• Title/Summary/Keyword: volumetric composition

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Preparation of LaGaO3 Based Oxide Thin Film on Porous Ni-Fe Metal Substrate and its SOFC Application

  • Ju, Young-Wan;Matsumoto, Hiroshige;Ishihara, Tatsumi;Inagaki, Toru;Eto, Hiroyuki
    • Journal of the Korean Ceramic Society
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    • v.45 no.12
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    • pp.796-801
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    • 2008
  • $LaGaO_3$ thin film was prepared on Ni-Fe metal porous substrate by Pulsed Laser Deposition method. By the thermal reduction, the dense $NiO-{Fe_3}{O_4}$ substrate is changed to a porous Ni-Fe metal substrate. The volumetric shrinkage and porosity of the substrate are controlled by the reduction temperature. It was found that a thermal expansion property of the Ni-Fe porous metal substrate is almost the same with that of $LaGaO_3$ based oxide. $LaGaO_3$ based electrolyte films are prepared by the pulsed laser deposition (PLD) method. The film composition is sensitively affected by the deposition temperature. The obtained film is amorphous state after deposition. After post annealing at 1073K in air, the single phase of $LaGaO_3$ perovskite was obtained. Since the thermal expansion coefficient of the film is almost the same with that of LSGM film, the obtained metal support LSGM film cell shows the high tolerance against a thermal shock and after 6 min startup from room temperature, the cell shows the almost theoretical open circuit potential.

Food and feeding habits of the large cyprinid fishes in the upper Blue Nile River, Ethiopia

  • Marishet Teshome;Minwyelet Mingist;Elias Dadebo;Degsera Aemro
    • Fisheries and Aquatic Sciences
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    • v.26 no.5
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    • pp.344-354
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    • 2023
  • Food and feeding habits of large cyprinid fishes (Labeobarbus intermedius, Labeobarbus nedgia, and Labeo forskalii) had been investigated in the upper Blue Nile River, Ethiopia. Four sampling sites were selected and specimens were sampled during the post-rainy (November 2016) and dry (March 2017) seasons by gillnets of 6 cm, 8 cm, 10 cm, 12 cm, and 14 cm mesh sizes. Totally 401 fishes were collected and about 30.4% (122) of the samples were documented with empty guts and 279 (69.6%) of them were with non-empty guts. The whole contents of all non-empty gut specimens were taken, labeled, and preserved using a 5% formaldehyde solution for further analysis. In the laboratory, gut contents were examined and identified using compound and stereo microscopes. The relative importance of different food items in the diet compositions was analyzed using a frequency of occurrence and volumetric analysis. During the post-rainy season, insects and phytoplankton were mostly ingested as food items. However, during the dry season, phytoplankton was the most important food item in the diet of all cyprinid fishes of the river. Based on current study results, L. intermedius and L. nedgia might be omnivores in their diet but Labeobarbus forskalii seemed to be detritivorous.

A Basic Study on Physical Method for Preventing Recombination of Gas Product from the Decomposition of Ammonium Carbamate (암모니움 카바메이트 분해 시 생성된 가스의 재결합 방지를 위한 물리적 방법의 기초연구)

  • Chun, Minwoo;Yoon, Cheon Seog;Kim, Hongsuk
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.41 no.10
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    • pp.639-647
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    • 2017
  • This basic study is focused on the physically removal method of carbon dioxide from the decomposition of ammonium carbarmate to prevent the recombination of ammonium salts. A basic visual experimental set-up was designed and constructed to observe the recombination phenomena from the proper composition of ammonia gas, carbon dioxide gas, and compressed air dilution gas. To quantify the recombination phenomena, a simple device was designed to measure the weight change under severe cases for three different tube sizes. The temperature and pressure in the visual tube and the volumetric flow rates of the nitrogen dilution gas were studied and the conditions to avoid recombination were analyzed according to mean free path theory. Diffusivity values based on the Chapman-Enskog theory were calculated from the experimental data. These value may serve as an index for the prevention of recombination.

재조합 단백질 생산을 위한 식물세포 고농도 배양과 기체조성에 따른 영향

  • Lee, Sang-Yun;Jeon, Su-Hwan;Min, Byeong-Hyeok;Heo, Won;Jo, Gyu-Heon;Kim, Dong-Il
    • 한국생물공학회:학술대회논문집
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    • 2000.11a
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    • pp.425-428
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    • 2000
  • To enhance the productivity of recombinant protein, ${\beta} -glucuronidase(GUS)$, by transgenic Nicotiana suspensions, perfusion culture was carried out in a 5-L stirred tank bioreactor. Maximum cell density of 20.0 gDCW/L was obtained and GUS activity was noticeably affected by medium composition, such as salt concentration. Effect of headspace purging by $CO_2-enriched$ air was also investigated. Aeration of $CO_2(5%)-enriched$ air with 0.2 vvm significantly promoted the cell growth in lag pahse and increased volumetric GUS activity from 0.69 U/mL to 5.76 U/mL. In contrast, aeration of $CO_2(5%)-enriched$ air with 0.1 vvm did not affect the cell growth but enhanced the GUS acitivity from 3.24 to 5.25 U/mL at the 4th day.

