• 제목/요약/키워드: waste oil

검색결과 530건 처리시간 0.03초

혼합폐플라스틱 열분해 왁스오일의 고급화 연구 (A Study of Upgrading of Pyrolysis Wax Oil Obtained from Pyrolysis of Mixed Plastic Waste)

  • 이경환;남기윤;송광섭;김극태;최정길
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2009년도 추계학술대회 논문집
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    • pp.321-324
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    • 2009
  • Upgrading of pyrolysis wax oil has been conducted in a continuous fixed bed reactor at $450^{\circ}C$, 1hour, LHSV 3.5/h. The catalytic degradation using HZSM-5 catalyst are compared with the thermal degradation and also was studied with a function of experimental variables. The raw pyrolysis wax oil shows relatively high boiling point distribution ranging from around $300^{\circ}C$ to $550^{\circ}C$, which has considerably higher boiling point distribution than that of commercial diesel. The product characteristic from thermal degradation shows a similar trend with that of raw pyrolysis wax oil. This means the thermal degradation of pyrolysis wax oil at high degradation temperature is not sufficiently occurred. On the other hand, the catalytic degradation using HZSM-5 catalyst relative to the thermal degradation shows the high conversion of pyrolysis wax oil to light hydrocarbons. This liquid product shows high gasoline range fraction as around 90% fraction and considerably high aromatic fraction in liquid product. Also, in the catalytic degradation the experimental variable such as catalyst amount and reaction temperature was studied.

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우라늄 정광의 용해/정제 및 핵연료 분말 가공공정에서 발생된 폐액의 처리에 관한 연구 (A Study on Treatment of Wastes from the Uranium Ore Dissolution/purification and Nuclear Fuel Powder Fabrication)

  • 정경채;황성태
    • 공업화학
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    • 제8권1호
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    • pp.99-107
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    • 1997
  • 핵연료분말 변환공정 중 우라늄 정광의 용해/정제 및 가공공정에서 발생하는 폐액의 처리에 대한 연구가 수행되었다. 우라늄 정광의 용해/정제공정에서 발생된 폐액은 pH 1 이하의 강산성으로 AUC 분말 제조공정에서 발생된 폐액 중의 우라늄을 ADU 형태로 회수한 후 발생된 2차 여액 속의 미세 ADU 입자 용해를 위해 사용된다. 2차 여액 속의 미세 ADU 입자들의 용해를 위해 용해/정제 공정의 폐액을 사용해서 pH 4로 전처리한 후, lime을 이용하여 pH 9.2로 30분 정도 반응시킬 경우 여액 중의 우라늄 농도를 3ppm 이하로 처리할 수 있었다. 가공 폐액은 미세 oil droplet들이 emulsion 형태로 발생하며, 약 300ppm의 우라늄 농도를 나타내었다. 먼저, emulsion을 파괴시키는 방법은 질산을 가하여 급속가열시키는 것이 효과적이었다. Emulsion 파괴 후 1mole NaOH를 가하여 $Na_2U_2O_7$형태로 우라늄을 회수하였으며, pH11.5에서 최적 처리조건을 나타내었으나 최종 여액 중의 우라늄 농도는 5ppm을 나타냈다. 여액 중의 우라늄 농도를 최소화하기 위해 lime으로 처리하는 방법이 연구되었으며, 가공폐액을 직접 lime 처리하기 위해 4N 질산으로 emulsion을 파괴 시킨 후, pH 1.6에서 lime을 1.5g/100ml로 반응시킬 경우 여액 중의 우라늄 농도를 1ppm까지 낮출 수 있었다. 한편, 경수로형 분말 제조공정 중 우라늄 회수공정에서 발생된 폐액 중의 미량 우라늄은 NaOH를 가하여 우라늄을 침전시킨 결과, $Na{\cdot}U{\cdot}F{\cdot}NH_4$등이 혼합된 침전물이 얻어졌으며, 여과후 상등액에서는 우라늄은 감지할 수 없었다.

