• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.160.1-160.1
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• 2014

Using a density functional theory calculation including van der Waals (vdW) corrections, we report that $H_2$ adsorption in a cubic-crystalline microporous metal-organic framework (MOF-5) leads to volume shrinkage, which is in contrast to the intuition that gas adsorption in a confined system (e.g., pores in a material) increases the internal pressure and then leads to volumetric expansion. This extraordinary phenomenon is closely related to the vdW interactions between MOF and $H_2$ along with the $H_2$-$H_2$ interaction, rather than the Madelung-type electrostatic interaction. At low temperatures, $H_2$ molecules adsorbed in the MOF-5 form highly symmetrical interlinked nanocages that change from a cube-like shape to a sphere-like shape with $H_2$ loading, helping to exert centrosymmetric forces and hydrostatic (volumetric) stresses from the collection of dispersive interactions. The generated internal negative stress is sufficient to overcome the stiffness of the MOF-5 which is a soft material with a low bulk modulus (15.54 GPa).

• International Journal of Naval Architecture and Ocean Engineering
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• v.11 no.1
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• pp.462-473
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• 2019

The effects of the location and dimension of the gate, location, and volume of the feeder, application of a chill, chill volume, and heating method of the feeder with respect to the effect of the mold-designing technologies on the defect status of the products are described. It is possible to increase the solidification time of the feeder by heating feeder. Furthermore, the pressure generated from the feeder is imposed on a product, and this decreases the generation of shrinkage porosities. In this study, two types of gating and feeding systems had been proposed: the bottom L-type junctions and the top L-type junctions. Additionally, solidification behaviors, such as solidification time, shrinkage porosities, weight percentage of chill system to product, hot spot, and solidification time ratio (=Solidification time of feeder/solidification time of product), are extensively analyzed by using commercial casting simulation software. Based on the solidification behaviors, reasonable mold design, feeding system, critical feeder heating temperature, and solidification time ratios are proposed in the sand casting process for the fabrication of carrier housing in order to reduce the casting defects and to increase the recovery rate.

• Restorative Dentistry and Endodontics
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• v.27 no.2
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• pp.135-141
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• 2002

Objectives : The aim of this study is to evaluate the effect of light intensity variation on the polymerization rate of composite resin using IB system (the experimental equipment designed by Dr. IB Lee) by which real-time volumetric change of composite can be measured. Methods : Three commercial composite resins [Z100(Z1), AeliteFil(AF), SureFil(SF)] were photopolymerized with Variable Intensity Polymerizer unit (Bisco, U.S.A.) under the variable light intensity (75/150/225/300/375/450mW$^2$) during 20 sec. Polymerization shrinkage of samples was detected continuously by IB system during 110 sec and the rate of polymerization shrinkage was obtained by its shrinkage data. Peak time(P.T.) showing the maximum rate of polymerization shrinkage was used to compare the polymerization rate. Results : Peak time decreased with increasing light intensity(p<0.05). Maximum rate of polymerization shrinkage increased with increasing light intensity(p<0.05). Statistical analysis revealed a significant positive correlation between peak time and inverse square root of the light intensity (AF:R=0.965, Zl:R=0.974, SF:R=0.927). Statistical analysis revealed a significant negative correlation between the maximum rate of polymerization shrinkage and peak time(AF:R=-0.933, Zl:R=-0.892, SF:R=-0.883), and a significant positive correlation between the maximum rate of polymerization shrinkage and square root of the light intensity (AF:R=0.988, Zl:R=0.974, SF:R=0.946). Discussion and Conclusions : The polymerization rate of composite resins used in this study was proportional to the square root of light intensity Maximum rate of polymerization shrinkage as well as peak time can be used to compare the polymerization rate. Real-time volume method using IB system can be a simple alternative method to obtain the polymerization rate of composite resins.

• Computers and Concrete
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• v.19 no.5
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• pp.579-588
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• 2017

Creep and shrinkage are the main types of volume change with time in concrete. These changes cause deflection, cracking and stresses that affect durability, serviceability, long-term reliability and structural integrity of civil engineering infrastructure. Although laboratory test may be undertaken to determine the deformation properties of concrete, these are time-consuming, often expensive and generally not a practical option. Therefore, relatively simple empirically design code models are relied to predict the creep strain. This paper reviews the accuracy of creep and shrinkage predictions of reinforced concrete (RC) shear walls structures strengthened with carbon fibre reinforced polymer (CFRP) plates, which is characterized by a widthwise varying fibre volume fraction. This review is yielded by three commonly used international "code type" models. The assessed are the: CEB-FIP MC 90 model, ACI 209 model and Bazant & Baweja (B3) model. The time-dependent behavior was investigated to analyze their seismic behavior. In the numerical formulation, the adherents and the adhesives are all modelled as shear wall elements, using the mixed finite element method. Several tests were used to demonstrate the accuracy and effectiveness of the proposed method. Numerical results from the present analysis are presented to illustrate the significance of the time-dependency of the lateral displacements and eigenfrequencies modes.

