• Title/Summary/Keyword: waste rock

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Rock Weathering and Geochemical Characteristics in the KURT (한국원자력연구소 지하처분연구시설(KURT)의 암석 풍화 및 지화학적 특성)

  • Lee, Seung-Yeop;Baik, Min-Hoon;Cho, Won-Jin;Hahn, Pil-Soo
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.4 no.4
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    • pp.321-328
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    • 2006
  • A basic research was conducted on the mineral weathering and geochemical characteristics in the KURT (KAERI Underground Research Tunnel), which was recently constructed at a site in KAERI. Some rock samples exposed during the KURT construction were examined using a microscope and chemical analysis for some micro-changes of the rocks caused by the chemical weathering. The weathered granite has some small and fine cracks around the rock-forming minerals. In particular, there are a characteristic weathering of feldspar mineral and a preferential leaching of Ca component from the mineral dissolution. In addition, by the dissolution of biotite containing $Fe^{2+}$ component there were iron-oxides precipitates as secondary products into the microcracks of around minerals. The results also show that the micro-cracks initiated from the mineral interior are extended and connected into the larger cracks along the grain boundary with the progress of the weathering. Thus, it is considered that some chemicals dissolved from the fresh rock would be involved in the formation of secondary minerals and migrate interacting with them.

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A Study on the Hydraulic Properties of Domestic Clay/Crushed Rock Mixture for the Backfill Material in a Radioactive Waste Repository (방사성폐기물 처분장 되메움재를 위한 국산점토/분쇄암석 혼합물의 수리특성에 관한 연구)

  • Lee, J.O.;Cho, W.J.;Hahn, P.S.;Park, H.H.
    • Nuclear Engineering and Technology
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    • v.26 no.1
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    • pp.54-62
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    • 1994
  • The hydraulic properties of domestic natural clay/crushed rock mixture suggested as a candidate backfill material for the low and intermediate level waste repository were investigated. The dry density-water content relationship was studied to define an optimum water content that gives a maximum attainable dry density at constant compaction pressure. The hydraulic conductivities of clay/crushed rock mixture as a function of clay content were also measured. As the clay content decreased, the maximum attainable dry density increased and the optimum water content became more distinct. However the attainable density is not significantly sensitive to water content. The hydraulic conductivities of the mixture increased from 5 $\times$ 10$^{-12}$ m/s to 7 $\times$ 10$^{-10}$ m/s with clay content decreasing from 100 wt.% to 25 wt.% at dry density of 1.2 Mg/㎥. In case of dry density of 1.5 Mg/㎥, they maintain the lower values of 5 $\times$ 10$^{-12}$ m/s even at 25 wt.% clay content. The concept of effective clay dry density was suggested to estimate the hydraulic conductivity of the mixture. It was shown that the effective clay dry density concept can explain welt the hydraulic conductivities of the mixtures with various dry density and crushed rock content.

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A Study on Electrode Array for Measurement of Induced Polarization of Rock Samples (암석 시료의 유도분극 측정을 위한 전극배열 비교)

  • Man-ho Han;Jung-hwan Lee;Keun-Soo Lee;Myeong-Jong Yi
    • Tunnel and Underground Space
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    • v.33 no.6
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    • pp.483-494
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    • 2023
  • Measurement of the physical properties of rocks or minerals is an important factor in determining the distribution of the underground medium as well as mineral resource investigations. Resistivity and induced polarization, which are widely used in Korea, are methods for measuring electrical properties, which are representative properties of obtaining subsurface information. In order to precisely analyze the exploration data obtained from various sites, it is important to accurately measure the material properties. Electrical properties of rock is measured using two-electrode or four-electrode method. Compared to the four-electrode method, the two-electrode method is generally used because it is very easy to contact the sample and the electrode, but there is a problem in that the impedance of the electrode and the sample is measured together. In this study, the time-domain the induced polarization effects were measured using the 2-electrode method and the 4-electrode method for artificial samples mixed with graphite and cement having induced polarization characteristics, and the results were compared. Although the 4-electrode method has difficulties in installing potential electrodes, it was confirmed that it is effective in measuring electrical properties because it can reduce the problem caused by the impedance of potential electrodes compared to the 2-electrode method.

