• Carbon letters
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• v.19
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• pp.66-71
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• 2016

The development of nanostructured functional materials derived from biomass and/or waste is of growing importance for creating sustainable energy-storage systems. In this study, nanoporous carbonaceous materials containing numerous heteroatoms were fabricated from waste coffee grounds using a top-down process via simple heating with KOH. The nanoporous carbon nanosheets exhibited notable material properties such as high specific surface area (1960.1 m² g⁻¹), numerous redox-active heteroatoms (16.1 at% oxygen, 2.7 at% nitrogen, and 1.6 at% sulfur), and high aspect ratios (>100). These unique properties led to good electrochemical performance as supercapacitor electrodes. A specific capacitance of ~438.5 F g⁻¹ was achieved at a scan rate of 2 mV s⁻¹, and a capacitance of 176 F g⁻¹ was maintained at a fast scan rate of 100 mV s⁻¹. Furthermore, cyclic stability was achieved for over 2000 cycles.

• Journal of Advanced Marine Engineering and Technology
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• v.40 no.10
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• pp.894-898
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• 2016

Solution plasma is a unique method which provides a direct discharge in solutions. It is one of the promising techniques for various applications including the synthesis of metallic/non-metallic nanomaterials, decomposition of organic compounds, and the removal of microorganism. In the context of nanomaterial syntheses, solution plasma has been utilized to produce carbon nanoparticles and metallic-carbon nanoparticle systems. The main purpose of this study was to synthesize nickel nanoparticles embedded in a matrix of carbon particles by solution plasma in one-step using waste vegetable oil as the carbon source. The experimental setup was done by simply connecting a bipolar pulsed power generator to nickel electrodes, which were submerged in the waste vegetable oil. Black powders of the nickel nanoparticles-embedded carbon (NiNPs/Carbon) particles were successfully obtained after discharging for 90 min. The morphology of the synthesized NiNPs/Carbon was investigated by a scanning electron microscope, which revealed a good dispersion of NiNPs in the carbon-particle matrix. The X-ray diffraction of NiNPs/Carbon clearly showed the co-existence of crystalline Ni nanostructures and amorphous carbon. The crystallite size of NiNPs (through the Ni (111) diffraction plane), as calculated by the Scherrer equation was found to be 64 nm. In addition, the catalytic activity of NiNPs/Carbon was evaluated by cyclic voltammetry in an acid solution. It was found that NiNPs/Carbon did not show a significant catalytic activity in the acid solution. Although this work might not be helpful in enhancing the activity of the fuel cell catalysts, it is expected to find application in other processes such as the CO conversion (by oxidation) and cyclization of organic compounds.

• Journal of Powder Materials
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• v.12 no.2 s.49
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• pp.112-116
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• 2005

In the present study, the focus is on the analysis of carbothermal reduction of oxide powder prepared from waste WC/Co hardmetal by solid carbon under a stream of argon for the recycling of the WC/Co hard-metal. The oxide powder was prepared by the combination of the oxidation and crushing processes using the waste $WC-8 wt.\%Co$ hardmetal as the raw material. This oxide powder was mixed with carbon black, and then this mixture was carbothermally reduced under a flowing argon atmosphere. The changes in the phase structure and gases discharge of the mixture during carbothermal reduction was analysed using XRD and gas analyzer. The oxide powder prepared from waste $WC-8wt.\%Co$ hardmetal has a mixture of $WO_{3} and CoWO_{4}$. This oxide powder reduced at about $850^{\circ}C$, formed tungsten carbides at about $950^{\circ}C$, and then fully transformed to a mixed state of tungsten carbide (WC) and cobalt at about $1100^{\circ}C$ by solid carbon under a stream of argon. The WC/Co composite powder synthesized at $1000^{\circ}C$ for 6 hours from oxide powder of waste $WC-8wt.\%Co$ hardmetal has an average particle size of $0.3 {\mu}m$.

• Journal of the Korean Recycled Construction Resources Institute
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• v.10 no.2
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• pp.176-183
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• 2022

High-purity waste CNTs were mixed into cement mortar to manufacture heat-generating concrete that can use low voltage power, and carbon fiber and waste cathode materials were also used improve the conductivity of the mortar. The waste CNTs were analyzed to have a high concentration of multi-walled CNTs, and substituted liquid type waste CNTs were used during mortar mixing in order to increase dispersibility. The temperature change of the mortar with CNT was evaluated when using electric power below DC 24 V in order to utilize a small self-generation facility such as small solar power module when the mortar heats up and to minimize electromagnetic waves. When liquid-type waste CNTs were applied and a voltage of DC 24 V was introduced, it rose to 60 ℃ in a 200 × 100 × 50 mm mortar block specimen. The field applicability of self heating mortar with waste CNT was sufficient and also the amount of change in heat energy in mortar with liquid type waste CNT, carbon fiber and waste cathode materials is more effective compared to it of other variables.

• Resources Recycling
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• v.31 no.6
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• pp.3-17
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• 2022

The cement industry, which is an energy-intensive and high carbon dioxide emission industry, requires strategy for carbon neutrality and sustainable development. Most domestic cement companies are generating electricity by waste heat recovery system to improve energy efficiency during cement processes; however, few studies exist on recycling of energy related to this. Certain countries with high cement production researched on modifying the conventional waste heat recovery system to maximize waste heat recovery using various methods such as applying the Rankine cycle depending on the temperature, comparing working fluids, applying two or more Rankine cycles, and combining with other industries. In this study, we reviewed the research direction for energy efficiency improvement by summarizing waste heat recovery and utilization methods in the domestic and overseas cement industries.