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On the Improvement of the Combustibility of Waste Plastics used in Blast Furnace

  • Ban, Bong-Chan;Choi, Jin-Shik;Kim, Dong-Su
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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    • pp.751-754
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    • 2001
  • A possibility of using waste plastics as a source of secondary fuel in blast furnace has been of recent interest. The success of this process, however, will be critically dependent upon the optimization of operating systems. for instance, the supply of waste plastics must be reliable as well as economically attractive compared with conventional secondary fuels such as heavy oil, natural gas and pulverized coal. In this work, we put special importance on the improvement of the combustibility of waste plastics as a way to enhance energy efficiency in blast furnace. As experimental variables to approach this target, the effects of plastic particle size, blast temperature, and the level of oxygen enrichment were investigated using a custom-made blast model designed to simulate a real furnace. Lastly, the combustion efficiency of the mixture of waste plastics and pulverized coal was tested. The observations made from these experiments led us to the conclusion that with the increase of both blast temperature and the level of oxygen enrichment, and with the decrease of particle size, the combustibility of waste PE could be improved at a given distance from tuyere. Also it was found that the efficiency of coal combustion decreased with the addition of plastics; however, the combustion efficiency of mixture could be comparable at longer distance from tuyere.

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Tribology 관점에서 생분해성 유압작동유 실적용 평가에 관한 연구 (Study on vehicle application of biodegradable hydraulic oils from the point of tribological evaluation technology)

  • 나병철;김진용;서준호
    • 한국윤활학회:학술대회논문집
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    • 한국윤활학회 2004년도 학술대회지
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    • pp.367-371
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    • 2004
  • Bio-degradable hydraulic oil using polyolester base oil is formulated for the applications of heavy duty hydraulic machineries. It has proved quality and market price competitiveness by assessment of reliability test in vehicle manufacturer and specific vehicle related institute. Contribution of bio-degradable oil keep the working environment clean and increase export competitiveness in European market. Leakage or waste of mineral types of hydraulic oils in heavy duty machineries causes pollution of river, ocean, underground water. Drinkable-water pollution is serious problem in Europe. In some European countries, using bio-degradable hydraulic oils become an obligation in heavy duty machineries. New product of bio-degradable oils satisfy the European regulations(OECD 302B) and shows excellent performance in compare with European products.

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LDPE 반회분식 촉매열분해에서 조업조건이 반응 특성에 미치는 영향 (Effects of Reaction Conditions on the Performance of Catalytic Pyrolysis of LDPE in a Semi-Batch Reactor)

  • 나정걸;임철현;최휘경;정수현
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2006년도 추계학술대회
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    • pp.79-82
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    • 2006
  • Fueled by ballooning oil prices, waste plastics are now regarded as being cheap and abundant renewable sources, removing their stigma of dirty wastes Catalytic pryolysis of plastics in liquid phase allows recovery of light fuel oil as well as green treatment of polymerics wastes, and therefore significant efforts have been devoted to this research field. In this study, catalytic Pyrolysis of LDPE was carl ied out in semi-batch reactor which equipped a unit of separation and recirculation. The effect of react ion conditions were examined by analyzing liquid oil yield and carbon number distribution of products

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개량된 이탄과 유기성 슬러지를 이용한 유류오염토양 분해제 개발 (Development of Degradation Agent for Oil Contaminated Soil using Modified Peat Moss and Organic Sludge)

  • 김수홍;이창한;서정호
    • KSBB Journal
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    • 제25권1호
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    • pp.103-107
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    • 2010
  • Oil degradation agent was developed with organic sludge and modified peat moss (MPM) to recover oil contaminated soil. Waste sludge discharged from wastewater treatment plant of chemical plant in Ulsan National Industrial Park was used as organic sludge, and MPM was purchased. Organic sludge was adequate to use as growth medium for microorganism, the surface of MPM had porous structure which could enhance the cultivation condition of oil degradation microorganisms. Water contents and TPH variation with time were observed to investigate the degradation capacity of developed degradation agent. Water contents were rapidly decreased with higher contents of MPM, however, in case of TPH, high MPM content decreased the degradation capacity. Therefore, it was recommended that the content of MPM was controlled to below 10% in degradation agent as mixing organic sludge with MPM.

Extraction and Determination of Phytosterols from Corn Oil Foots

  • Kim, Sang-Ho;Park, Sang-Hoo;Ahn, Byung-Goo;Yi, Jeong-Sang;Park, Moo-Sin;Lee, Byeong-Ryong;Kim, Kweon
    • Archives of Pharmacal Research
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    • 제13권3호
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    • pp.282-284
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    • 1990
  • By saponification and extraction of corn oil foots abandoned as waste during oil refining, a mixture of phytosterols was obtained, and its major components were determined as .betha.-sitosterol, campesterol and stigmasterol by gas chromatographic analysis. The mixture is very cheap and regarded as an excellent substrate for direct fermentation of C-17 keto steroid intermediate for various steroid pharmaceuticals.

