• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.20 no.2
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• pp.151-160
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• 2022

The sorption of Eu on MX-80 bentonite in Na-Ca-Cl solutions is investigated at a molal proton concentration (pH_m) range of 3 to 10 and an ionic strength (I) range of 0.1 to 6 m (mol·kgw^-1). The sorption equilibrium of Eu on MX-80 is achieved within 14 to 21 d at I = 0.1 and 6 m. The sorption distribution coefficient (K_d) values of Eu for MX-80 increase as pH_m increases from 3 to 6 for all I values, and they are independent of pH_m between 8 and 10 at I ≥ 0.5 m. Meanwhile, at I = 0.1 m, the K_d value at pH_m = 10 is slightly lower than those at pH_m = 8 and 9. The K_d values are not affected by the I values between 0.5 m and 6 m, whereas the K_d value at I = 0.1 m is greater than those at I ≥ 0.5 m, except at pH_m = 10. A two-site protolysis nonelectrostatic surface complexation and cation exchange sorption model is applied to the Eu sorption data for I ≤ 4 m, and the equilibrium constants of the sorption reactions are estimated.

• Resources Recycling
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• v.28 no.5
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• pp.3-18
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• 2019

Due to the increasing demand for clean energy, the consumption of lithium ion batteries (LIBs) is expected to grow steadily. Therefore, stable supply of lithium is becoming an important issue globally. Commercially, most of lithium is produced from the brine and minerals viz., spodumene, although various processes/technologies have been developed to recover lithium from other resources such as low grade ores, clays, seawaters and waste lithium ion batteries. In particular, commercialization of such recycling technologies for end-of-life LIBs being generated from various sources including mobile phones and electric vehicles(EVs), has a great potential. This review presents the commercial processes and also the emerging technologies for exploiting minerals and brines, besides that of newly developed lithium-recovery-processes for the waste LIBs. In addition, the future lithium-supply is discussed from the technical point of view. Amongst the emerging processes being developed for lithium recovery from low-grade ores, focus is mostly on the pyro-cum-hydrometallurgical based approaches, though only a few of such approaches have matured. Because of low recycling rate (<1%) of lithium globally compared to the consumption of lithium ion batteries (56% of lithium produced currently), processing of secondary resources could be foresighted as the grand opportunity. Considering the carbon economy, environment, and energy concerns, the hydrometallurgical process may potentially resolve the issue.

• Resources Recycling
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• v.16 no.5
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• pp.19-24
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• 2007

Reefs are the marine structure that can give resting, inhabiting, feeding and nursing spaces for a variety of fishes. Usually artificial reefs are made of cement and steels respectively in Japan as well as in Korea. However since resources deficiency has been getting serious, other materials are taken into consideration for the basic bodies of artificial reefs. About 300 thousand tons of waste agricultural plastic films are generated every yew in Korea, but no effective recycling techniques have been developed. In this sense, artificial reefs made of waste agricultural plastic films are the most representative symbol of the recycled products in the Resource Recycling Era. In particular, since these reefs could be made of the semi-cleaned waste agricultural plastic films that still contain high portion of soil, it is very environmentally friendly not only in manufacturing process but also in using under water. Furthermore they have some evident advantages as follows; 1) high fish swarming effect 2) good initial attachment of the marine growths 3) extremely low corrosion to brine 4) easy adjustment of the gravity 5) economical manufacture, transportation and jettison 6) excellent safety to ecosystem caused by lower elution of toxic substances 7) good recyclable property after application and so on.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.21 no.6
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• pp.355-366
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• 2009

In the present study, fuel cell driven ground source heat pump system is applied to a large community building and performance of the heat pump system is computationally analyzed. Conduction heat transfer between brine pipe and ground is analyzed by TEACH code to predict the performance of heat pump system. Predicted COP of the heat pump system and the energy cost were compared with variation of the location of the objective building the water saturation rate of soil and the driven powers of heat pump system. Significant reduction of energy cost can be accomplished by employing the fuel cell driven heat pump system in comparison with the late-night electricity driven system. It is due to the low electricity production cost of fuel cell system and the application of recovered waste heat generated during electricity production process to the heating of large community building.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.26 no.2
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• pp.72-78
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• 2014

In a cold chain, the refrigerator is also employed for defrosting, by using an electric heater, which consumes 15% of the power for the system operation. In this study, the condensation heat of the refrigerant was suggested as the heat source of defrosting heat, instead of that from an electric defrost heater. The heat for defrosting was stored to a phase change material (PCM, NMP : $52^{\circ}C$) in thermal storage, and was periodically supplied to the evaporator by a circulation loop of brine. As a result, a defrost time by the PCM was obtained that was less than or equal to that by the electric heater. Moreover, power consumption during defrosting was saved by up to 99% of that of the electric heater.