• 제목/요약/키워드: wall charge

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Active Materials for Energy Conversion and Storage Applications of ALD

  • 신현정
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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    • pp.75.2-75.2
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    • 2013
  • Atomic layer deposition (ALD), utilizing self-limiting surface reactions, could offer promising perspectives for future efficient energy conversion devices. The capabilities of ALD for surface/interface modification and construction of novel architectures with sub-nanometer precision and exceptional conformality over high aspect ratio make it more valuable than any other deposition methods in nanoscale science and technology. In the context, a variety of researches on fabrication of active materials for energy conversion applications by ALD are emerging. Among those materials, one-dimensional nanotubular titanium dioxide, providing not only high specific surface area but also efficient carrier transport pathway, is a class of the most intensively explored materials for energy conversion systems, such as photovoltaic cells and photo/electrochemical devices. The monodisperse, stoichiometric, anatase, TiO2 nanotubes with smooth surface morphology and controlled wall thickness were fabricated via low-temperature template-directed ALD followed by subsequent annealing. The ALD-grown, anatase, TiO2 nanotubes in alumina template show unusual crystal growth behavior which allows to form remarkably large grains along axial direction over certain wall thickness. We also fabricated dye-sensitized solar cells (DSCs) introducing our anatase TiO2 nanotubes as photoanodes, and studied the effect of blocking layer, TiO2 thin films formed by ALD, on overall device efficiency. The photon convertsion efficiency ~7% were measured for our TiO2 nanotubebased DSCs with blocking layers, which is ~1% higher than ones without blocking layer. We also performed open circuit voltage decay measurement to estimate recombination rate in our cells, which is 3 times longer than conventional nanoparticulate photoanodes. The high efficiency of our ALD-grown, anatase, TiO2 nanotube-based DSCs may be attributed to both enhanced charge transport property of our TiO2 nanotubes photoanode and the suppression of recombination at the interface between transparent conducting electrode and iodine electrolytes by blocking layer.

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압력배출구를 설치한 전동화 차량 배터리 시험실의 내부 폭압 평가 (Evaluation of Internal Blast Overpressures in Test Rooms of Elcetric Vehicles Battery with Pressure Relief Vents)

  • 방승기;신진원;정현진
    • 한국지열·수열에너지학회논문집
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    • 제18권3호
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    • pp.7-18
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    • 2022
  • Secondary batteries used in electric vehicles have a potential risk of ignition and explosion. Various safety measures are being taken to prevent these risks. A numerical study was performed using a computational fluid dynamics code on the cases where pressure relief vents that can reduce the blast overpressures of batteries were installed in the through-compression test room, short-circuit drop test room, combustion test room, and immersion test room in facilities rleated to battery used in electric vehicles. This study was conducted using the weight of TNT equivalent to the energy release from the battery, where the the thermal runaway energy was set to 324,000 kJ for the capacity of the lithium-ion battery was 90 kWh and the state of charge (SOC) of the battery of 100%. The explosion energy of TNT (△HTNT) generally has a range of 4,437 to 4,765 kJ/kg, and a value of 4,500 kJ/kg was thus used in this study. The dimensionless explosion efficiency coefficient was defined as 15% assuming the most unfavorable condition, and the TNT equivalent mass was calculated to be 11 kg. The internal explosion generated in a test room shows the very complex propagation behavior of blast waves. The shock wave generated after the explosion creates reflected shock waves on all inner surfaces. If the internally reflected shock waves are not effectively released to the outside, the overpressures inside are increased or maintained due to the continuous reflection and superposition from the inside for a long time. Blast simulations for internal explosion targeting four test rooms with pressure relief vents installed were herein conducted. It was found that that the maximum blast overpressure of 34.69 bar occurred on the rear wall of the immersion test room, and the smallest blast overpressure was calculated to be 3.58 bar on the side wall of the short-circuit drop test room.