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A Study of Lorentz-Meutzner's Two Evaporator Refrigeration System Using Alternative Refrigerant Mixtures (대체혼합냉매를 사용하는 Lorentz-Meutzner의 이중 증발기 냉동 시스템의 성능에 관한 연구)

  • Park, Y.M.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.4 no.2
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    • pp.123-136
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    • 1992
  • A preliminary thermodynamic design model of two-evaporator refrigerator/freezer system is constructed. This system is based on Lorentz-Meutzner cycle using refrigerant mixtures. This model screens alternative refrigerant (R32, R125, R143a, R22, R134a, R152a, R124, R142b, R123) mixtures to select the best performance-giving refrigerant mixtures and its composition for the system. Also, it estimates the effects of cooling temperatures of intercoolers, evaporator's area ratio, cooling load ratio on the performance of the system. The COP of the system ranges from 1.4 to 1.6, which is superior to that of the single evaporator system charged with R12 by 13% to 29%. Among 15 mixtures, R22/R123, R143a/R123, R32/R142b, and R32/R124 (in the order of high COP) are most recommendable. For the case of R22/R123, R22 mass fraction more than 0.5(Load Ratio=1.0) or 0.7(Load Ratio=0.33) is recomended in order to replace R12 without reduction in volumetric capacity when keeping the compressor as the same one. COP has the highest value with X(R22)=0.7 and 0.8, respectively. For the case of R143a/R123, in the similar manner, mass fraction of R143a is more than 0.5 or 0.6 while best performance occurs at X(R143a)=0.8. Higher temperature intercooler is more important for the performance of the system than lower temperature intercooler. The area ratio of evaporators is roughly proportional to load ratio of the evaporators.

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Actual Production Conditions of Fermented Soybean Products on the Level of Farmhouses (장류가공사업 농가의 장류 생산실태에 관한 연구)

  • 김은미;정금주;이승교;원향례
    • The Korean Journal of Community Living Science
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    • v.14 no.3
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    • pp.89-98
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    • 2003
  • To assess the actual status of businesses selling fermented soybean products, this study surveyed 130 Farmhouse style small size soybean sauce processing sites supported by the Rural Development Administration nationwide. The sex composition of the businesses representatives of 2% male and 98% female showed that a farmhouse soybean processing business is generally operated by rural women as a non-filming business. The percentage of co-worked sites was 71.2 and that of sites with permits was 39.2. The main products were meju, doenjang, and kanjang. Total production volume was found to be 523 tons, 256 tons, and 135 k$\ell$s, respectively. The number of years of experience of the manufacturers of the kanjang and doenjang was found to be 25.7 on average which shows that long-experienced, skilled manufacturers are participating in this project. The traditional measuring unit differed greatly depending on the region. This difference in the measuring unit of soybeans resulted in a large difference in the volume of doenjang and kanjang produced Per Province. For one kg of raw soybeans, the weight of Doenjang produced also varied from 2.14 kg in the Gyeongbuk area to 1.62 kg in Jeju. In the aspect of salt use, 1.75 $\ell$ (translated by volumetric unit 0.704 due) of salt pet kg of meju, in Jeju, was the highest in Korea. Government supervision would be beneficial in the areas of raw material products, standardization of measuring units and production methods, organization and operation of a conference for the different groups of producers, and in construction of a nationwide database.

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Development and Performance Evaluation of Liquid-type Chemical Additive for Warm-Mix Asphalt (중온화 액상형 화학첨가제 개발과 이를 적용한 중온 아스팔트의 성능 평가)

  • Baek, Cheolmin;Yang, Sunglin;Hwang, Sungdo
    • International Journal of Highway Engineering
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    • v.15 no.4
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    • pp.107-116
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    • 2013
  • PURPOSES: The liquid-type chemical warm-mix asphalt (WMA) additive has been developed. This study evaluates the basic properties of the additive and the mechanical properties of WMA asphalt and mixture manufactured by using the newly developed chemical additive. METHODS: First, the newly developed WMA additive was applied to the original asphalt by various composition of additive components and dosage ratio of additive. These WMA asphalt binders were evaluated in terms of penetration, softening point, rotational viscosity, and PG grade. Based on the binder test results, one best candidate was chosen to apply to the mixture and then the mechanical properties of WMA mixture were evaluated for moisture susceptibility, dynamic modulus, and rutting and fatigue resistance. RESULTS : According to the binder test, WMA asphalt binders showed the similar properties to the original asphalt binder except the penetraion index of WMA additive was a little higher than original binder. From the Superpave mix design, the optimum asphalt content and volumetric properties of WMA mixture were almost the same with those of hot mix asphalt (HMA) mixture even though the production and compaction temperatures were $30^{\circ}C$ lower for the WMA mixture. From the first set of performance evaluation, it was found that the WMA mixture would have some problem in moisture susceptibility. The additive was modified to improve the resistance to moisture and the second set of performance evaluation showed that the WMA mixture with modified chemical additive would have the similar performance to HMA mixture. CONCLUSIONS : Based on the various laboratory tests, it was concluded that the newly developed chemical WMA additve could be successfully used to produce the WMA mixture with the comparable performance to the HMA mixture. These laboratory evaluations should be confirmed by applying this additive to the field and monitoring the long-term performance of the pavement, which are scheduled in the near future.