• Journal of the Korean Wood Science and Technology
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• v.52 no.2
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• pp.118-133
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• 2024

The sapwood portion of fast-growing teak is mostly ignored due to its inferior quality. One of the possibilities for utilizing sapwood waste is to convert it into activated carbon that has good adsorption capabilities. The raw materials used in this research were sapwood of 14-year-old fast-growing teak sapwood (FTS) waste, which was taken from three trees from community forests in Wonosari, Gunungkidul, Yogyakarta Special Region. FTS waste was taken from the bottom of the tree up to a height of 1.3 m. The activation process is conducted with an activation temperature of 750℃, 850℃, and 950℃. The heating duration consists of three variations: 30 min, 60 min, and 90 min. The quality evaluation parameters of activated carbon include yield, moisture content, volatile matter content, ash content, fixed carbon content, adsorption capacity of benzene, adsorption capacity of methylene blue, and adsorption capacity of iodine. The results showed that the activated carbon produced had the following quality parameters: yield of 75.61%; moisture content of 1.27%; volatile matter content of 9.98%; ash content of 5.43%; fixed carbon content of 84.58%; benzene absorption capacity of 8.58%; methylene blue absorption capacity of 87.73 mg/g; and iodine adsorption capacity of 948.19 mg/g. It can be concluded that activated carbon from FTS waste has good iodine adsorption, which fulfilled the SNI 06-3730-1995 quality standard. Due to the iodine adsorption ability of FTS waste activated carbon, the conversion of FTS waste to activated carbon is categorized as a potential method to increase the value of this material.

• Journal of the Korean Recycled Construction Resources Institute
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• v.7 no.1
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• pp.22-28
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• 2019

Cement is a basic material for the construction industry and it requires high temperature sintering when manufacturing cement. $CO_2$ emissions from raw materials and fuels are recognized as new environmental problems and efforts are underway to reduce them. Techniques for reducing $CO_2$ in concrete are also recommended to use blended cement such as blast furnace slag or fly ash. In addition, the construction waste generated in the dismantling of concrete structures is recognized as another environmental problem. Thus, various methods are being implemented to increase the recycling rate. The purpose of this study is to utilize the inorganic raw materials generated during the dismantling of the structure as a raw material for the low carbon type cement binder. Such as, waste concrete powder, waste cement block, waste clay brick and waste textile as raw materials for low carbon type cement binder. From the research results, low carbon type cement binder was manufactured from the raw material composition of waste concrete powder, waste cement block, waste clay brick and waste textile.

• Resources Recycling
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• v.31 no.5
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• pp.52-58
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• 2022

Silicon carbide powder was prepared from carbon black and silicon recovered from waste solar panels. In the solar power generation market, the number of crystalline silicon modules exceeds 90%. As the expiration date of a photovoltaic module arrives, the development of technology for recovering and utilizing silicon is very important from an environmental and economic point of view. In this study, silicon was recovered as silicon carbide from waste solar panels: 99.99% silicon powder was recovered through purification from a 95.74% purity waste silicon wafer. To examine the synthesis characteristics of SiC powder, purified 99.99% silicon powder and carbon powder were mixed and heat-treated (1,300, 1,400 and 1,500 ℃) in an Ar atmosphere. The characteristics of silicon and silicon carbide powders were analyzed using particle size distribution analyzer, XRD, SEM, ICP, FT-IR, and Raman analysis.

• Journal of Energy Engineering
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• v.27 no.1
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• pp.33-39
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• 2018

In this paper, we reviewed briefly about the barrier materials for the radioactive waste disposal. The primary concept of the radioactive waste disposal is safety. The goal of the radioactive waste management is to assure that the environment is not adversely affected and also public. There are a wide variety of materials are available for the radioactive waste disposal or storage. Among those coal fly ash is one of the significant materials are used as a barrier material. Here we reported, the Calcium sulfo aluminate (CSA) from coal fly ash is effectively suitable for the radioactive waste disposal. This is one of the ways of utilization of waste and manufactured the valuable materials for future indeeds.

• Korean Journal of Materials Research
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• v.32 no.9
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• pp.369-378
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• 2022

The recycling of solid waste materials to fabricate carbon-based electrode materials is of great interest for low-cost green supercapacitors. In this study, porous carbon foam (PCF) was prepared from waste floral foam (WFF) as an electrode material for supercapacitors. WFF was directly carbonized at various temperatures of 600, 800, and 1,000 ℃ under an inert atmosphere. The WFF-derived PCF (C-WFF) was found to have a specific surface area of 458.99 m²/g with multi-modal pore structures. The supercapacitive behavior of the prepared C-WFF was evaluated using a three-electrode system in a 6 M KOH aqueous electrolyte. As a result, the prepared C-WFF as an active material showed a high specific capacitance of 206 F/g at 1 A/g, a rate capability of 36.4 % at 20 A/g, a specific power density of 2,500 W/kg at an energy density of 2.68 Wh/kg, and a cycle stability of 99.96 % at 20 A/g after 10,000 cycles. These results indicate that the C-WFF prepared from WFF could be a promising candidate as an electrode material for high-performance green supercapacitors.