica in the waste glass.

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Preparation of Glass-Ceramic by Recycling of Various Slags and Its Properties (다종슬래그를 재활용한 Glass-Ceramic의 제조 및 물성)

  • Lee, Duk-Hee;Shin, Dongyoon;Yoon, Mijung;Park, Hyun Seo;Yoon, Jin-Ho
    • Korean Journal of Materials Research
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    • v.26 no.5
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    • pp.266-270
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    • 2016
  • Glass-ceramics were developed many years ago and have been applied in many fields such as electronics, chemistry, optics, etc. Much is already known about glass-ceramic technology, but many challenges in glass-ceramic research are still unresolved. Recently, large amounts of slag have steadily increased in the steel industry as by-products. To promote recycling of industrial waste, including steel industry slags, many studies have been performed on the fabrication of basalt-based high-strength glass-ceramics. In this study, we have fabricated such ceramics using various slags to replace high performance cast-basalt, which is currently imported. Glass-ceramic material was prepared in similar chemical compositions with commercial cast-basalt through a pyro process using slags and power plant by-product (Fe-Ni slag, converter slag, dephosphorization slag, Fly ash). The properties of the glass-ceramic material were characterized using DTA, XRD, and FE-SEM; measurements of compressive strength, Vicker's hardness, and abrasion were carefully performed. It is found that the prepared glass-ceramic material showed better performance than that of commercial cast-basalt.

Fabrication of the Cement for the Solidification of the Toxic Waste using Waste Concrete Powder (폐콘크리트 미분말을 이용한 유해 폐기물 고화용 시멘트의 제조)

  • Kim, In-Seob;Won, Jong-Han;Choi, Kwang-Hui;Choi, Sang-Hul;Lee, Jong-Gyu;Sohn, Jin-Gun;Shim, Kwang-Bo
    • Journal of the Korean Ceramic Society
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    • v.39 no.12
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    • pp.1133-1137
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    • 2002
  • The cement for solidification of the toxic waste was fabricated using a mixture of the waste concrete powder and blast furnace slag in the ratio of 1:1 and its hydrate morphology and compressive strength of the sample were evaluated in order to apply to the solidification of the COREX sludge. The X-ray diffraction analysis of the sample which prepared by the addition of 10% Portland cement and hemihydrate showed the presence of $Ca(OH)_2$, ettringite, gel-phase and C-S-H hydrate. Compressive strength of the sample exhibited enough high to use as a solidification cement. The strength of the sample was over 140 kgf/$m^2$ in 7 days in case of solidification of the COREX sludge and the sample possess sufficient morphology for the solidification and stabilization of the waste sludge.

Strength evaluation of concrete with fly ash and GGBFS as cement replacing materials

  • Chore, H.S.;Joshi, M.P.
    • Advances in concrete construction
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    • v.3 no.3
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    • pp.223-236
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    • 2015
  • Concrete is the most widely used material of construction. Concrete gained the popularity as a construction material due to the easy availability of its component materials, the easy formability, strength and rigidity upon setting and curing.In construction industry, strength is the primary criterion in selecting a concrete for a particular application. Now a days, the substantial amount of waste materials, containing the properties of the Pozzolana, is being generated from the major industries; and disposal of such industrial wastes generated in abundance is also a serious problem from the environmental and pollution point of view. On this backdrop, efforts are made by the researchers for exploring the possible utilization of such waste materials in making the sustainable construction material. The present paper reports the experimental investigations to study the strength characterization of concrete made from the pozzolanic waste materials. For this purpose, the Pozzolanic materials such as fly ash and ground granulated blast furnace slag were used as a cement replacing materials in conjunction with ordinary Portland cement. Equal amount of these materials were used in eight trial mixes with varying amount of cement. The water cement ratio was also varied. The chemical admixture was also added to improve the workability of concrete. The compressive strengths for 7, 28, 40 and 90 days' were evaluated whereas the flexural and tensile strengths corresponding to 7, 28 and 40 days were evaluated. The study corroborates that the pozzolanic materials used in the present investigation along with the cement can render the sustainable concrete.

