• 한국염색가공학회지
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• 제18권1호
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• pp.1-9
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• 2006

Treatment of PET fabrics with alkali, chitosan and Al-mordanting has been carried out and the role of the chitosan coating in the dyeing process was clarified. The pre-treatment was effectively evaluated differences in dyeing behavior between its treated and untreated PET fabrics using wood of Caesalpinia sappan. The pre-treated on PET fabrics has been examined by SEM and evidence for the presence of chitosan sought using a air permeability test. Similar colour fastness by computer color matching(CCM) obtained on both untreated and pre-treated PET fabrics. The pre-treated PET was found to be of a deeper hue to that of its dyed untreated PET and, despite of its better colour depth, the wash fastness of the pre-treated dyeing was comparable to that of its dyed untreated PR. The application of chitosan or mordanting reveled that pre-treatment imparted to the PET additional functional groups that were available for coordination with the Brazilin.

• 한국대기환경학회지
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• 제12권4호
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• pp.421-428
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• 1996

In this study, in order to make up its draw-back in Cu-ZSM-5 catalytic system, some of transition metals or alkaline earth metals were cocation-exchanged in Cu-ZSM-5. Among various cocation-ion-exchanged ZSM-5 catalysts, Mg/Cu-ZSM-5 has been found the most active and durable in NOx reduction even at high oxygen content as well as at the presence of water vapor. The role of Mg in ZSM-5 is supposed to prevent the dealumination of aluminum ions in super-cage even at harsh hydro-thermal conditions, and also it seems to stabilize the Cu ions in the structure. In order to prepare commercially available catalysts, Mg/Cu-ZSM-5 catalysts were wash-coated on the surface of honeycomb type monolith, and tested in terms of catalytic activities. As a result, it was found that the catalyst prepared bt the wash-coating showed satisfactorily high NOx conversion for the practical use in SCR process.

• 한국수소및신에너지학회논문집
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• 제21권6호
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• pp.500-506
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• 2010

The metal monolith catalyst coated with 15wt% Ni/$MgAl_2O_4$ is applied to the natural gas steam reforming for hydrogen production. To address the improvement of adherence between metal monolith and catalyst coating layer, the pre-calcination temperature as well as the coating conditions of $Al_2O_3$ sol are optimized. When the Fe-Cr alloy monolith is pre-calcined at $900^{\circ}C$ for 6 h, $Al_2O_3$ layer was formed uniformly on the entire surface of the metal substrate. It is seen that the formation of $Al_2O_3$ layer on the monolith surface is essential for the uniform coating of $Al_2O_3$ sol onto the monolith substrate. The monolith catalyst coated with 10wt% $Al_2O_3$ sol shows high $CH_4$ conversion and good thermal stability as compared with the monolith catalyst without $Al_2O_3$ sol coating under severe reaction conditions with high GHSV of 30,000 $h^{-1}$ at $700^{\circ}C$. In addition, the metal monolith catalyst shows higher catalytic activity and better thermal conductivity than 15wt% Ni/$MgAl_2O_4$ pellet catalyst.

• 대한치과기공학회지
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• 제34권2호
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• pp.129-134
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• 2012

Purpose: This study was conducted to investigate the colors of zirconia and veneered ceramics according to the build-up method of veneer porcelain. Methods: The samples were divided into three groups: a group for which a liner was applied to the zirconia surface and dentine coating was built up and burned (Cz1), a group for which the dentine coating was directly built up and burned (Cz2), and a group for which the samples were wash-burned with dentine coating and a dentine coating was built up and burned again (Cz3). The the colors were measured with a Spectrophoto-meter. Results: The average $L^*$ value of the Cz3 group was the highest among the groups at $59.1{\pm}0.5$ (P<0.05), followed by Cz2 at $57.5{\pm}0.8$ and Cz1 at $56.6{\pm}1.3$. The $a^*$ value of Cz3 was negative at $-0.0{\pm}0.0$ and the $a^*$ values of Cz2 and Cz1 were positive at $0.2{\pm}0.1$ and $0.4{\pm}0.0$, respectively (P<0.05). The $b^*$ of Cz1 was the highest at $11.2{\pm}0.6$, followed by Cz3 at $10.8{\pm}0.5$ and Cz2 at $10.5{\pm}0.8$ (P<0.05). Conclusion: Compared to other experimental groups, the Cz3 groups showed the brightest colors with high brightness and relatively low green and yellow levels.