The Behavior of Leachate on The Transient Condition in The Nanji Waste Landfill (부정류 상태에서의 난지도 매립지 침출수 거동 예측)

  • 강동희;조원철;이재영
    • Journal of Soil and Groundwater Environment
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    • v.6 no.2
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    • pp.57-67
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    • 2001
  • The purpose of this study is to predict appropriate leachate rates and leachate transport velocity through weathered zone and basement rock on the transient condition at Nanji waste landfill. The leachate transport in the Nanji waste landfill is analyzed using MODFLOW(A Modular 3-D Finite Different Groundwater Flow Model) model which simulates three dimension groundwater flow and MT3D(A Modular Three Dimentional Transport Model) model which describes three dimensional transport for advection, dispersion and chemical reaction of dissolved constituents in groundwater system on the transient condition. Leachate production rates are estimated by HELP(Hydraulical Evaluation of Landfill Performance) model and used weather records for recent 10 years. Leachate transport is predicted by a change of leachate level to after/before established HDPE, established slurry wall and wells.

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Assessment of Corrosion Lifetime of a Copper Disposal Canister Based on the Finnish Posiva Methodology

  • Choi, Heui-Joo;Lee, Jongyoul;Cho, Dongkeun
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.18 no.spc
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    • pp.51-62
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    • 2020
  • In this paper, an approach developed by the Finnish nuclear waste management organization, Posiva, for the construction license of a geological repository was reviewed. Furthermore, a computer program based on the approach was developed. By using the computer program, the lifetime of a copper disposal canister, which was a key engineered barrier of the geological repository, was predicted under the KAERI Underground Research Tunnel (KURT) geologic conditions. The computer program was developed considering the mass transport of corroding agents, such as oxygen and sulfide, through the buffer and backfill. Shortly after the closure of the repository, the corrosion depths of a copper canister due to oxygen in the pores of the buffer and backfill were calculated. Additionally, the long-term corrosion of a copper canister due to sulfide was analyzed in two cases: intact buffer and eroded buffer. Under various conditions of the engineered barrier, the corrosion lifetimes of the copper canister due to sulfide significantly exceeded one million years. Finally, this study shows that it is necessary to carefully characterize the transmissivity of rock and sulfide concentration during site characterization to accurately predict the canister lifetime.

ROLE OF SOILS IN THE DISPOSAL OF NUCLEAR WASTE

  • Lee, S.Y.
    • Korean Journal of Soil Science and Fertilizer
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    • v.19 no.3
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    • pp.251-268
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    • 1986
  • Selecting a site for the safe disposal of radioactive waste requires the evaluation of a wide range of geologic, mineralogic, hydrologic, and physicochemical properties. Although highly diverse, these properties are in fact interrelated. Site requirements are also diverse because they are influenced by the nature of the radionuclides in the waste, for example, their half-lives, specific energy, and chemistry. A fundamental consideration in site selection is the mineralogy of the host rock, and one of the most ubiquitous mineral groups is clay minerals. Clays and clay minerals as in situ lithologic components and engineered barriers may playa significant role in retarding the migration of radionuclides. Their high sorptivity, longevity (stability), low permeability, and other physical factors should make them a very effective retainer of most radionuclides in nuclear wastes. There are, however, some unanswered questions. For example, how will their longevity and physicochemical properties be influenced by such factors as radionuclide concentration, radiation intensity, elevated temperatures, changes in redox condition, pH, and formation fluids for extended periods of time? Understanding of mechanisms affecting clay mineral-radionuclide interactions under prevailing geochemical conditions is important; however, the utilization of experimental geochemical information related to physicochemical properties of clays and clay-bearing materials with geohydrologic models presents a uniquely challenging problem in that many assessments have to be based on model predictions rather than on experiments. These are high-priority research investigations that need to be addressed before complete reliance for disposal area performance is made on clays and clay minerals.

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Hydrogeological Performance Assessment for Underground Oil Storage Caverns (지하유류비축시설 수리안정성 평가방안)

  • 김천수;배대석;김경수;고용권;송승호
    • The Journal of Engineering Geology
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    • v.7 no.3
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    • pp.229-245
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    • 1997
  • There are Common aspects between the underground oil storage cavern and the radioactive waste disposal facility. Both facilities use appropriately the intrinsic natural berrier characteristics of the rock mass and additionally the engineered barrier system for the long term safety. The geological structures and their hydrogeological characteristics in a faactured rock mass act a major role in the safety and performance of the underground oil storage facility through the design, construction and the operation stages. Because the fracture system distributed in a fractured rock block is complicated owing to their own geometrical and hydrogeological attributes, the hydrogeological perforrmrnce of the facility would depend mainly upon the understandings of their characteristics. This study reviews the uncertainties and key issues which have to be considered to analyse the groundwater flow system in a fractured rock mass and proposes the techniques applicable to characterize the hydrogeological parameter.

