• 청정기술
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• 제25권1호
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• pp.14-18
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• 2019

여러 금속 부품을 가공하기 위하여 사용된 염화제이철 에칭 폐액은 유가금속인 니켈 등을 함유하고 있다. 본 연구에서는 식각공정을 완료한 에칭폐액을 재생하고 부산물로 나온 니켈 함유 폐액으로부터 정제하여 니켈 금속분말로 제조하는 공정을 개발하였다. 부산물인 니켈함유용액을 철 등의 불순물을 침전 제거하기 위하여 수산화나트륨 수용액을 실험을 통하여 가수분해 중화제로서 선정하였고, 이를 통하여 철 등의 불순물을 pH = 4 조건하에 침전 제거하였다. 그 후, 불순물로 잔류하는 망간 및 아연과 같은 금속이온들을 D2EHPA (Di-(2-ethylhexyl) phosphoric acid)를 사용하여 용매추출 하였다. 정제된 염화니켈은 99% 이상의 순도를 가지고 있으며, 그 후 환원제로 하이드라진을 이용하여 99% 이상의 순도와 약 150 nm의 크기를 가지는 니켈 금속분말로 제조하였다. 염화니켈 및 니켈 금속분말의 성분은 EDTA 적정법과 유도결합 플라즈마 방출분광법(inductively coupled plasma optical emission spectrometer, ICP-OES)을 이용하여 확인하였으며, 전계방사 주사전자현미경(field emission scanning electron microscope, FE-SEM), X-선 회절분석기(X-ray diffraction, XRD) 및 투과전자현미경(transmission electron microscopy, TEM)을 통하여 금속분말의 형태, 입자 크기 및 결정성과 같은 물리적 특성을 확인하였다.

• Computers and Concrete
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• 제13권3호
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• pp.325-342
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• 2014

The use of lightweight aggregate (LWA) instead of ordinary aggregate may make lightweight aggregate concrete, which possesses many advantages such as lightweight, lower thermal conductivity, and better fire and seismic resistance. Recently the developments of LWA have been focused on using industrial wastes as raw materials to reduce the use of limited natural resources. In view of this, the intent of this study was to apply Taguchi optimization technique in determining process condition for producing synthetic LWA by incorporating waste thin film transition liquid crystal displays (TFT-LCD) glass powder with reservoir sediments. In the study the waste TFT-LCD glass cullet was used as an additive. It was incorporated with reservoir sediments to produce LWA. Taguchi method with an orthogonal array L16(45) and five controllable 4-level factors (i.e., cullet content, preheat temperature, preheat time, sintering temperature, and sintering time) was adopted. Then, in order to optimize the selected parameters, the analysis of variance method was used to explore the effects of the experimental factors on the performances (particle density, water absorption, bloating ratio, and loss of ignition) of the produced LWA. The results showed that it is possible to produce high performance LWA by incorporating waste TFT-LCD glass cullet with reservoir sediments. Moreover, Taguchi method is a promising approach for optimizing process condition of synthetic LWA using recycled glass cullet and reservoir sediments and it significantly reduces the number of tests.

• Elastomers and Composites
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• 제36권2호
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• pp.79-85
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• 2001

폐고무의 증가로 인하여 환경문제가 날로 심각해지고 있다. 그러므로 효율적인 재활용을 통하여 이러한 문제를 해결하는데 많은 연구가 진행되고 있다. 본 연구에서는 탈황시스템을 이용하여 폐고무 분말의 가황 결합을 분리함으로서 기본물성을 높이는데 목적을 두었다. 폐고무분말의 입자크기에 따른 물성의 변화와 De-link 함량 증가에 따른 물성을 조사하였고 De-link를 함유한 시료를 기존 배합물에 10phr 충전하여 유변학적, 기계적 및 가교도 등의 물성을 조사하였다. 또한 광학현미경을 사용하여 표면을 확인함으로서 제품특성을 연구하였다.

• Elastomers and Composites
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• 제36권2호
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• pp.86-93
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• 2001

새로운 TPE(Thermoplastic Elastomer) 블렌드 재료로서 폐 EPDM(Ethylene Propylene Diene Monomer)분말의 사용에 따른 환경문제를 해결하고, TPE의 고부가 가치화를 위하여 PP (Polypropylene)와 폐 EPDM분말을 주원료로 하고, 동방향 이축압출기(Co-rotating Twin Screw Extruder)를 사용하여 동적가교를 이루어 TPE재료를 제조하였다. TPE 재료의 인장강도, 파단신율, 탄성율 등의 물성을 향상시킬 목적으로 스크류 조합별로 폐 EPDM/PP를 블렌드하여 기계적물성을 조사하였으며, 모폴로지를 조사하였다. 스크류 조합에서는 혼련판과 역 스크류 엘리먼트의 수가 증가할수록 블렌드물의 전단력과 체류시간이 증가하여 동적가교가 증가하였다.

• Nuclear Engineering and Technology
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• 제53권7호
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• pp.2261-2267
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• 2021

This paper evaluates the efficacy of magnesium potassium phosphate cements (MKPCs) as waste forms for the solidification of radioactive concrete powder wastes produced by the decommissioning of nuclear power plants. MKPC specimens that contained up to 50 wt% of simulated concrete powder wastes (SCPWs) were evaluated. We measured the porosity and compressive strength of the MKPC specimens, observing them using scanning electron microscopy and X-ray diffraction. The addition of SCPWs reduced the porosity and increased the compressive strength of the MKPC specimens. Struvite-K crystals were well-synthesized, and no additional crystal phase was formed. After thermal cycling and after immersion, MKPC specimens with 50 wt% SCPWs satisfied the waste-acceptance criteria (WAC) for compressive strength. Semi-dynamic leaching tests were performed using the ANS 16.1 method; the leachability indices of Cs, Co, and Sr were 11.45, 17.63, and 15.66, respectively, which also satisfy the WAC. Thus, MKPCs can provide stable matrices to immobilize radioactive concrete wastes generated by the decommissioning of nuclear power plants.