• 대한화장품학회지
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• 제46권1호
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• pp.57-65
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• 2020

세정 과정에서 물에 의한 단백질 소실을 차폐막을 통해서 방지 하고자 먼저 모발 내부의 물 거동 경로를 파악하였다. 이를 위해서 소수성을 가지는 건강한 모발과, 모발 내부는 정상이지만 표면의 최외곽 지질층에서 18-methyleicosanoic acid (18-MEA)만 소실시켜 친수성이 된 모발과, 다시 표면에 18-MEA를 결합시킨 회복모를 이용해서 모발 수분의 거동을 파악하였다. 모발에 열을 가할 때 일어나는 수분 증발에 따른 질량 변화를 관찰한 결과 표면이 소수성인 모발들은 39 s와 151 s의 두개의 시간 상수로 감소하였다. 이에 반해 표면이 친수성으로 변한 손상 모발에서는 83 s의 하나의 빠른 시간 상수로 감소함을 확인하였는데, 이는 모발 내부에 있는 비결합과 결합 수분들이 외곽으로 빠져나올때 모발 표면에 소수성 막이 없음으로써 바로 용출됨을 반증한다. 따라서 세정과정에서 모발 내부의 단백질 용출을 효율적으로 방지하기 위해서는 모발 표면을 소수성 코팅하여 물분자의 거동을 저지시킬 필요가 있을 것이라는 가정한 결과 친수성 polyethylene glycol (PEG)를 코팅한 경우 179 ㎍/mL의 단백질이 용출한데 반해서 소수성 polydimethylsiloxane (PDMS)를 코팅한 모발은 보다 적은 148 ㎍/mL를 용출하였으며, 표면을 소수성 및 친수성으로 코팅하여 모발 내부 단백질을 검량하여 비교하였다. 마침내 소수성 차폐막이 세정 과정에서 모발 단백질 소실을 방어하는 방법이 됨을 확인하였고, 이 소수성 지표를 lateral force microscopy (LFM) 값으로 환산하여 정리하였다. 마침내 이 연구 결과물은 세정 과정에서 발생하는 단백질 소실을 소수성 코팅막을 부여함으로써 막을 수 있는 모발 세정제품 개발에 기여할 수 있다.

• 대한치과기공학회지
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• 제31권4호
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• pp.15-23
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• 2009

The aim of this study was to evaluate the bond strength of using a Au bonding agent applied on cp-Ti and nonprecious metal-gold-ceramic system. Metallic frameworks(diameter: 5mm, height: 20mm)(N=56, n=7per group) cast in Ni-Cr alloy, Co-Cr alloy and cp-Ti were obtained using acrylic templates and airborne particle abraded with $110{\mu}m$ aluminum oxide. Au bonding agent was applied on wash opaque firing as intermediate layer. SEM and SEM/EDS line profile were performed on the cutting the cross-section of the metal substrate-porcelain with intermediate Au coating. Groups were tested using shear bond strength(SBS) testing at 0.5mm/min. The mean SBS values for the ceramic-Au layer-metal combination were significantly higher than those ceramic-metal combination. While ceramic-Au layer-cp-Ti combinations failed to increase bond strength instead of using a titanium bonding porcelain. The appication of using Au intermediate layer significantly improve the bond strength combination with metal-ceramic system.

• 산업기술연구
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• 제26권A호
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• pp.189-197
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• 2006

Water shortage as well as water control problems including urban flood and drought have led to developing technologies for rainwater utilization in order to provide a sustainable water supply. However, relatively few works have been done to improve the water quality during rainwater utilization. Therefore, in this study, the characteristics of rainwater were examined in terms of pollutant concentrations and outflow rate. A experimental rain and roof model($1m{\times}1m$) were produced to evaluate wash-off properties of pollutants. And rainfall intensity were standardized in 10 mm/hr, a experimental model roof catchment surface were coated in $TiO_2$ photocatalyst. Samples of runoff rainwater collected from a experimental model were analyzed for physicochemical parameters such as Turbidity, Suspended Solid, EC. The results show that the first flush of rainwater contains substantial amount of contaminants that potentially pollute the whole rainwater. Surface treatment of roof catchment area using $TiO_2$ photocatalyst allowed a better runoff property of rainwater because of its improved hydrophilicity.