Comparison of Catalytic Activity for Methanol Electrooxidation Between Pt/PPy/CNT and Pt/C

  • Lee, C.G.;Baek, J.S.;Seo, D.J.;Park, J.H.;Chun, K.Y.
    • 전기화학회지
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    • 제13권4호
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    • pp.240-245
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    • 2010
  • This work explored the catalytic effect of Pt in multi-wall carbon nanotube and poly-pyrrole conductive polymer electrocatalysts (Pt/PPy/MWCNT). A home-made Pt/PPy/MWCNT catalyst was first evaluated by comparing its electrochemical active surface area (ESA) with E-Tek commercial catalysts by cyclic voltammetry in $H_2SO_4$ solution. Then, the methanol oxidation currents of Pt/PPy/MWCNT and the hydrogen peaks in $H_2SO_4$ solution were serially measured with microporous electrode. This provided the current density of methanol oxidation based on the ESA, allowing a quantitative comparison of catalytic activity. The current densities were also measured for Pt/C catalysts of E-Tek and Tanaka Precious Metal Co. The current densities for the different catalysts were similar, implying that catalytic activity depended directly on the ESA rather than charge transfer or electronic conductivity.

Low Cost Driving System for Plasma Display Panels by Eliminating Path Switches and Merging Power Switches

  • Lee, Dong-Myung;Hyun, Dong-Seok
    • Journal of Power Electronics
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    • 제7권4호
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    • pp.278-285
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    • 2007
  • Recently, plasma display panels (PDP) have become the most promising candidate in the market for large screen size flat panel displays. PDPs have many merits such as a fast display response time and wide viewing angle. However, there are still concerns about high cost because they require complex driving circuits composed of high power switching devices to generate various voltage waveforms for three operational modes of reset, scan, and sustain. Conventional PDP driving circuits use path switches for voltage separation and a scan switch to offer a scan voltage for reset and scan operations, respectively. In addition, there exist reset switches to initialize PDPs by regulating the wall charge conditions with ramp shaped pulses, which means the necessity of specific power devices for the reset operation. Because power for the plasma discharge accompanied by a large current is transferred to a panel via path switches, high power rating switches are used for path switches. Therefore, this paper proposes a novel low-cost PDP driving scheme achieved by not only eliminating path switches but also merging the function of reset switches into other switches used for sustain or scan operations. The simulated voltage waveforms of the proposed topology and experimental results implemented in a 42-inch panel to demonstrate the validity of using a new gate driver that merges the functions of power switches are presented.

AC PDP 화질 향상을 위한 개선된 ADS 고속 구동법에 대한 연구 (Improved High Speed Addressing Driving Method for Increment of the Image Quality for AC PDPs)

  • 임종식;김현석;김준엽
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2003년도 추계학술대회 논문집 전기물성,응용부문
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    • pp.229-232
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    • 2003
  • AC PDP의 ADS 추동 방식은 구동 방법이 간단하여 구현하기가 용이할 뿐만 아니라 가장 안정적인 구동 방식으로 널리 사용되고 있다 [1]. 그러나 ADS 구동 방식은 주사선의 수가 늘어남에 따라 어드레싱에 필요한 시간이 증가하게 되고 유지방전 구간에 할애할 시간이 상대적으로 감소하게 되어 휘도가 저하되게 되는 문제점을 갖고 있다. 이러한 문제를 해결하기 위하여 어드레싱 시간을 최소화하기 위한 고속 어드레싱 기술에 대한 연구가 계속하여 진행되고 있다 [2-10]. 본 논문에서는 고속 구동 시에 나타나는 불안정한 어드레싱으로 인한 화질의 저하문제를 해결하기 위한 개선된 ADS 구동파형을 제시한다. 초기화 구간의 Reset 파형은 어드레싱 추간의 특성에 중요한 영향을 미치게 되는데, Reset 구간에서 생성된 벽전하를 어드레싱 방전구간 동안 지속적으로 유지되게 함으로서 어드레싱 방전전압을 줄이고 안정적인 어드레싱이 유지될 수 있도록 하였다. 본 논문에서는 Priming Effect의 영향이 급격히 감소하는 80us 이후, 벽전하의 생성을 돕는 Wall Charge Acceleration Pulse를 적용함으로서 불안정한 어드레싱 문제를 해결할 수 있는 방법을 제시하였고 휘도의 불균등화로 인한 화질 저하의 문제를 해결하였다.