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Impact of Media Type and Various Operating Parameters on Nitrification in Polishing Biological Aerated Filters

  • Ha, Jeong-Hyub;Ong, Say-Kee;Surampalli, R.
    • Environmental Engineering Research
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    • v.15 no.2
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    • pp.79-84
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    • 2010
  • Three biological aerated filters (BAFs) composed of a PVC pipe with a diameter of 75 mm were constructed and operated at a waste-water temperature at $13^{\circ}C$. The media used for each BAF were: 5-mm gravel; 5-mm lava rock; 12.5-mm diameter by 15-mm long plastic rings, all with a media depth of 1.7 m. The feedwater, which simulated the effluent of aerated lagoons, had influent soluble chemical oxygen demand (sCOD) and ammonia concentrations of approximately 50 and 25 mg/L, respectively. For a hydraulic retention time (HRT) of two hours without recirculation, ammonia percent removals were 98.5, 98.9, and 97.8%, for the gravel, lava rock, and plastic rings, respectively. By increasing the effluent recirculation from 100 to 200% for an HRT of one hour, respective ammonia removals improved from 90.1 to 96, 76.5 to 90, and 65.3 to 79.5% for gravel, lava rock, and plastic rings. Based on the ammonia and sCOD loadings for different HRTs, the estimated maximum ammonia loading was approximately 0.6 kg $NH_3-N/m^3$-day for the three BAFs of different media types. The zero-order biotransformation rates for the BAF with gravel were found to be higher than the lava rock and plastic ring media. The results ultimately showed that BAF can be used as an add-on system to aerated lagoons or as a secondary treatment unit to meet ammonia discharge limits.

The DFN-DEM Approach Applied to Investigate the Effects of Stress on Mechanical and Hydraulic Rock Mass Properties at Forsmark, Sweden (암반균열망-개별요소법 수치실험을 통해 살펴본 스웨덴 포쉬마크지역 암반의 역학적 및 수리적 물성에 초기응력이 미치는 영향)

  • Min, K.B.;Stephansson, O.
    • Tunnel and Underground Space
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    • v.21 no.2
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    • pp.117-127
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    • 2011
  • The purpose of this study is to demonstrate the effect of in-situ rock stresses on the deformability and permeability of fractured rocks. Geological data were taken from the site investigation at Forsmark, Sweden, conducted by Swedish Nuclear Fuel and Waste Man-agement Company (SKB). A set of numerical experiments was conducted to determine the equivalent mechanical properties (essentially, elastic moduli and Poisson's ratio) and permeability, using a Discrete Fracture Network-Discrete Element Method (DFN-DEM) approach. The results show that both mechanical properties and permeability are highly dependent on stress because of the hyperbolic nature of the stiffness of fractures, different closure behavior of fractures, and change of fluid pathways caused by deformation. This study shows that proper characterization and consideration of in-situ stress are important not only for boundary conditions of a selected site but also for the understanding of the mechanical and hydraulic behavior of fractured rocks.

Development and Its Application of a Discrete Fracture Flow Model for the Analysis of Gas-Water Transient Flow in Fractured Rock Masses Around Storage Cavern (지하저장공동 주변 불연속 암반에서의 가스-물 천이유동해석을 위한 개별균열 유동모델의 개발 및 응용)

  • 나승훈;성원모
    • Proceedings of the Korean Geotechical Society Conference
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    • 2000.11a
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    • pp.705-712
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    • 2000
  • The fluid generally flows through fractures in crystalline rocks where most of underground storage facilities are constructed because of their low hydraulic conductivities. The fractured rock is better to be conceptualized with a discrete fracture concept, rather continuum approach. In the aspect of fluid flow in underground, the simultaneous flow of groundwater and gas should be considered in the cases of generation and leakage of gas in nuclear waste disposal facilities, air sparging process and soil vapor extraction for eliminating contaminants in soil or rock pore, and pneumatic fracturing for the improvement of permeability of rock mass. For the purpose of appropriate analysis of groundwater-gas flow, this study presents an unsteady-state multi-phase FEM fracture network simulator. Numerical simulation has been also conducted to investigate the hydraulic head distribution and air tightness around Ulsan LPG storage cavern. The recorded hydraulic head at the observation well Y was -5 to -10 m. From the results obtained by the developed model, it shows that the discrete fracture model yielded hydraulic head of -10 m, whereas great discrepancy with the field data was observed in the case of equivalent continuum modeling. The air tightness of individual fractures around cavern was examined according to two different operating pressures and as a result, only several numbers of fractures neighboring the cavern did not satisfy the criteria of air tightness at 882 kPa of cavern pressure. In the meantime, when operating pressure is 710.5 kPa, the most areas did not satisfy air tightness criteria. Finally, in the case of gas leaking from cavern to the surrounding rocks, the resulted hydraulic head and flowing pattern was changed and, therefore, gas was leaked out from the cavern ceiling and groundwater was flowed into the cavern through the walls.

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