• 한국의류학회지
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• 제29권7호
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• pp.997-1007
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• 2005

The textile finishing methods utilizing chitosan have been mostly focused on the applications in the improvement of the dyeing of cotton fabrics, or the improvement of hand of the cotton or wool fabrics. On the other hand, it Is difficult to find the application examples in the synthetic fiber fabrics including polyester and nylon fabrics. The aim of this study is to improve the stiffness and the poor wash fastness of the fabrics treated only with chitosan. We tried to improve the softness by employing chitosan and polyurethane mixture solution and to prevent the detachment of the chitosan from the fabric. The treatment was applied to cotton, polyester, and nylon fabrics. The change of the properties of the treated fabrics were investigated. The optimum finishing condition was sought by changing the mixture ratio of the chitosan/PU(polyurethane) solutions. The adjusted ratios of the chitosan/PU solutions were 1 : 0, 1 : 0.25, 1 : 0.5, and 1 : 2 during the mixture solution preparation. Using the KES(Kawabata Evaluation System), the physical and mechanical properties of the finished fabric specimens were analyzed, and hand values of the specimens were calculated through the use of translational formulas. According to the chemical composition of the fibers, chitosan solution or chitosan/PU mixture exhibited wide range of coating effect. Since the chitosan acid solution has high polarity, the bonding force with the cotton fibers is high. By the appropriate addition of PU in the chitosan treatment of cotton, KOSHI and HARI values of the fabric improved. The air permeability of the chitosan/PU treated cotton fabric specimen improved, resulting in the highest value at the mixture of chitosan : PU=1:0.25.

• 융합정보논문지
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• 제7권3호
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• pp.37-46
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• 2017

본 연구는 소방공무원들의 구취자각 유무를 파악하고 구취에 관련된 요인을 알아보기 위하여 대전지역 소방공무원 241명을 대상으로 설문조사를 실시한 결과 다음과 같은 결과를 얻었다. 첫째, 흡연량과 음주량이 높은 경우 구취를 더 자각하고 있었고 전신질환을 가진 경우 구취를 모두 자각하고 있었으며 스트레스가 심할수록 구취를 더 자각하고 있었다. 둘째, 잇솔질 3회 집단, 잇솔질 시간 1~2분 집단, 혀닦기를 안하는 집단, 구강보건교육경험 없는 집단이 구취를 가장 높게 자각하고 있었다. 셋째, 설태량이 '많음', 음식이 '잘낌', 건조감을 '느낌' 집단에서 다른 집단들에 비해 구취를 더 자각하고 있었다. 넷째, 구취자각 유무에 관련된 요인을 확인한 결과 연령, 설태량, 건조감이 구취 자각 유무에 영향을 미치는 것으로 나타났다. 따라서 한국 소방공무원의 구취자각 유무 실태와 관련요인에 대해 파악할 수 있었고 소방공무원들의 구취예방과 구강증상을 해결하기 위한 프로그램의 개발과 올바른 구강건강관리를 위한 교육의 필요성이 강조되었다.

• 한국응용과학기술학회지
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• 제36권1호
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• pp.153-164
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• 2019

본 연구에서는 기존 상용 SCR 촉매보다 비표면적, 경량성 및 온도 응답성이 우수한 SCR 촉매의 개발을 목적으로 바나듐과 텅스텐의 함량과 바인더의 첨가량을 달리하여 Metal foam 형태의 지지체에 코팅하여 SCR 촉매를 제조한 후, 실험실 규모의 마이크로 상압반응기상에서 공간속도별로 NOx 저감 성능을 측정하였다. 촉매의 특성은 Porosimeter, SEM(scanning electron microscope), EDX(energy dispersive x-ray spectrometer) 및 ICP(inductively coupled plasma), 실체현미경(Stereomicroscope) 기기를 이용하여 분석하였다. 연구 결과 NOx 저감 성능은 공간속도가 증가할수록 감소하였고, 바나듐과 텅스텐의 함량이 3.5 wt.% 일 때 가장 우수한 것으로 확인하였다. 또한, 바인더 첨가량이 많을수록 NOx 저감 성능이 감소하는 것으로 나타났는데, 이는 촉매 표면상의 활성점 수가 바인더에 의해 점유되어 감소된 것에 따른 것으로 판단된다. 또한 표면 코팅 상태 분석을 통하여 바인더의 첨가량이 적절히 조절 되어야 함을 알 수 있었다.