• Journal of the Korean Recycled Construction Resources Institute
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• v.6 no.2
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• pp.87-93
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• 2018

The use of high-strength concrete in construction have been increasing steadily. However, high-strength concrete has a low water-binder ratio, and the problems such as cracks due to hydration heat and shrinkage during the hydration process at the early age. Recently, as a method to reduce the shrinkage of concrete, study of internal curing has carried out according to increasing about interest about it. In this study, the effect of compressive strength on the curing condition(drying, moist, water) was investigated by using artificial lightweight aggregate(LWA) in high strength and high volume mortar. As a result of autogenous shrinkage, the effect of shrinkage reduction was enhanced depending on the increasing of LWA replacement. According to the curing condition, the results of compressive strength showed the different trend. The compressive strength has increased on the drying and moisture condition and decreased on the water condition.

• Journal of the Korea Concrete Institute
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• v.24 no.3
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• pp.233-240
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• 2012

Hybrid SHCC is being researched actively for its excellent performance in controlling macro and micro cracks using macro and micro fibers, respectively. However, a significant autogenous shrinkage of SHCC is expected since it possesses high unit cement volume in its mix proportion, resulting in autogenous shrinkage cracks. Therefore, this study was performed to evaluate mechanical property of shrinkage-reducing type hybrid SHCC mixed together with steel fiber and PE fiber with excellent micro/macro crack controlling performance. In order to evaluate mechanical property of shrinkage-reducing type hybrid SHCC, replacement ratios of 0% and 10% of expansive admixture and water to binder ratios of 0.45, 0.3, and 0.2 were considered as variables. Then, shrinkage, compressive, flexural, and direct tensile tests were performed. The test results showed that mix proportion with W/B 0.3 significantly improved mechanical performance by using 10% replacement of expansive admixture.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.773-776
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• 2008

Restraining cracks on concrete structures can be the basic condition to improve the durability, so in this research, the resistibility on the drying shrinkage of concrete structures in the long period was being confirmed and as the reason of this shrinkage, the density of minute textures was being analyzed using a wooden prototype of a full scale produced with ready-mixed concrete and agents of glycol which can be used as a surfactant. As result of those tests, PFB technology can reduce the drying shrinkage by approximately $-100{\sim}200{\times}10^{-6}$ on a wooden prototype of a full scale and can also reduce the pore volume as the obstruction to the movement of gas or liquid by approximately $2.4{\sim}3.5$% so that PFB technology can be used to assure the resistibility on the drying shrinkage.

• Journal of the Korean Recycled Construction Resources Institute
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• v.7 no.4
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• pp.367-374
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• 2019

Drying shrinkage in the hardened cement is known to change in volume by decreasing the moisture content in the hardened body, and it is known that the higher the W / C and the higher the content of the paste, the larger the drying shrinkage. In the case of ECC, more drying shrinkage occurs compared to concrete, since it does not contain coarse aggregate. Since ECC is an important material for tensile performance, the effect of restrained tensile stress on mechanical tensile behavior should be considered. The purpose of this study is to analyze the effect of stress caused by restraint on the tensile behavior of ECC. The mechanical properties of the specimens were tested by uniaxial tension tests with different restraints. As a result, the difference of tensile behavior according to restraint stress was observed and the cause was analyzed.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.18 no.1
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• pp.31-41
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• 2020

We studied the anisotropic shrinkage and deformation characteristics of large size sintered bodies in the manufacturing of glass-ceramic composite wasteform. We used uranium-bearing waste, generated from the treatment of spent uranium catalyst. Sintered specimens were prepared in several forms, comprising a circular disk, and a quarter disk in several diameters of up to 40 cm. Regardless of form or size, the sintered bodies had high isotropic shrinkage when they were fabricated using green bodies prepared at 60 MPa. The average anisotropy rate and average shrinkage rate were 1.6%, and 37.4%, respectively. We confirmed that the glass-ceramic composite wasteform in a large scale disk-type for packing in a 200 L drum could be fabricated with a tolerable anisotropy shrinkage. This has resulted in a significant reduction in the volume of radioactive waste to be disposed of with highly stable wasteform.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2005.05a
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• pp.65-68
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• 2005

This paper investigated the engineering properties of cement mortar mixed with more than 2 kinds of sand. For fresh mortar properties, unit volume weight is constant regardless of mixing content and type of sand. An increase in contents of river and crushed sand resulted in an increase in flow, whereas an increase in recycled sand contents reduced flow. Gap between maximum flow in N3C0R0 and minimum flow in N0C0R3 exhibited about $12\%$. Compressive strength at 28 days ranged from 32 to 36 MPa in order for crushed sand, river sand and recycled sand. Mortar with mixed sand along with river sand and crushed sand showed compressive strength comparable to crushed sand. An increase of fraction of recycled sand in mixed sand resulted in a decrease in compressive strength. For drying shrinkage, N0C0R3 had the largest drying shrinkage among various mixture type. The combination of large contents of recycled sand and small contents of river and crushed sand had a large amount of drying shrinkage.