Effect of supplementary cementitious materials on the degradation of cement-based barriers in radioactive waste repository: A case study in Korea

  • Min-Seok Kim;Sol-Chan Han;Jong-Il Yun
    • Nuclear Engineering and Technology
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    • v.56 no.9
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    • pp.3942-3949
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    • 2024
  • This study focuses on investigating the chemical degradation characteristics of cementitious barriers used in low-and intermediate-level radioactive waste repository by reactive transport modeling. The impact of the blending with supplementary cementitious materials (SCMs) in the barriers on the chemical degradation was evaluated to find the optimum barrier design. A number of different barrier designs were examined by replacing ordinary Portland cement (OPC) by SCMs (i.e., fly ash, silica fume, and blast-furnace slag). The simulation results showed that silica fume blended barrier has better durability against chemical degradation by rainwater compared to fly ash or blast-furnace slag blended barriers. In addition, the chemical durability of silica fume-based barrier increased with increasing replacement level up to about 20 %. It seems that the amount of formed calcium silicate hydrate (CSH) in the initial cement-based barrier highly affects the overall chemical durability. The newly developed reactive transport model demonstrated its capability for understanding the barrier performance and investigating the optimal design of the barrier system.

Properties of High Volume Blast Furnace Slag Concrete using Recycled Aggregate with Incineration Waste Ash (소각장애시의 치환에 따른 고로슬래그 미분말 다량치환 순환골재 콘크리트의 특성)

  • Han, Cheon-Goo;Lee, Hyang-Jae;Kim, Jun-Ho
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.1 no.2
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    • pp.107-113
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    • 2013
  • This study is the study desiring to solve the problem by utilizing the kinds of recycled resources considered to be troubled complementarily. Namely the reaction of potential hydraulicity of Blast Furnace Slag Powder (BS) shall be reacted with the alkali of Recycled Fine Aggregates Coarse Aggregate, it has been experimented to obtain the optimum value with the replacement ratio of incineration plant ash (WA) treated with the slaked lime as the experiment variable by solving the alkali of shortage with the Ordinary Portland Cement (OPC). As a result, the liquidity and the air volume are declined slightly as the replacement ratio of incineration plant ash WA increases, the mixture of incineration plant ash WA 1% has been analyzed to be the most suitable considering the viewpoint of effective handling of waste as the compression and the tensile strength showed the maximum value before and after 1% even though it was disadvantageous with the increase of chloride content.

Evaluation of Rutting Behavior of Hot Mix Asphalt using Slag and Waste Foundry Sand as Asphalt Paving Materials (슬래그와 폐주물사를 이용한 아스팔트 혼합물의 소성변형특성에 관한 연구)

  • Lee, Kwan-Ho;Cho, Jae-Yoon;Jeon, Joo-Yong
    • 한국도로학회:학술대회논문집
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    • 2002.10a
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    • pp.89-92
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    • 2002
  • The objective of this research is to evaluate engineering properties of recycled aggregates, slag as coarse & fine aggregate and waste foundry sand(WFS) as fine aggregate, in hot mix asphalt(HMA). In this research, soundness, gradation and particle analysis, abrasion, specific gravity and absorption test were carried out. The optimum asphalt binder content(OAC) for various HMA combinations of recycled aggregate was determined by Marshall Mix Design. The ranges determined is between 7.2% and 7.5%. Indirect tensile test, resilient modulus test, creep test were carried out for characterization of rutting behavior of various combination of HMA. Judging from the limited tests, the HMA with recycled aggregates is not as good rutting resistance as the HMA with common aggregates. After finishing the Wheel tracking test, the application or feasibility for the use of recycled aggregate as asphalt paving material will be determined.