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음식물류폐기물 제로화 주거단지 구축 시나리오별 비용 및 환경효과 분석 (Analysis of Greenhouse Gas Reduction according to Different Scenarios of Zero Food Waste Residential Buildings)

  • 오정익;윤은주;박이레;김영민
    • 대한환경공학회지
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    • 제38권7호
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    • pp.353-363
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    • 2016
  • 본 연구에서는 공동주택 단지에서의 음식물류폐기물을 수거 이송하여 대용량처리시설에 자원화 혹은 재활용하는 기존 방식과 발생지인 공동주택 내에서 처리하는 제안 방식을 가상하여 차량수거방식, 자동집하방식, 자동집하처리방식, 소규모분산처리방식, 오수처리연계방식으로 시나리오를 설정하고 각 시나리오별 초기 투자비용, 석유 사용량, 이산화탄소 배출량, 음식물류폐기물 처리 운영비용, 입주자 부담 관리비를 비교 분석하였다. 기존처리 방식에 비해 제안하는 소규모분산처리방식이 초기 투자비용, 연간 석유사용량, 이산화탄소 배출량이 가장 낮았으며 적용, 도입 가능성이 높았다. 음식물류폐기물 처리 운영비용은 기존 처리방식과 비교하여 1톤당 334,465원(약 91%)이 절감되며 세대 당 월 1,500원인 입주자 부담 관리비용 또한 902원으로 약 40% 절감이 가능하다고 분석되었다. 각 시나리오별 초기 투자비용과 석유사용량, 이산화탄소 배출량을 비교한 결과, 초기 투자비용이 낮은 처리방식이 연료 사용량과 이산화탄소 발생량도 낮은 경향을 나타내었다. 초기 투자비용과 석유사용량, 이산화탄소 배출량이 가장 낮은 시나리오는 소규모분산처리방식이며 가장 높은 시나리오는 오수처리연계방식이었다. 연구의 공간적 범위를 공동주택 단지로 설정할 때 소규모분산처리방식이 음식물류폐기물 제로화 모델로서 가장 적합한 방식으로 판단된다.

폐윤활유의 아크 열분해 생성물 및 잔류물 특성 연구 (Characterization of Product Gas and Residues from Arc Cracking of Waste Lubricating Oil)

  • 김인태;김정국;송금주;서용칠;김준형
    • 자원리싸이클링
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    • 제8권5호
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    • pp.34-43
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    • 1999
  • 폐윤활유로부터 활융가능한 연료기체를 생산하기 위해 개발한 전기아크를 이용한 분해자치에서 폐윤활유를 아크 분해할 때의 기체생성물과 잔류물의 특성을 연구하였다. 생성되는 기체는 수소(35~40%)와 아세틸렌(13~20%), 에틸렌(3~4%), 그 외 탄산수소들로 이루어져 있으며, 저온 열분해에서는 주요 생성물인 일산화탄소의 함량은 매우 적었다. 발생기체의 발열량은 11,000~13,000kacl/kg으로 기체 연료로의 활용성이 충분하여 유해기체도 배출기준치 이하였다. 액상 잔류물을 GC/MS로 분석한 결과 폐유의 고분자량 탄화수소물들이 저분자량 탄화수소물과 수소로 분해되었음을 알 수 있었고, 전지아크에 의한 고온 열분해이므로 탈수소반응이 주 반응임을 확인할 수 있었다. 고상 잔류물인 검댕이 평균 입경은 $10.3\mu\;extrm{m}$이며, 탄소 함량은 60%이상이고, 중금속 성분은 0.01ppm 이하였는데 전제과정을 거치 재활용이 가능할 것으로 생각된다.

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Experience in Combustion of Various Dewatered Sludges at a Commercial-Scale Fluidized Bed Incinerator

  • Gu, Jae-Hoi;Yoo, Byung-Sang;Yeo, Woon-Ha;Seo, Yong-Chil;Lee, Jea-Keun
    • 한국에너지공학회:학술대회논문집
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    • 한국에너지공학회 2000년도 추계 학술발표회 논문집
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    • pp.91-96
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    • 2000
  • A commercial-scale Fluidized Bed Incinerator(FBI) to treat dewatered sludges has been developed by Jindo Corporation, Korea, as one of the governmental R&D project during 1990 to 1997. The FBI plant was constructed at Kunsan city and fully in operation after finishing the successful test-burn period since June 1998. The company now has a capability of the design, construction and operation of commercial FBI plants. This paper introduces the experiences of design and operation of Kunsan FBI plant, which has the capacity of 60 ton/day and incinerates various sludges from waste water treatment facilities and liquid waste such as waste oil or waste solvent.

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