• Advances in concrete construction
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• 제13권6호
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• pp.461-470
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• 2022

Solid waste management is of great concern in today's world. An enormous amount of waste is generated from various industrial activities. Concrete production utilizing some of the potential waste materials will add to the benefit of society. These benefits will include reduction of landfill burden, improved air quality, riverbed protection due to excessive sand excavation, economical concrete production and much more. This study aims to utilize waste granite powder (GP) originating from granite industries as a sand replacement in concrete. Fine GP was collected in the form of slurry from different granite cutting industries. In this study, GP was added in an interval of ten percent as 10%, 20%, 30%, 40% and 50% by weight of sand in concrete. Mechanical assets; compressive strength, flexural strength and splitting tensile strength were prominent for control and blended mixes. Modulus of elasticity (MoE) and abrasion tests were also performed on control and blended specimens of concrete. To provide a comprehensive clarification for enhanced performance of GP prepared concrete samples, scanning electron microscopy (SEM) and X-ray diffraction (XRD) were performed. Results indicate that 30% replacement of sand by weight with GP enhances the mechanical assets of concrete and even the results obtained for 50% replacement are also acceptable. Comprehensive analysis through SEM and XRD for 30% replacement was better than control one. The performance of GP added to concrete in terms of abrasion and modulus of elasticity was far better than the control mix. A significant outcome shows the appropriateness of granite fines to produce sustainable and environmentally friendly concrete.

• Elastomers and Composites
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• 제46권4호
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• pp.318-323
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• 2011

폐타이어고무분말을 재활용하기 위하여 방수시트용 고무분말 복합체를 제조하였으며, 수지 종류와 가교제의 함량이 복합체의 기계적 특성에 미치는 영향을 고찰하였다. EPDM이 부가됨에 따라 고무분말 PE 복합체의 신장율이 3배 이상 증가하는 현상을 나타내었다. 고무분말 충전 복합체에 가교제의 농도가 증가함에 따라 복합체의 강도가 증가하였으며, 특히 재생 폴리프로필렌을 사용한 경우 3배 이상 인장강도가 현저하게 높게 나타났다. 따라서 폴리프로필렌 블렌드물로 고무분말 복합체를 제조하는 경우 신재 폴리프로필렌을 사용하는 것 보다 재생 폴리프로필렌을 사용하는 것이 기계적 특성면에서 효과적인 것으로 나타났다.

• 한국산업융합학회 논문집
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• 제23권6_2호
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• pp.1111-1117
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• 2020

In this study, the carbonation characteristics of concrete according to the mixture of OLED waste glass were evaluated. Replacement capacities of OLED waste glass were 0%, 10%, 20%, and 30% of cement, and they were named OG 0, OG 10, OG 20, and OG 30. As a result of the compressive strength test, OG 0 without replacing OLED waste glass showed high intensity until the 14th. However, the higher the replacement rate of OLED waste glass, the higher the compressive strength of 28 days. In addition, the speed of carbonation was faster with the higher the replacement rate of OLED waste glass, and the accelerated carbonation experiment was about three times faster than the natural carbonation test. In conclusion, the carbonation characteristics of OLED concrete are expected to be positive in terms of atmospheric CO2 absorption.

• 자원리싸이클링
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• 제11권2호
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• pp.45-51
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• 2002

본 연구는 수산폐기물인 폐굴껍질과 우리나라에 넓게 분포되어 있는 황토를 이용하여 응집제를 제조하기 위한 것으로서 응집제원료의 성분조사 결과, 폐굴껍질은 CaO성분이 55.43(wt%)로 가장 많이 함유되어 있었고, 황토는$ SiO_2$가 45.30(wt%)로 주성분임을 알 수 있었다. 폐굴껍질 내의 CaO순도를 높이기 위해 $900^{\circ}C$에서 2시간동안 소성 하였으며. ball mill을 사용하여 0.074 mm(200mesh)로 분쇄 하였다. 소성된 폐굴껍질 분말과 황토 분말을 각각 6:4, 7:3, 8:2, 9: 1의 비율로 혼합하여 응집제를 제조하였다 또한 제조된 응집제와 화학 소석회와의 비교실험을 통해 화학 소석회의 대체 가능성을 확인하였다.

• 방사성폐기물학회지
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• 제18권4호
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• pp.509-516
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• 2020

An important property of glass and ceramic solid waste forms is processability. Tellurite materials with low melting temperatures and high halite solubilities have potential as solid waste forms. Crystalline TiTe3O8 was synthesized through a solid-state reaction between stoichiometric amounts of TiO2 and TeO2 powder. The resultant TiTe3O8 crystal had a three-dimensional (3D) structure consisting of TiO6 octahedra and asymmetric TeO4 seesaw moiety groups. The melting temperature of the TiTe3O8 powder was 820℃, and the constituent TeO2 began to evaporate selectively from TiTe3O8 above around 840℃. The leaching rate, as determined using the modified American Society of Testing and Materials static leach test method, of Ti in the TiTe3O8 crystal was less than the order of 10-4 g·m-2·d-1 at 90℃ for durations of 14 d over a pH range of 2-12. The chemical durability of the TiTe3O8 crystal, even under highly acidic and alkaline conditions, was comparable to that of other well-known Ti-based solid waste forms.