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Distribution Characteristics of Radionuclies (60Co, 137Cs) During the Melting of Radioactive Metal Waste (방사성 금속폐기물의 용융시 방사성 핵종(60Co, 137Cs)의 분배특성)

  • Min, Byung Youn;Choi, Wang Kyu;Oh, Won Zin;Jung, Chong Hun;Kang, Yong
    • Korean Chemical Engineering Research
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    • v.45 no.6
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    • pp.627-632
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    • 2007
  • A fundamental study on the melt decontamination of metal wastes generated by dismantling the nuclear facility, the melting of metal wastes such as stainless steel and carbon steel have been carried out to investigate the distribution phenomena of the radioisotopes such as $^{60}Co$ and $^{137}Cs$ into the ingot, slag and dust phases by using the various slag types, slag concentration and basicity in an arc furnace. The $^{60}Co$ remained homogeneously in the ingot phase above 90 % and it was barely present in the slag below 10 %. The effect of the slag composition on the distribution for Co-60 was not considerable, but a basic slag former with high fluidity showed effective. $^{137}Cs$ was completely eliminated from the melt of the stainless steel as well as the carbon steel and distributed to the slag and the dust phase.

The Study of Luppe Smelting with Converting Dust and Slag (제강전로 더스트와 슬래그를 이용한 루페제련에 관한 연구)

  • 황용길;이상화;김재일;김연수
    • Resources Recycling
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    • v.7 no.2
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    • pp.39-45
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    • 1998
  • We smelted thc pellets made by mixing the distilled carbon from wlISte Lires, LD converter dust and slag with reduction process in the revcrberatory furnace. Thc obtained results are as follows 1) The removal mte of zinc appears above 97% after T reducing the pellets at $1300^{\circ}C$ for Ihr and the zinc content in the residue are 0.1~D.2%. 2) Under the mixing condition of 500 g LD dust. 150-200 g LD slag and 30-50 g distilled carbon of waste lires the removal raho of zinc shows above 95%, while t the 50-60% Fe remains in the residue. 3) After smelting at $1350^{\circ}C$ for 3hrs, the recovery ratio of pig iron reduced from lhe p pellets containing 15-20% LD slag and 4.1-7.2% distilled carbon of waste tires appears in the range of 89.3-92%. 4) Tbe c chemical composition of the recovered pig iron is 1.7%C, O.05%P, 0.05%S and balance Fe. 5) Tbe recovered dust from the d dust collcctor alter finishing the reduction rcaction appears as a crude zinc oxide conLaining 60% zinc.

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Guideline for Media-contact Recycling of Steel-Making Slag: Leaching Tests and Comparison of International Recycling Guidelines (제강슬래그의 친환경적 매체접촉형 재활용 방안: 용출시험 및 국내외 재활용 지침 비교)

  • Donghyun Kim;Inseong Hwang;Won Sik Shin
    • Journal of Soil and Groundwater Environment
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    • v.29 no.1
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    • pp.39-50
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    • 2024
  • Slags from steel-making industry have been recycled at a target rate of 95% and most of them are recycled as media-contact type such as fill and cover materials in Korea. However, as they contain free phase CaO during their generation, they may not only expand and collapse upon contact with water, but high pH leachate and heavy metals leaching may occur. In this study, the Korean leaching procedure (KLP) and up-flow percolation test were performed for the samples collected from 17 steel-making production plants in Korea. The waste quality criteria were met in all tests, but pH of the samples was above 10. There are no regulations on the pH of leachate in most of the countries, however, Germany, Italy, and Australia have set a pH range of 10 to 13 for the leachates. Although slag leachate cannot be considered hazardous based only on its high pH, it is necessary to reduce the pH of leachate to minimize the impact on the surrounding environment. Furthermore, conflicting regulations on wastes handling and management in Korea created confusion on the types of wastes subject to recycling. Therefore, an appropriate management plan for steel-making slags needs to be established. To this end, this study attempted to provide a guideline for managing steel-making slag waste by considering international guidelines and current management practices in Korea.