Enhanced Si based negative electrodes using RF/DC magnetron sputtering for bulk lithium ion batteries

  • Hwang, Chang-Muk;Park, Jong-Wan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.277-277
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    • 2010
  • The capacity of the carbonaceous materials reached ca. $350\;mAhg^{-1}$ which is close to theorestical value of the carbon intercalation composition $LiC_6$, resulting in a relatively low volumetric Li capacity. Notwithstanding the capacities of carbon, it will not adjust well to the need so future devices. Silicon shows the highest gravimetric capacities (up to $4000\;mAhg^{-1}$ for $Li_{21}Si_5$). Although Si is the most promising of the next generation anodes, it undergoes a large volume change during lithium insertion and extraction. It results in pulverization of the Si and loss of electrical contact between the Si and the current collector during the lithiation and delithiation. Thus, its capacity fades rapidly during cycling. We focused on electrode materials in the multiphase form which were composed of two metal compounds to reduce the volume change in material design. A combination of electrochemically amorphous active material in an inert matrix (Si-M) has been investigated for use as negative electrode materials in lithium ion batteries. The matrix composited of Si-M alloys system that; active material (Si)-inactive material (M) with Li; M is a transition metal that does not alloy with Li with Li such as Ti, V or Mo. We fabricated and tested a broad range of Si-M compositions. The electrodes were sputter-deposited on rough Cu foil. Electrochemical, structural, and compositional characterization was performed using various techniques. The structure of Si-M alloys was investigated using X-ray Diffractometer (XRD) and transmission electron microscopy (TEM). Surface morphologies of the electrodes are observed using a field emission scanning electron microscopy (FESEM). The electrochemical properties of the electrodes are studied using the cycling test and electrochemical impedance spectroscopy (EIS). It is found that the capacity is strongly dependent on Si content and cycle retention is also changed according to M contents. It may be beneficial to find materials with high capacity, low irreversible capacity and that do not pulverize, and that combine Si-M to improve capacity retention.

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Characteritics of Toluene and $H_2S$ Removal in a Biotrickling filters with Plastic & Woodchip composite Media (복합플라스틱계 담체를 이용한 Biotrickling filters의 Toluene과 황화수소 제거특성)

  • Yim, Dong-Won;Kong, Sung-Ho
    • Journal of Soil and Groundwater Environment
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    • v.12 no.2
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    • pp.37-46
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    • 2007
  • This study developed composition-plastic media with woodchips and plastic as main materials, and examined the performance of media. Compared to the existing commercial media, the media had similar performance in removal efficiency and microbes attaching characteristic, and was evaluated that they are distinguished from economic side. Performance test of media was conducted to examine the removal capacity of toluene and hydrogen sulfide in a gas stream by using a lab-scale biotrickling filter systems packed with them. At a volumetric loading of $1.5\;m^3/hr$ with inlet concentration 260 ppm and empty bed residence time (EBRT) 42s, the toluene removal efficiency was shown over 90%, and the maximum elimination capacity of toluene in the biotrickling filter was $77g/m^3{\cdot}hr$. Effective co-treatments of $H_2S$ and Toluene were observed in the lab-scale biotrickling filters. The maximum elimination capacity of $H_2S$ was $100\;g-S/m^3{\cdot}hr$. Up to 100 ppm, the concentration of $H_2S$ did not have an effect on toluene removal efficiency, but the removal efficiency of toluene decreased with increasing inlet $H_2S$ concentration.

Evaluation on the Possibility of Preparation of Nanosized Alumina Powder under W/O Emulsion Method Using Homogenizer (Homogenizer를 사용한 W/O 에멀젼법하에 나노크기 알루미나 분체 제조 가능성 평가)

  • Lee, Yoong;Hahm, Yeong-Min
    • Applied Chemistry for Engineering
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    • v.21 no.5
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    • pp.488-494
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    • 2010
  • Under W/O emulsion method using a homogenizer, ${\alpha}$-alumina powder was prepared to evaluate the effects of experimental conditions on its properties, such as particle shape, extent of aggregation, average particle size and distribution. The experimental parameters were the change of type, quantity and composition of emulsifiers as well as the change of O : W volumetric ratio and agitation rate. As results, in the case of the use of single surfactant of SP80, sphere-like particles could be prepared and the average particle size was hardly affected by the agitation speed more than 16000 rpm regardless of SP80 quantity used. When the extent of aggregation among sphere-like particles prepared using $HLB_m$ = 5 of [SP80 & TW80] was compared with that prepared using SP80 at the same vol% surfactant and agitation speed, the former showed more or less low aggregation phenomena and average particle size was slightly reduced. In addition, the fraction of nano-sized particles with low aggregation was increased by the use of 0.1 vol% n-butanol, as a co-surfactant, with $HLB_m$ = 5 of [SP80 & TW80].