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마이크로 전기영동 소자의 제작과 유로 면 특성에 따른 전기삼투 및 전기영동 효과 (Fabrication of electro phoresis microchips and effects of channel surface properties)

  • 김민수;조승일;이국녕;김용권
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2003년도 추계학술대회 논문집 전기물성,응용부문
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    • pp.286-289
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    • 2003
  • We investigated the influence of the properties of substrate material on the separation efficiency in microchip electrophoresis. We fabricated the various microchips and studied separation efficiency in microchannels composed of a single material such as quartz, glass, polydimethylsiloxane (PDMS), and polymethylmetha crylate (PMMA), as well as hybrid micro channels composed of different materials. New fabrication process for glass chip was suggested and some treatment is added to improve fabrication process in other chip. Separation efficiency was compared by measuring migration times and bandwidths of EOF and analytes in each microchip. The efficiency is the function of migration time, which is affected by the electroosmotic flow (EOF), and bandwidth of an analyte. EOF is highly dependent upon the characteristics of a microchannel wall surface. Migration time was more reproducible in silica chips than that of PDMS chip and more band broadening was observed in the microchip composed of hybrid material due to non-uniformity of surface charge density at the walls of the channel.

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새로운 등가회로모델을 이용한 AC PDP의 유지방전시의 벽전하 특성 분석 (Wall Charge Characteristic Analysis during the Sustain Period Using an New Equivalent Circuit Model for AC PDPs)

  • 김준엽;임종식
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2003년도 추계학술대회 논문집 전기물성,응용부문
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    • pp.174-177
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    • 2003
  • 본 논문에서는 AC PDP의 유지방전구간에서의 인가전압에 따른 방전전류, 공간전압, 벽전하 등의 변화를 새로운 AC PDP를 위한 등가회로모델을 사용하여 효율적이고 간편하게 시뮬레이션 한 결과를 소개한다. 벽전하의 정확한 분석은 안정적이고 효율적인 AC PDP의 구동 방법을 개발하기 위해 계속 연구, 보고 되어 왔지만, 인가되는 전압의 변화에 따른 시간적인 셀 내부의 변화를 빠르고 편리하게 분석하고 이해하는데 효과적인 방법은 제시되지 못하였다. 본 논문에서는 AC PDP의 전극간 물리적인 특성을 고려하여 3개의 직렬 커패시터와 1개의 병렬 커패시터, 2개의 싸이리스터를 사용하여 AC PDP를 위한 등가회로모델을 구성하여 제시하였다. 제안된 등가회로모델은 SPICE와 같은 표준 회로시뮬레이션 툴에 손쉽게 적용가능하며, 이러한 방법으로 분석된 패널내의 전류, 공간전압, 벽전하의 동특성을 소개하였다. 등가회로모델을 이용한 시뮬레이션 결과는 실험을 통한 측정 결과와 비교하여 그 정확성을 검증하였다. 인가전압의 시간적 변화의 따른 유입전류 및 셀 내의 전압 및 전하의 분포를 손쉽고 정확하게 시뮬레이션 할 수 있는 본 AC PDP의 등가회로모델은 AC PDP의 특성을 이해하는 데에 중요한 도구가 될 것이며 효율적인 구동 방식의 개발 및 분석 등에 널리 활용될 수 있을 것이다.

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AC PDP에서의 최적의 페닝 방전가스 혼합비에 대한 휘도와 효율 향상에 관한 연구 (A Study of Penning gas for the improvement of luminance and luminous efficiency in AC plasma display panel)

  • 이재경;함정국;변기량;강정원;황호정
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 하계학술대회 논문집 Vol.4 No.2
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    • pp.1074-1077
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    • 2003
  • 우리는 AC-PDP에서 휘도와 효율을 향상시키기 위하여 Ne-Xe(4%)와 He(7)-Ne(3)-Xe(3%)에 소량의 Ar 또는 Kr를 첨가하여 최적의 페닝 방전가스 혼합비를 연구하였다. 우리는 이것을 증명하기 위해 효율과 Q-V 방법을 이용하여 벽전하를 계산하였으며, 2차원 시뮬레이션에서의 결과값과 비교하였다. 200 Torr 압력에서 He-Ne-Xe 또는 Ne-Xe에 소량의 Ar(0.01-0.1%) 또는 Kr(0.01-0.1%)을 첨가시켰을 때, 우리는 20% 이상의 휘도의 증가와 25% 이상의 효율 증가를 발견하였고, 또한 벽전하도 25% 이상의 증가를 보였다. 400 Torr 압력에서 He-Ne-Xe-Kr(0.005%)에 소량의 Ar(0.005-0.1%)를 첨가시켰을 때는 8% 이상의 휘도의 증가와 18% 이상의 효율 증가, 12% 이상의 벽전하 증가를 확인하였다. 결론적으로 이 결과는 He, Ne, Ar, Kr 사이에 추가적인 페닝효과가 휘도와 효율을 향상시켰다는 것을 보여준다.

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Antimicrobial Peptides (AMPs): Peptide Structure and Mode of Action

  • Park, Yoon-Kyung;Hahm, Kyung-Soo
    • BMB Reports
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    • 제38권5호
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    • pp.507-516
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    • 2005
  • Antimicrobial peptides (AMPs) have been isolated and characterized from tissues and organisms representing virtually every kingdom and phylum. Their amino acid composition, amphipathicity, cationic charge, and size allow them to attach to and insert into membrane bilayers to form pores by 'barrel-stave', 'carpet' or 'toroidal-pore' mechanisms. Although these models are helpful for defining mechanisms of AMP activity, their relevance to resolving how peptides damage and kill microorganisms still needs to be clarified. Moreover, many AMPs employ sophisticated and dynamic mechanisms of action to carry out their likely roles in antimicrobial host defense. Recently, it has been speculated that transmembrane pore formation is not the only mechanism of microbial killing by AMPs. In fact, several observations suggest that translocated AMPs can alter cytoplasmic membrane septum formation, reduce cell-wall, nucleic acid, and protein synthesis, and inhibit enzymatic activity. In this review, we present the structures of several AMPs as well as models of how AMPs induce pore formation. AMPs have received special attention as a possible alternative way to combat antibiotic-resistant bacterial strains. It may be possible to design synthetic AMPs with enhanced activity for microbial cells, especially those with antibiotic resistance, as well as synergistic effects with conventional antibiotic agents that lack cytotoxic or hemolytic activity.

2 성분 혼합물을 작동유체로 사용하는 태양열 집열기용 히트파이프의 실험적 연구 (An Experimental Study of a Heat pipe with Binary Mixture Working Fluid for Solar Collector)

  • 정의국;부준홍;정원복
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2003년도 추계학술대회
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    • pp.13-18
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    • 2003
  • Heat pipes with binary mixture fabricated and tested for applications where condenser temperature is in a range of $10^{\circ}C$ to $130^{\circ}C$. The pipe materials 8.0 mm O.D. cupper tube and the working fluids are ethanol-water mixtures. The total length of test of the heat pipe was 1710mm in which evaporator section was 1570mm, adiabatic section was 50mm and condenser section was 90mm. Mixing ratios of ethanol and water could be variable in mole fraction. Temperature of condenser section was $10^{\circ}C$, $80^{\circ}C$ and $130^{\circ}C$. Heat pipe performance experimental study was accomplished with change of mixing ratio in these temperatures. The fill charge ratio was 20% of the heat pipe volume. Wick structure was woven-wire and method of experimental work was that thermal load was increased 20W step until the heat pipe wall temperature reached at $150^{\circ}C$. Results were following: At coolant $10^{\circ}C$ and $130^{\circ}C$, mixing ratio that have beat thermal performance was 0.8M+ and at coolant $80^{\circ}C$, was 0.3 ${\sim}$ 0.5 M+.

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